• Title/Summary/Keyword: Near Infrared Spectroscopy

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Rapid Compositional Analysis of Naphtha by Near-Infrared Spectroscopy

  • 구민식;정호일;이준식
    • Bulletin of the Korean Chemical Society
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    • v.19 no.11
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    • pp.1189-1193
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    • 1998
  • The determination of total paraffin, naphthene, and aromatic (PNA) contents in naphtha samples, which were directly obtained from actual refining process, has been studied using near-infrared (NIR) spectroscopy. Each of the total PNA concentrations in naphtha has been successfully analyzed using NIR spectroscopy. Partial least squares (PLS) regression method has been utilized to quantify the total PNA contents in naphtha from the NIR spectral bands. The NIR calibration results showed an excellent correlation with those of conventional gas chromatography (GC). Due to its rapidity and accuracy, NIR spectroscopy is appeared as a new analytical technique which can be substituted for the conventional GC method for the quantitative analysis of petrochemical products including naphtha.

Measurement of lipid content of compost fermentation using near-infrared spectroscopy

  • Daisuke Masui;Suehara, Ken-ichiro;Yasuhisa Nakano;Takuo Yano
    • Near Infrared Analysis
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    • v.2 no.1
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    • pp.37-42
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    • 2001
  • Near infrared spectroscopy (NIRS) was applied to determination of the lipid content of the compost during the compost fermentation of tofu (soybean0curd) refuse. The absorption of lipid observed at 5 wavelengths, 1208, 1712, 1772, 2312 and 2352 nm on the second derivative spectra. To formulated a calibration equation, a multiple linear regression analysis was carried out between the near-infrared spectral data and on the lipid content in the calibration sample set (sample number, n=60) obtained using Soxhlet extraction method. The value of the multiple correlation coefficient (R) was 0.975 when using the wavelengths of 1208 and 1712 nm were used in the calibration equation. To validate the calibration equation obtained, the lipid content in the validation sample set (n=35) not used for formulating the calibration equation was calculated using the calibration equation, and compared with the value obtained using the Soxhlet extraction method. Good agreement was observed between the results of the Soxhlet extraction method and those values of the NIRS method. The simple correlation coefficient (r) and standard error of prediction (SEP) were 0.964 and 0.815 %, respectively. suitability of the lipid content as an indicator of the compost fermentation of tofu refuse was also studied. The decrease of the lipid content in the compost corresponded to the decrease of the total dry weight of the compost in the composter. The lipid content was a significant indicator of the compost fermentation. The NIRS method was applied to measure the time course of the lipid content in the compost fermentation and good results were obtained. The study indicates that NIRS is a useful method for process management of the compost fermentation of tofu refuse.

AKARI near Infrared spectroscopy of luminous infrared galaxies

  • Lee, Jong-Chul;Hwang, Ho-Seong;Lee, Myung-Gyoon
    • The Bulletin of The Korean Astronomical Society
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    • v.37 no.1
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    • pp.50.2-50.2
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    • 2012
  • We present the results of near infrared (2.5-5 micron) spectroscopy of nearby luminous infrared galaxies (LIRGs) using AKARI. The LIRG catalog is constructed from the cross-correlation between the Infrared Astronomical Satellite and the Sloan Digital Sky Survey data, and optically non-Seyfert type LIRGs are selected for main targets. We search for optically elusive active galactic nuclei (AGNs), based on the strengths of 3.3 micron polycyclic aromatic hydrocarbon emission and dust absorption features at 3-4 micron. We investigate the hidden AGN fraction as a function of the infrared luminosity and correlation between optical and near infrared star formation indicators.

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Evaluation of the Scar Treatment using Near Infrared Diffuse Reflectance Spectroscopy (근적외선 확산반사 분광법을 이용한 흉터치료 평가)

  • Jang, I.J.;Youn, Jong-In
    • Journal of Biomedical Engineering Research
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    • v.37 no.1
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    • pp.53-60
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    • 2016
  • Monitoring of dermal collagen is important to assess various scar conditions, and many diagnostic methods have been applied to quantify collagen contents in scar tissue. In this study, Monte Carlo simulation was used to evaluate diffuse reflectance distributions in scar condition by a near-infrared laser source. The results showed that the effective distance of the light source and the detector was 2 mm to monitor the various scar conditions using diffuse reflectance spectroscopy. This study may suggest to the optimal design for a near infrared diffuse reflectance spectroscopy during the scar treatment.

Discrimination of Alismatis Rhizoma According to Geographical Origins using Near Infrared Spectroscopy (근적외선분광법을 이용한 택사의 산지 판별법 연구)

  • Lee, Dong Young;Kim, Seung Hyun;Kim, Hyo Jin;Sung, Sang Hyun
    • Korean Journal of Pharmacognosy
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    • v.44 no.4
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    • pp.344-349
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    • 2013
  • Near infrared spectroscopy (NIRS) combined with multivariate analysis was used to discriminate the geographical origin of Alisma orientale from Korea (n=94) and China (n=72). Two-thirds of samples were selected randomly for the training set, and one-third of samples for the test set. Second derivative was used for the pretreatment of NIR spectra. Partial least square discriminant analysis (PLS-DA) models correctly discriminated 100% of the Korean and Chinese A. orientale samples. These results demonstrate the potential use of NIR spectroscopy combined with multivariate analysis as a rapid and accurate method to discriminate A. orientale according to their geographical origin.

FACTORS INVOLVED IN DEVELOPMENT OF ELECTRONIC SYSTEMS FOR GRADING GRAINS AND SEEDS

  • Williams, Phil
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.3121-3121
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    • 2001
  • The factors involved in development of electronic grading systems for commodities such as grains and seeds include determination of the factors that influence the end-product utilization of the commodities, and the degree to which these can be predicted by electronic methods. The possibility of exchanging existing methods of grading by electronic methods has to be considered. The respective merits of techniques such as Digital Imaging and Near-infrared (NIR) spectroscopy have to be considered. Digital Imaging is a computerized version of visual inspection and grading, whereas NIR spectroscopy has the potential for grading on the basis of composition and functionality, Selection and evaluation of NIR instruments is an important factor, as are sampling and sample presentation to electronic instruments, and particularly the engineering involved in sample presentation. Sample assembly, and software for calibration development are described in the presentation. Finally the impact and implications of introduction of electronic grading are discussed with particular attention to marketing of the commodities.

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Nondestructive Classification between Normal and Artificially Aged Corn (Zea mays L.) Seeds Using Near Infrared Spectroscopy

  • Min, Tai-Gi;Kang, Woo-Sik
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.53 no.3
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    • pp.314-319
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    • 2008
  • Near infrared (NIR) spectroscopy was used to classify normal and artificially aged nonviable corn (Zea mays L., cv. 'Suwon19') seeds. The spectra at 1100-2500nm were scanned with normal and artificially aged single seeds and analyzed by principle component analysis (PCA). To discriminate normal seeds from artificially aged seeds, a calibration modeling set was developed with a discriminant partial least square 2 (PLS 2) method. The calibration model derived from PLS 2 resulted in 100% classification accuracy of normal and artificially aged (aged) seeds from the raw, the 1st and 2nd derivative spectra. The prediction accuracy of the unknown normal seeds was 88, 100 and 97% from the raw, the $1^{st}$ and $2^{nd}$ derivative spectra, and that of the unknown aged seeds was 100% from all the raw, the $1^{st}$ and $2^{nd}$ derivative spectra, respectively. The results showed a possibility to separate corn seeds into viable and non-viable using NIR spectroscopy.

Analysis on Food Waste Compost by Near Infrared Reflectance Spectroscopy(NIRS) (Near Infrared Reflectance Spectroscopy(NIRS)에 의한 음식물 쓰레기 퇴비 분석에 관한 연구)

  • Lee Hyo-Won;Kil Dong-Yong
    • Korean Journal of Organic Agriculture
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    • v.13 no.3
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    • pp.281-289
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    • 2005
  • In order to find out an alternative way of analysis of food waste compost, the Near Infrared Reflectance Spectroscopy(NIRS) was used for the compost assessment because the technics has been known as non-detructive, cost-effective and rapid method. One hundred thirty six compost samples were collected from Incheon food waste compost factory at Namdong Indurial Complex. The samples were analyzed for nitrogen, organic matter (OM), ash, P, and K using Kjedahl, ignition method, and acid extraction with spectrophotometer, respectively. The samples were scanned using FOSS NIRSystem of Model 6500 scanning mono-chromator with wavelength from $400\~2,400nm$ at 2nm interval. Modified partial Least Squares(MPLS) was applied to develop the most reliable calibration model between NIR spectra and sample components such as nitrogen, ash, OM, P, and K. The regression was validated using validation set(n=30). Multiple correlation coefficient($R^2$) and standard error of prediction(SEP) for nitrogen, ash, organic matter, OM/N ratio, P and K were 0.87, 0.06, 0.72, 1.07, 0.68, 1.05, 0.89, 0.31, 0.77, 0.06, and 0.64, 0.07, respectively. The results of this experiment indicates that NIRS is reliable analytical method to assess some components of feed waste compost, also suggests that feasibility of NIRS can be Justified in case of various sample collection around the year.

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Predicting Soil Chemical Properties with Regression Rules from Visible-near Infrared Reflectance Spectroscopy

  • Hong, Suk Young;Lee, Kyungdo;Minasny, Budiman;Kim, Yihyun;Hyun, Byung Keun
    • Korean Journal of Soil Science and Fertilizer
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    • v.47 no.5
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    • pp.319-323
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    • 2014
  • This study investigates the prediction of soil chemical properties (organic matter (OM), pH, Ca, Mg, K, Na, total acidity, cation exchange capacity (CEC)) on 688 Korean soil samples using the visible-near infrared reflectance (VIS-NIR) spectroscopy. Reflectance from the visible to near-infrared spectrum (350 to 2500 nm) was acquired using the ASD Field Spec Pro. A total of 688 soil samples from 168 soil profiles were collected from 2009 to 2011. The spectra were resampled to 10 nm spacing and converted to the 1st derivative of absorbance (log (1/R)), which was used for predicting soil chemical properties. Principal components analysis (PCA), partial least squares regression (PLSR) and regression rules model (Cubist) were applied to predict soil chemical properties. The regression rules model (Cubist) showed the best results among these, with lower error on the calibration data. For quantitatively determining OM, total acidity, CEC, a VIS-NIR spectroscopy could be used as a routine method if the estimation quality is more improved.

Nondestructive determination of humic acid in compost by NIRS

  • Seo, Sang-Hyun;Han, Xiao-Ri;Cho, Rae-Kwang;Park, Woo-Churl
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1623-1623
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    • 2001
  • Composting is a biological method used to transform the organic waste into stable, humified organic amendments. Humification is indicated as the key factor in improving the quality of compost, because of the importance of humic substances to soil ecology, fertility and structure, and their beneficial effects on plant growth The compost constituents vary widely, however, the degree of maturity is very important factor in compost quality. So this experiment carried out to determine the rapid estimation of the quality in cattle, pig, chicken and waste composts using near infrared reflectance spectroscopy(NIRS). Near infrared reflectance spectra of composts was obtained by Infra Alyzer 500 scanning spectrophotometer at 2-nm intervals from 1100 to 2500nm. Multiple linear regression(MLR) or partial least square regression (PLSR) was used to evaluate a NIRS method for the rapid and nondestructive determination of humic acid contents in composts. The results summarized that NIR spectroscopy can be used as a routine testing method to determine quantitatively the humic acid content in the compost samples ondestructively. Especially, we supposed that absorbance around 2300nm is related to humic acid as a factor of compost maturity. However the NIR absorption approach is empirical, it actually requires many combinations of samples and data manipulations to obtain optimal prediction.

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