• Title/Summary/Keyword: Nd-rich

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Two-step Solution Treatment for Enhancement of Mechanical Properties of AlSiCu Aluminum Alloy (Al6Si2Cu 알루미늄 합금의 기계적 물성 향상을 위한 이단계 고용화 열처리)

  • Park, Sang-Gyu;Kim, Chung-Seok
    • Journal of the Korean Society for Heat Treatment
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    • v.31 no.3
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    • pp.97-103
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    • 2018
  • The objective of this study is to develop the mechanical properties of AlSiCu aluminum alloy by the two-step solution heat treatment. The microstructure of gravity casting specimen represents a typical dendrite structure having a secondary dendrite arm spacing (SDAS) of 40 mm. In addition to the Al matrix, a large amount of coarsen eutectic Si phase, $Al_2Cu$ intermetallic phase, and Fe-rich phases are generated. The eutectic Si phases are fragmented and globularized with solution heat treatment. Also, the $Al_2Cu$ intermetallic phase is resolutionized into the Al matrix. The $2^{nd}$ solution temperature at $525^{\circ}C$ might be a optimum condition for enhancement of mechanical properties of AlSiCu aluminum alloy.

Effect of deposition temperature on the photoluminescence of Si nanocrystallites thin films (증착 온도에 따른 실리콘 나노결정 박막의 광학적 특성변화 연구)

  • Jeon, Kyung-Ah;Kim, Jong-Hoon;Choi, Jin-Back;Lee, Sang-Yeol
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.04b
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    • pp.38-41
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    • 2002
  • The variation of photoluminescence(PL) properties of Si thin films was investigated by changing deposition temperatures, Si-rich silicon oxide films on p-type (100) Si substrate have been fabricated by pulsed laser deposition(PLD) technique using a Nd:YAG laser. During deposition, the substrates were kept at the temperature range of room temperature(RT) to $400^{\circ}C$. After deposition, samples were annealed at $800^{\circ}C$ in nitrogen ambient, Strong Blue PL has been observed on RT-deposited Si nanocrystallites. When the deposition temperature was increased over $100^{\circ}C$, PL intensities abruptly decreased. The experimental results show the growing mechanism of Si nanocrystallites by PLD.

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Rare earth removal from pyroprocessing fuel product for preparing MSR fuel

  • Dalsung Yoon;Seungwoo Paek;Chang Hwa Lee
    • Nuclear Engineering and Technology
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    • v.56 no.3
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    • pp.1013-1021
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    • 2024
  • A series of experiments were performed to produce a fuel source for a molten salt reactor (MSR) through pyroprocessing technology. A simulated LiCl-KCl-UCl3-NdCl3 salt system was prepared, and the U element was fully recovered using a liquid cadmium cathode (LCC) by applying a constant current. As a result, the salt was purified with an UCl3 concentration lower than 100 ppm. Subsequently, the U/RE ingot was prepared by melting U and RE metals in Y2O3 crucible at 1473 K as a surrogate for RE-rich ingot product from pyroprocessing. The produced ingot was sliced and used as a working electrode in LiCl-KCl-LaCl3 salt. Only RE elements were then anodically dissolved by applying potential at - 1.7 V versus Ag/AgCl reference electrode. The RE-removed ingot product was used to produce UCl3 via the reaction with NH4Cl in a sealed reactor.

Geochemical Characteristics of Allanite from Rare Metal Deposits in the Chungju Area, Chungcheongbuk-Do (Province), Korea (충주지역 희유원소광상에서 산출되는 갈렴석의 지구화학적특성)

  • Park, Maeng-Eon;Kim, Gun-Soo;Choi, In-Sik
    • Economic and Environmental Geology
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    • v.29 no.5
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    • pp.545-559
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    • 1996
  • Rare metal (Nb-Zr-REE) ore deposits are located in the Chungju area. Geotectonically, the rare metal ore deposits are situated in the transitional zone between Kyeonggi massif and Okcheon belt. The rare metal deposits are distributed in Kyemyeongsan Formation which consist of schist and alkaline igneous rocks. Alkali granite has suffered extensive post-magmatic metasomatism and hydrothermal processes. The ore contains mainly Ce-La, Ta-Nb, Y, Y-Nd, Nd-Th group minerals. More than 15 RE and REE minerals are found in the ore deposits. Allanite, one of the Ce-La rich REE minerals belonging to the epidote group, is the most common mineral in the studied area. The allanite- bearing rocks may be devided into seven types by features of occurrence and mineral associations; zircon type (ZT), allanite-vein type (AT), feldspar type (KT), fluorite type (FT), quartz-mica type (QT), iron-oxide type (MT), and amphibole type (HT). The allanite veins (AT) and zircon rich rocks (ZT) contain the highest total REE contents. Differences in REE abundance can be interpreted in terms of varying portions of magmatic hydrothermal fluid. Petrographical and chemical data are presented for allanites which were collected from different types. The allanites show wide variations in optical properties, due in part to differences in their chemical composition (depending on the types) and to the degree of crystallinity of the individual specimens. Allanite metamicts in biotite are generally surrounded by well developed pleochroic haloes. Usually, allanite is accompanied by zircon and other REE-bearing minerals. CaO and total REE contents $({\sum}RE_2O_3)$ range from 9.29 to 18.79% and 11.66 to 26.31%, respectively. Also, SiO, (28.87~32.61%), $Al_2O_3$ (8.30~16.88%), and $Fc_2O_3$ (16.74~24.38%) contents show varying contents from type to type. The ${\sum}RE_2O_3$ of allanite has positive relationships with $Fe_2O_3$ and negative relaton with CaO, $SiO_2$, and $Al_2O_3$ Backscattered electron microscope images (BEl) of allanite shows that the its mineral composition and texture is very complex. The allanite-bearing hosts show distinct light REE enrichment with strong negative Eu anomaly except for HI. The HT has an almost flat REE distribution pattern with a small negative Eu anomaly. The chemical variation of the allanites with occurrences and mineral association can be related to condition of temperature and oxidation states in precipitation environment.

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Magnetic Properties of SmCo Thin Films Grown by Using a Nd-YAG Pulsed Laser Ablation Method (Nd-YAG Pulsed Laser Ablation법으로 제작한 SmCo계 박막의 자기특성)

  • 김상원;양충진
    • Journal of the Korean Magnetics Society
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    • v.10 no.1
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    • pp.30-36
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    • 2000
  • SmCo films were deposited on Si(100) substrate by a Nd-YAG pulsed laser ablation of the targets of Sm$\_$100-x/Co$\_$x/ (73$\leq$x$\leq$93) at the substrate temperature of 600∼700$\^{C}$ and the laser beam energy density of Q switching mode or fixed Q mode. The magnetic properties of the films obtained from the Q switching mode exhibited a 4 $\pi$ Ms of 5200∼7700 Gauss, iHc of 190-250 Oe, and 4$\pi$M$\_$r//4$\pi$M$\_$s/ of 0.4∼0.74, respectively, while the fixed Q mode gave the magnetic properties of corresponding films of a 4$\pi$M$\_$r//4$\pi$M$\_$s/ = 0.32∼0.91 and iHc of 430-6290 Oe, respectively. The fixed Q mode gave the better magnetic properties of the SmCo films which seems to be due to a formation of magnetically hard minor phases in droplet of Sm-rich intermetallics. However, the resultant rough surface of the SmCo films is a problem to be solved by a continued study.

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Mantle Source Lithologies of Late Cenozoic Basaltic Rocks and Two Varieties of Enriched Mantle in the Korean Peninsula (한반도 신생대 후기 현무암의 근원 맨틀 암상과 두 종류의 부화 맨틀)

  • Choi, Sung Hi
    • Korean Journal of Mineralogy and Petrology
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    • v.35 no.3
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    • pp.183-197
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    • 2022
  • Geochemical data, including Sr-Nd-Pb-Mg-Zn isotopes, reported on the late Cenozoic intraplate basaltic rocks in the Korean Peninsula (Mt. Baekdu, Jeongok, Baengnyeong Island, Pyeongtaek, Asan, Ganseong, Ulleung Island, Dok Island, and Jeju Island) are summarized to constrain their mantle source lithologies, and the nature of mantle end-members required. In the Sr-Nd isotope correlation diagram, Jeju basalts plot in the field of EM2-type oceanic island basalts (OIB), while the other basalts fall in the EM1-type OIB field. In Pb-Pb isotope space, Jeju basalts show a mixing array between Indian MORB and EM2 component, whereas the other basalts display an array with EM1 component. The Korean basalts were derived from a hybrid source of garnet lherzolite and recycled stagnant slab materials (eclogite/pyroxenite, pelagic sediments, carbonates) in the mantle transition zone. The EM1 component could be ancient (~2.0 Ga) K-hollandite-bearing pelagic sediments that were isolated for a long period in the mantle transition zone due to their neutral buoyancy. The EM2 component might have been relatively young (probably Pacific slab) and recently recycled clay-rich pelagic sediments. Eclogite and carbonates are unlikely to account for the EM components, but they are common in the mantle source of the Korean basalts.

Corrosion and mechanical properties of hot-rolled 0.5%Gd-0.8%B-stainless steels in a simulated nuclear waste treatment solution

  • Jung, Moo Young;Baik, Youl;Choi, Yong;Sohn, D.S.
    • Nuclear Engineering and Technology
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    • v.51 no.1
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    • pp.207-213
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    • 2019
  • Corrosion and mechanical behavior of the hot-rolled 0.5%Gd-0.8%B-stainless steel to develop a spent nuclear fuel storage material was studied in a simulated nuclear waste treatment condition with rolling condition. The austenite and ferrite phases of the 0.5%Gd-0.8%B-stainless steels are about 88:12. The average austenite and ferrite grain size of the plane normal to rolling, transverse and normal directions of the hot rolled specimens are about 5.08, 8.94, 19.35, 23.29, 26.00 and 18.11 [${\mu}m$], respectively. The average micro-hardness of the as-cast specimen is 200.4 Hv, whereas, that of the hot-rolled specimen are 220.1, 204.7 and 203.5 [$H_v$] for the plane normal to RD, TD and ND, respectively. The UTS, YS and elongation of the as-cast and the hot-rolled specimen are 699, 484 [MPa], 34.0%, and 654, 432 [MPa] and 33.3%, respectively. The passivity was observed both for the as-cast and the hot rolled specimens in a simulated nuclear waste solution. The corrosion potential and corrosion rate of the as-casted specimens are $-343[mV_{SHE}]$ and $3.26{\times}10^{-7}[A/cm^2]$, whereas, those of the hot rolled specimens with normal to ND, RD and TD are -630, -512 and -620 [$mV_{SHE}$] and $6.12{\times}10^{-7}$, $1.04{\times}10^{-6}$ and $6.92{\times}10^{-7}[A/cm^2]$, respectively. Corrosion tends to occur preferentially Cr and B rich area.

An Analysis on the Example Spaces of the Concepts of Triangles in the Korean Elementary Mathematics Textbooks (초등 수학교과서의 삼각형의 개념에 대한 예 공간의 분석)

  • Park, Man-Goo
    • Journal of the Korean School Mathematics Society
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    • v.13 no.1
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    • pp.143-161
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    • 2010
  • The purpose of this paper was to analyze the example spaces related with the concepts of triangles in the 2nd grade Korean elementary mathematics textbooks, investigate the meaning of example spaces, and suggest the implications to teaching and learning geometrical concepts in the elementary schools. Mathematics textbooks are usually major materials in teaching and learning mathematics in Korea, and the content of the textbooks affects the quality of teaching and learning in the classroom. The results of the study showed that the Korean elementary textbooks provided examples with limited example spaces concerning the concepts of triangles. The researcher suggested that we should provide rich examples spaces, encourage learner-generated example spaces, and strengthen the connections of examples between in textbooks and in the classroom.

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Optimal Double Heat Treatment Process to Improve the Mechanical Properties of Lightweight AlSiCu Alloy (자동차 경량소재 AlSiCu 합금의 기계적 특성을 개선하기 위한 최적의 이중 열처리공정)

  • Park, Sang-Gyu;Kim, Chung-Seok
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.17 no.3
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    • pp.102-108
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    • 2018
  • The objective of this study is to develop the mechanical properties of an AlSiCu aluminum alloy using the two-step solution heat treatment. The microstructure of the gravity casting specimen represents a typical dendrite structure with a secondary dendrite arm spacing (SDAS) of 40 um. In addition to the Al matrix, a large amount of coarsen eutectic Si phase, $Al_2Cu$ intermetallic phase, and Fe-rich phases is generated. The eutectic Si phases are fragmented and globularized with the solution heat treatment. The $Al_2Cu$ intermetallic phase is also resolutionized into the Al matrix. The $2^{nd}$ solution temperature at $525^{\circ}C$ may be an optimal condition to enhance the mechanical properties of the AlSiCu aluminum alloy.

Propulsion Technologies of Supercavitating Rocket Torpedo, Shkval (초공동 로켓 어뢰 Shkval 추진기술)

  • Kim, Yoon-Gon;Nah, Young-In
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2011.11a
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    • pp.383-387
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    • 2011
  • The supercavitating rocket torpedo SHKVAL was analyzed in view of its system operation procedure and the structure and performance. 3 different propulsion systems installed in SHKVAL were 1st solid rocket booster for launch and acceleration, 2nd solid rocket booster for further acceleration, and Mg-rich Hydroreactive fuel rocket propulsion system for cruising. The gas generator used to help generate the supercavitation bubble was composed of a solid propellant gas generator and a hydroreactive fuel one. The structures and their performance were described based on as much knowledge as we have obtained from cumulative information and up-to-date analysis.

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