• Title/Summary/Keyword: Negative temperature coefficient

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Dielectric Properties of Strontium-substituted Lead Magnesium Tungstate up to Microwave Frequencies

  • Kim, J.H.;Choo, W.K.
    • The Korean Journal of Ceramics
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    • v.4 no.4
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    • pp.394-398
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    • 1998
  • $Pb_{1-x}Sr_x(Mg-{1}2}W_{1}2})O_3$$ ceramics for application in the microwave frequency range were investigated by dielectric constant and X-ray diffraction measurements. The dielectric constant curves showed two concentration dependent characteristics in the $$Pb(Mg-{1}2}W_{1}2})O_3$-rich$ region. As the Sr constant further increases to x=0.3 the dielectric curve levels off. In the concentration range between x=0.4 and x=1 in which dielectric constant dependence on temperature is negligible, it decreases and Qf value increases in the microwave frequency with increasing Sr. The temperature coefficient (${\tau}_{\varepsilon} $) of the dielectric constant changes from the negative to positive value between x=0.9 and x=1. The dielectric constant, Qf and $\tau\varepsilon$ are correlated with tolerance factor(t). From the X-ray diffraction results for $0.1{\le}x{\le}1$ the cell parameter is found to decrease as x increases and B-site ordering is observed in all the composition ranges.

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The Fabrication of Mulilayer Chip NTC Thermistor for Mobile Communication Telephone (이동통신 단말기에 이용되는 적층 칩 써미스터 제작)

  • Yoon, Jung-Rag;Lee, Heon-Yong;Kim, Jee-Gyun;Lee, Suk-Won
    • Proceedings of the KIEE Conference
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    • 2000.07c
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    • pp.1794-1796
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    • 2000
  • Oxides of the form $Mn_{3}O_4$-$Co_{3}O_4$-NiO present properties that make them useful as multilayer chip NTC thermistor for mobile communication telephone. When $Mn_{2}Ni_{x}CO_{1-x}O_4$ composition with the X = 0.12$\sim$0.24 at sintered temperature 1250$^{\circ}C$, resistivity and B-constant were 300$\sim$450[${\Omega}-cm$] and 3250$\sim$3450, respectively. Multilayer chip NTC(Negative Temperature Coefficient) resistor were fabricated with 4 layer by a conventional multilayer capacitor techniques, using 100 pd paste as internal electrode and $Mn_{2}Ni_{0.20}CO_{0.8}O_4$ composition as NTC materials. In particular, resistance change ratio (${\Delta}R$), the important factor for reliability, varied within $\pm$3%, indicating the compositions of multilayer chip NTC thermistor products could be available for mobile communication telephone.

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Heat Transfer Analysis of Hydropneumatic Suspension Unit By Finite Element Method (유한요소법을 이용한 유기압 현수장치의 열전달 해석)

  • Bae, Jing-Do;Cho, Jin-Rae;Lee, Hong-Woo;Song, Jung-In;Lee, Jin-Kyoo
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.531-536
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    • 2004
  • In-arm type hydropeumatic suspension unit(ISU) is an equipment of armed tracked vehicle to absorb impact load and vibration from the irregular ground. During the operation of ISU, main piston moves forward and backward and oil flowing through damper transmits the external impact load to floating piston. Heat is generated in ISU by the oil pressure drop through the damper orifice and the friction between cylinder wall and two pistons. On the other hand, internal heat dissipatis outside via heat convection. Occurrence of high temperature can deteriorate durability of major components and basic function of ISU. And, it can cause fatal problem in the ISU life time and the sealing performance of piston rings. As well, the spring constant change of nitrogen gas that is caused by the temperature rise exerts the negative effect to the vehicle stability. Therefore, in this paper, we analyze the heat transfer analysis of the entire ISU unit, by finite element method, with the outside flow velocities 8m/s and 10m/s.

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Transport Properties of Polypyrrole Films Doped with Sulphonic Acids

  • Basavaraja, C.;Kim, Na-Ri;Jo, Eun-Ae;Pierson, R.;Huh, Do-Sung;Venkataraman, A.
    • Bulletin of the Korean Chemical Society
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    • v.30 no.11
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    • pp.2701-2706
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    • 2009
  • The polymer blends containing polypyrrole (PPy) and the sulphonic acids such as β-naphthalene sulfonic acid (NSA), camphor sulfonic acid (CSA), and dodecylbenzenesulfonic acid (DBSA) were synthesized by in situ deposition technique in an aqueous media using ammonium per sulfate (APS) as an initiator. The obtained films were characterized by scanning electron microscopy (SEM), and the thermal behavior of these polymer blends was analyzed by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The temperature-dependent (DC) conductivity of the obtained films shows a semiconducting behavior with a negative temperature coefficient of resistivity (TCR). The conductivity data were also analyzed through Mott’s equation, which provides the variable range hopping model in three dimensions. The parameters such as density of states at the Fermi energy, hopping energy, and hopping distance were calculated for PPy, PPy-NSA, PPy-CSA, and PPy-DBSA films, and the data were compared.

Structural and electrical properties of lead free ceramic: Ba(Nd1/2Nb1/2)O3

  • Nath, K. Amar;Prasad, K.;Chandra, K.P.;Kulkarni, A.R.
    • Advances in materials Research
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    • v.2 no.2
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    • pp.119-131
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    • 2013
  • Impedance and electrical conduction studies of $Ba(Nd_{1/2}Nb_{1/2})O_3$ ceramic prepared using conventional high temperature solid-state reaction technique are presented. The crystal symmetry, space group and unit cell dimensions were estimated using Rietveld analysis. X-ray diffraction analysis indicated the formation of a single-phase cubic structure with space group $Pm\bar{3}m$. Energy dispersive X-ray analysis and scanning electron microscopy studies were carried to study the quality and purity of compound. The circuit model fittings were carried out using the impedance data to find the correlation between the response of real system and idealized model electrical circuit. Complex impedance analyses suggested the dielectric relaxation to be of non-Debye type and negative temperature coefficient of resistance character. The correlated barrier hopping model was employed to successfully explain the mechanism of charge transport in $Ba(Nd_{1/2}Nb_{1/2})O_3$. The ac conductivity data were used to evaluate the density of states at Fermi level, minimum hopping length and apparent activation energy.

Trend Analysis of GPS Precipitable Water Vapor Above South Korea Over the Last 10 Years

  • Sohn, Dong-Hyo;Cho, Jung-Ho
    • Journal of Astronomy and Space Sciences
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    • v.27 no.3
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    • pp.231-238
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    • 2010
  • We analyzed global positioning system (GPS)-derived precipitable water vapor (PWV) trends of the Korea Astronomy and Space Science Institute 5 stations (Seoul, Daejeon, Mokpo, Milyang, Sokcho) where Korea Meteorological Administration meteorological data can be obtained at the same place. In the least squares analysis, the GPS PWV time series showed consistent positive trends (0.11 mm/year) over South Korea from 2000 to 2009. The annual increase of GPS PWV was comparable with the 0.17 mm/year and 0.02 mm/year from the National Center for Atmospheric Research Earth Observing Laboratory and Atmospheric InfraRed Sounder, respectively. For seasonal analysis, the increasing tendency was found by 0.05 mm/year, 0.16 mm/year, 0.04 mm/year in spring (March-May), summer (June-August) and winter (December-February), respectively. However, a negative trend (-0.14 mm/year) was seen in autumn (September-November). We examined the relationship between GPS PWV and temperature which is the one of the climatic elements. Two elements trends increased during the same period and the correlation coefficient was about 0.8. Also, we found the temperature rise has increased more GPS PWV and observed a stronger positive trend in summer than in winter. This is characterized by hot humid summer and cold dry winter of Korea climate and depending on the amount of water vapor the air contains at a certain temperature. In addition, it is assumed that GPS PWV positive trend is caused by increasing amount of saturated water vapor due to temperature rise in the Korean Peninsula. In the future, we plan to verify GPS PWV effectiveness as a tool to monitor changes in precipitable water through cause analysis of seasonal trends and indepth/long-term comparative analysis between GPS PWV and other climatic elements.

Prismatic-core advanced high temperature reactor and thermal energy storage coupled system - A preliminary design

  • Alameri, Saeed A.;King, Jeffrey C.;Alkaabi, Ahmed K.;Addad, Yacine
    • Nuclear Engineering and Technology
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    • v.52 no.2
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    • pp.248-257
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    • 2020
  • This study presents an initial design for a novel system consisting in a coupled nuclear reactor and a phase change material-based thermal energy storage (TES) component, which acts as a buffer and regulator of heat transfer between the primary and secondary loops. The goal of this concept is to enhance the capacity factor of nuclear power plants (NPPs) in the case of high integration of renewable energy sources into the electric grid. Hence, this system could support in elevating the economics of NPPs in current competitive markets, especially with subsidized solar and wind energy sources, and relatively low oil and gas prices. Furthermore, utilizing a prismatic-core advanced high temperature reactor (PAHTR) cooled by a molten salt with a high melting point, have the potential in increasing the system efficiency due to its high operating temperature, and providing the baseline requirements for coupling other process heat applications. The present research studies the neutronics and thermal hydraulics (TH) of the PAHTR as well as TH calculations for the TES which consists of 300 blocks with a total heat storage capacity of 150 MWd. SERPENT Monte Carlo and MCNP5 codes carried out the neutronics analysis of the PAHTR which is sized to have a 5-year refueling cycle and rated power of 300 MWth. The PAHTR has 10 metric tons of heavy metal with 19.75 wt% enriched UO2 TRISO fuel, a hot clean excess reactivity and shutdown margin of $33.70 and -$115.68; respectively, negative temperature feedback coefficients, and an axial flux peaking factor of 1.68. Star-CCM + code predicted the correct convective heat transfer coefficient variations for both the reactor and the storage. TH analysis results show that the flow in the primary loop (in the reactor and TES) remains in the developing mixed convection regime while it reaches a fully developed flow in the secondary loop.

Thermoelectric Properties of Bi2Te3 Films Grown by Modified MOCVD with Substrate Temperatures (개조된 MOCVD법으로 성장한 Bi2Te3 박막의 기판온도에 따른 열전 특성)

  • You, Hyun-Woo;Kwon, O-Jong;Kim, Kwang-Chon;Choi, Won-Chel;Park, Chan;Kim, Jin-Sang
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.4
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    • pp.340-344
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    • 2011
  • Thermoelectric bismuth telluride ($Bi_2Te_3$) films were deposited on $4^{\circ}$ off oriented (001) GaAs substrates using a modified metal organic chemical vapor deposition (MOCVD) system. The effects of substrate temperature on surface morphologies, crystallinity, electrical properties and thermoelctric properties were investigated. Two dimensional growth mode (2D) was observed at substrate temperature lower than $400^{\circ}C$. However, three dimensional growth mode (3D) was observed at substrate temperature higher than $400^{\circ}C$. Change of growth mechanism from 2D to 3D was confirmed with environmental scanning electron microscope (E-SEM) and X-ray diffraction analysis. Seebeck coefficients of all samples have negative values. This result indicates that $Bi_2Te_3$ films grown by modified MOCVD are n-type. The maximum value of Seebeck coefficient was -225 ${\mu}V/K$ and the power factor was $1.86{\times}10^{-3}\;W/mK^2$ at the substrate temperature of $400^{\circ}C$. $Bi_2Te_3$ films deposited using modified MOCVD can be used to fabricate high-performance thermoelectric devices.

Organic Solvent Dyeing(III) -The Interpretation of Dyeing Behavior by Thermodynamic Parameters on Dyeing of Polyester Fiber in Alkanes as Dyeing Media- (유기용매염색(III) -Alkane류를 염색매체로 한 PET의 염색에 있어서 열역학적 파라미터에 의한 염착거동 해석-)

  • 김태경;임용진;조광호;조규민
    • Textile Coloration and Finishing
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    • v.12 no.1
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    • pp.52-60
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    • 2000
  • In the prior studies, we reported that the dye uptakes of C. I. Disperse Violet 1 on polyester fiber in hexane and cyclohexane were higher than those in the other solvents, as the number of carbon atoms of alkanes decreased, the dye uptake increased, and the logarithmic plot of the dye uptakes vs. the solubilities of the dye showed that the dye uptakes are inversely proportional to the solubilities. In this study, for Interpretation of dyeing behavior of C. I. Disperse Violet 1 on polyester in alkanes, the thremodynamic parameters of dyeing, such as standard affnity, heat of dyeing(enthalpy change), entropy change, diffusion coefficient, and activation energy of diffusion, were obtained from isotherms and dyeing rates at different temperature. As the number of carbon atoms of alkanes increased, the standard affinity decreased, but the heat of dyeing(enthalpy change) and the entropy change showed larger negative values. These results mean that as the number of carbon atoms of alkanes increases, the dye uptake decreases, but both the fraction of the dye molecules dyed at relatively highly aligned or compact region of polyester fiber and the regularity of dye aggregates in the fiber become increased. As the number of carbon atoms of alkanes increased, the diffusion coefficient decreased, but the activation energy of diffusion increased. In the alkane of larger number of carbon atoms, because the solubility of the dye is higher, the desorption rate of the dye is faster and the diffusion coefficient is smaller than those in the smaller alkanes. But the energy required to separate the dye molecules from the alkane molecules is much higher because the interaction between the alkane molecule and the dye molecule become strong with the number of carbon atoms.

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The Development of Infrared Thermal Imaging Safety Diagnosis System Using Pearson's Correlation Coefficient (피어슨 상관계수를 이용한 적외선 열화상 안전 진단 시스템 개발)

  • Jung, Jong-Moon;Park, Sung-Hun;Lee, Yong-Sik;Gim, Jae-Hyeon
    • Journal of the Korean Solar Energy Society
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    • v.39 no.6
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    • pp.55-65
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    • 2019
  • With the rapid development of the national industry, the importance of electrical safety was recognized because of a lot of new electrical equipment are installing and the electrical accidents have been occurring annually. Today, the electrical equipments is inspect by using the portable Infrared thermal imaging camera. but the most negative element of using the camera is inspected for only state of heating, the reliable diagnosis is depended with inspector's knowledge, and real-time monitoring is impossible. This paper present the infrared thermal imaging safety diagnosis system. This system is able to monitor in real time, predict the state of fault, and diagnose the state with analysis of thermal and power data. The system consists of a main processor, an infrared camera module, the power data acquisition board, and a server. The diagnostic algorithm is based on a mathematical model designed by analyzing the Pearson's Correlation Coefficient between temperature and power data. To test the prediction algorithm, the simulations were performed by damaging the terminals or cables on the switchboard to generate a large amount of heat. Utilizing these simulations, the developed prediction algorithm was verified.