• Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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• 2001.06a
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• pp.1281-1281
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• 2001

Near-infrared (NIR) spectra have bean measured for high-density (HDPE), linear low-density (LLDPE), and low-density (LDPE) polyethylene in pellet or thin films. The obtained spectra have been analyzed by conventional spectroscopic analysis methods and chemometrics. By using the second derivative, principal component analysis (PCA), and two-dimensional (2D) correlation analysis, we could separate many overlapped bands in the NIR. It was found that the intensities of some bands are sensitive to density and crystallinity of PE. This may be the first time that such bands in the NIR region have ever been discussed. Correlations of such marker bands among the NIR spectra have also been investigated. This sort of investigation is very important not only for further understanding of vibration spectra of various of PE but also for quality control of PE by vibrational spectroscopy. Figure 1 (a) and (b) shows a NIR reflectance spectrum of one of the LLDPE samples and that of PE, respectively. Figure 2 shows a PC weight loadings plot of factor 1 for a score plot of PCA for the 16 kinds of LLDPE and PE based upon their 51 NIR spectra in the 1100-1900 nm region. The PC loadings plot separates the bands due to the $CH_3$ groups and those arising form the $CH_2$ groups, allowing one to make band assignments. The 2D correlation analysis is also powerful in band enhancement, and the band assignments based upon PCA are in good agreement with those by the 2D correlation analysis.(Figure omitted). We have made a calibration model, which predicts the density of LLDPE by use of partial least square (PLS) regression. From the loadings plot of regression coefficients for the model , we suggest that the band at 1542, 1728, and 1764 nm very sensitive to the changes in density and crystalinity.

• Journal of Korean Society for Atmospheric Environment
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• v.19 no.E4
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• pp.149-155
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• 2003

In this study. the amounts of the total precipitable water (TPW) in both global and regional scale are estimated from the MODIS instrument, which is on-board the EOS satellites, Terra and Aqua. The estimation is made from the five near-infrared spectral bands, using a technique employing ratios of water- vapor absorbing channels centered at 0.905, 0.936, 0.940 ${\mu}{\textrm}{m}$ with atmospheric window channels at 0.865 and 1.240 ${\mu}{\textrm}{m}$. Through analyses of monthly and eight-days mean TPW, one can monitor characteristics of seasonal variations as well as amount and distribution (i.e., water resources) of TPW at both global and local regions. Long-term monitoring of TPW is essential to understand the regional variations of water resources in East Asia.

• The Bulletin of The Korean Astronomical Society
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• v.37 no.2
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• pp.223.2-223.2
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• 2012

Grating spectrograph observation in near-infrared bands requires wavelength calibrations. We first need to extract order-strips from the echellogram data using flat images, and then to correct the spatial distortions and wavelength scales of the order strips using calibration arc lamps or the telluric OH emission lines. For very high resolution spectrograph using echelle, however, the arc lamps do not have enough emission lines in the order-strips, so we usually use the OH lines for accurate wavelength calibrations in wavelengths shorter than 2.3 microns. In this poster, we present wavelength calibration methods for longer wavelength bands using the telluric absorption lines in early-type stellar spectra and the telluric atmospheric transmission models. This technique will be applied to the data reduction pipeline for the IGRINS.

• Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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• 2001.06a
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• pp.1283-1283
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• 2001

NIR spectroscopy has been used extensively to investigate the structure of water, alcohol and other self-associate molecules because the frequencies of NIR bands due to OH and NH groups strength of hydrogen bonds. We have studied the structure of water -methanol mixtures by use of NIR spectroscopy. Strong features in the 7200-6300 $cm^{-1}$ / region consist of a number of overlapped bands due to the combination of OH antisymmetric and symmetric stretching modes of water and the first overtone of the OH stretching modes of free and hydrogen bonded methanol, while weak fratures in the 6000-5800 cm-1 region are ascribed to the first overtones of $CH_3$ stretching modes of methanol. We will focus the discussion on the $CH_3$ stretching bands. They seem to show a significant shift is not clear from the spectra shown in figure 1(a). Figure 1(b) depicts the second derivative in the 6000-5700 $cm^{-1}$ / region. Now, it is clear from the second derivative that there are two major bands near 5950 and 5900 $cm^{-1}$ / and that they do show a shift be about 30 $cm^{-1}$ / Why do the $CH_3$ bands show the shift with increasing concentration of methanol\ulcorner Probably, the CH, group interacts directly with OH groups of water. The results in figure 1(b) demonstrate the usefulness of the second derivative in resolution enhancement as well as the potential of NIR spectroscopy in the studies of molecular interactions.(Figure omitted).

• Publications of The Korean Astronomical Society
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• v.32 no.1
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• pp.83-85
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• 2017

We conducted an unbiased near- to mid-infrared imaging and spectroscopic survey of the Large Magellanic Cloud (LMC) as a part of the AKARI Mission Program "Large-area Survey of the LMC" (LSLMC, PI: T. Onaka). An area of about 10 square degrees of the LMC was observed by five photometric bands (3.2, 7, 11, 15, and $24{\mu}m$) and a low-resolution slitless prism ($2-5{\mu}m$, R ~20) equipped with AKARI /IRC. We constructed and publicly released photometric and spectroscopic catalogues of point sources in the LMC based on the survey data. The catalogues provide a large number of near-infrared spectral data, coupled with complementary broadband photometric data. Combined use of the present AKARI LSLMC catalogues with other infrared point source catalogues of the LMC possesses scientific potential that can be applied to various astronomical studies.

• Publications of The Korean Astronomical Society
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• v.32 no.1
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• pp.101-103
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• 2017

We have carried out the near-infrared spectroscopic observations of recent classical novae (e.g., V2468Cyg, V1280Sco) within a few years from the outburst with AKARI as a part of AKARI Open Time Observing Program for Phase 3-II "Spectral Evolution of Novae in the Near-Infrared based on AKARI Observations (Proposal ID: SENNA)". The homogeneous datasets of near-infrared spectra from $2.5{\mu}m$ to $5{\mu}m$ with AKARI/IRC collected in this program are useful to infer the physical conditions of the shell formed by the ejected materials, to examine the chemical properties of the ejecta gas, and to examine the properties of dust formed in the nova ejecta.

• Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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• 2001.06a
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• pp.1518-1518
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• 2001

In the area of the destruction-free NIR analysis of fruit and vegetables development has not yet progressed as far as in grain and similar products. One reason for that is, that in contrast to grains, in fruit and vegetables water appears as the outstanding main-component making up typically 80% by weight of the fruit. Of the M absorption spectrum of pure water the bands at 1450, 970 and 760 nm are the first, second and third overtones respectively of O-H stretch while those at 1940 and 1190 are combination bands involving O-H stretch and O-H bend. The choice of band for spectrometry is governed by considerations of sensitivity and selectivity. The overtone bands are satisfactory for use in moisture measurements from 0 to 4 % depending on path length. Measurements in fruits and vegetables at wavelength areas that are also important for the determination of carbohydrates (sucrose, glucose, fructose) often lead to total absorption in the presence of significant water even if short path lengths are possible. In this work model systems are used containing different carbohydrates in solvents like heavy water (D$_2$O) or dimethylsulfoxide (DMSO) that do not contain O-H functional groups.

• Korean Journal of Remote Sensing
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• v.35 no.3
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• pp.375-387
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• 2019

The use of drone-based hyperspectral image offers considerable advantages in high resolution remote sensing applications. The primary objective of this study was to select the optimal bands based on hyperspectral image for the estimation yield of the chinese cabbage. The hyperspectral narrow bands were acquired over 403.36 to 995.19 nm using a 3.97 nm wide, 150 bands, drone-based hyperspectral imaging sensor. Fresh weight data were obtained from 2,031 sample for each field survey. Normalized difference vegetation indices were computed using red, red-edge and near-infrared bands and their relationship with quantitative each fresh weights were established and compared. As a result, predominant proportion of fresh weights are best estimated using data from three narrow bands, in order of importance, centered around 697.29 nm (red band), 717.15 nm (red-edge band) and 808.51 nm (near-infrared band). The study determined three spectral bands that provide optimal chinese cabbage productivity in the visible and near-infrared portion of the spectrum.

• Proceedings of the Korean Society For Composite Materials Conference
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• 1999.11a
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• pp.73-76
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• 1999

Near infrared spectroscopy techniques were used to study the cure reactions of epoxy resin system based on diglycidyl ether of bisphenol A(DGEBA) resins cured with 4, 4' diaminodiphenyl sulfone (DDS) hardner. Stoichiometric DGEBA/DDS resin formulation was involved in this study. The infrared absorption spectra of the prepared formulation were obtained on an FTIR spectrometer operating in the region of 11000 to 4000$cm^{-l}$. The chemical group peaks of interest in a DFEBA/DDS spectrum were identified by a comparative study with individual spectra of DGEBA and DDS monomers. Where necessary, special model compounds were used to identify unknown bands, such as the primary amine band at 4535$cm^{-l}$. The absorption bands of interest were integrated to quantify the areas and then converted to molar concentrations. This series of quantitative analyses of the major chemical groups led us to understand not only the reaction mechanism but also the cure kinetics. In this paper, the reaction mechanisms observed in stoichiometric DGEBA/DDS resin formulation and the various properties of the resin system as a function of cure temperature are described.

• Publications of The Korean Astronomical Society
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• v.27 no.4
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• pp.209-212
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• 2012

We present the results of the near-infrared (NIR) to mid-infrared (MIR) slit spectroscopic observations of the diffuse emission toward nine positions in the nearby irregular galaxy Large Magellanic Cloud (LMC) with the Infrared Camera (IRC) on board AKARI. The unique characteristic of AKARI/IRC provides a great opportunity to analyze variations in the unidentified infrared (UIR) bands based on continuous spectra from 2.5 to $13.4{\mu}m$ of the same slit area. The observed variation of $I_{3.3}/I_{11.3}$ suggests destruction of small-sized UIR band carriers, polycyclic aromatic hydrocarbons (PAHs) in harsh environments. This result demonstrates that the UIR $3.3{\mu}m$ band provides us powerful information on the excitation conditions and/or the size distribution of PAHs, which is of importance for understanding the evolutionary process of hydrocarbon grains in the Universe. It also suggests a new diagnostic diagram of two band ratios, such as $I_{3.3}/I_{11.3}$ versus $I_{7.7}/I_{11.3}$, for the interstellar radiation conditions. We discuss on the applicability of the diagnostic diagram to other astronomical objects, comparing the LMC results with those observed in other galaxies such as NGC 6946, NGC 1313, and M51.