• 자원환경지질
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• 제28권2호
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• pp.139-145
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• 1995

Tungsten skarn mineralization of the Sangdong mine is localized in the interbedded limestone layers of the Myobong Slate Formation and in the limestone of the Pungchon Limestone Formation of Cambrian age. Fluid inclusion, gas composition and Nd-Sr isotope for granites and skarns have been investigated. Gas compositions show $CO_2$ rich in the Sangdong granite and CH, rich in the Nonggeori and Eopyeong granites. The initial $^{87}Sr/^{86}Sr$ and $^{143}Nd/^{144}Nd$ ratios of the Sangdong granites have 0.714~0.716(${\varepsilon}_{Sr}$=138~162) and 0.51173~0.51178(${\varepsilon}_{Nd}$=-14.4~15.5), respectively. And their two stage model ages range from 1687 to 1764 Ma. The granite characterized by high strontium initial ratios and negative eNd value could have originated from the old continental crust source. Low homogenization temperature of the Sangdong granite having $203{\sim}296^{\circ}C$ with 1.9~9.2 NaCl equiv. wt% indicates the post-magmatic hydrothermal alteration temperature. Skarn ore fluid responsible for tungsten mineralization has been evolved from CH, rich fluid of early pyroxene garnet skarn to $CO_2$ rich later quartz-mica skarn.

• 자원환경지질
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• 제29권1호
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• pp.35-43
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• 1996

Sr-Nd-Pb isotopic results are reported for the Ogcheon amphibolites from the central part of the Ogcheon Belt. Rb-Sr and Pb-Pb whole rock isotope data plot greatly scattered in the isochron diagrams due to later alteration or metamorphism, whereas the Sm-Nd whole rock isotope data define a linear array with an age of $1270{\pm}220$ Ma ($1{\sigma}$). Considering several geochemical features of the amphibolites, the 1270 Ma linear array may be not a true but an apparent mixing isochron due to source heterogeneity.

• 자원환경지질
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• 제29권2호
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• pp.151-158
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• 1996

Rb-Sr isochron ages, Sr and Nd isotopic compositions were determined for late Cretaceous granophyre on the Haenam-Wando areas, the southwestern part of the Yeongdong-Kwangju depression in Korea. The granophyre in the Haenam-Wando areas are distributed in the shape of a resurgent cauldron. Five samples of Haenam granophyre give a defined Rb-Sr whole rock isochron age of $75.7{\pm}7.2Ma$ and Sr initial ratio of $0.70826{\pm}0.00020(2{\sigma})$. Plagioclase, orthoclase and whole rock of Haenam granophyre give a defined Rb-Sr whole rock-mineral isochron age of $67.0{\pm}5.8Ma$ and Sr initial ratio of $0.708880{\pm}0.00028(2{\sigma})$. Five samples of Wando granophyre give a defined Rb-Sr whole rock isochron age of $70.6{\pm}3.3Ma$ and Sr initial ratio of $0.70850{\pm}0.00088(2{\sigma})$. Eight samples of Haenam granophyre give a defined Nd isotope ratios of 0.512180~0.512259 and ${\varepsilon}Nd$ (T) values of -6.53~-8.15, ${\varepsilon}Sr$ (T) values of +51.49~+66.48 and model age of 1.28~1.60 Ga. Four samples of Wando granophyre give a defined Nd isotope ratios of 0.512228~0.512289 and ${\varepsilon}Nd$ (T) values of -6.74~-8.00, ${\varepsilon}Sr$ (T) values of +54.88~+78.98 and model age of 1.14~1.42 Ga.

• 대한자원환경지질학회:학술대회논문집
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• 대한자원환경지질학회 2000년도 춘계 공동학술발표회
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• pp.110-110
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• 2000

Temporal and spatial distribution patterns of the magmatic rocks and associated ore deposits in the Mesozoic magmatic - metallogenic belt along the Yangtz River, Anhui Province are used to determine and discuss the crust - mantle interaction processes. The magmatic rocks are Cu - Au mineralized high - K calc - alkalic intermediate ¬acidic (CAK) and Fe - Cu mineralized high - Na alkalic - calc intermediate - basic intrusive rocks (FCN) in the central part of the belt and grade to Cu - Mo - Pb - Zn - Ag mineralized calc - alkalic granitoids (CMG) and A - type granites (AG) in the southern and northern parts of the belt. Samples from the CAK and CMG yield Rb - Sr isochron ages of 137 - 140Ma with $(^{87}Sr/^{86}Sr)_{o}$ = 0.7060 - 0.7101, while those from the FCN and AG yield the ages of 120 - 129Ma with $(^{87}Sr/^{86}Sr)_{o}$ = 0.7047 - 0.7077. The Sr isotope ratios, CriTh ratios 0.4 - 3.1), Eu/Eu* ratios < 0.79 - 1.05) and initial epsilon (Nd) values (-16.6 - -6.3) for the CAK and CMG are consistent with magma derivation from old metamorphic basement rocks rich in metallogenic elements through a two - stage process of mantle - derived magma underplating caused by primary lithosphere extension and subsequent partial melting. On the basis of Sr isotope data, CriTh ratios (3.4 - 13.8), Eu/Eu* ratios (0.86 - 1.13) and initial epsilon (Nd) values (-7.7 - +1.4), the FCN and AG are considered to be formed through syntexis with material input from the mantle that resulted from further lithosphere extension followed by mantle - derived magma underplating on a large scale.

• 암석학회지
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• 제14권3호
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• pp.127-140
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• 2005

영남육괴의 중부의 무주군 적상면 삼유리 일대에는 선캠브리아기 원남층군에 해당되는 화강암질 편마암, 반상변정 화강암질 편마암과 우백질 편마암이 분포한다. 이 논문에서는 화강암질 편마암 지역에서 200m심도 까지 굴착한 시추코아의 주성분, 미량성분, 희토류원소 그리고 Sm-Nd, Rb-Sr 동위원소 자료의 지구화학적 의의를 토의하고자 한다. 시추코아의 암상은 심도에 따라 변하고, 주로 화강암질 편마암과 앰피볼라이트로 구성되어 있다. 주성분 및 미량성분의 화학조성 자료를 토대로 한 연구지역내 화강암질 편마암 및 앰피볼라이트의 기원물질은 각각 TTG(Tonalite-Trondhjemite-Granodiorite) 계열 및 솔레아이트 계열의 암석에 속한다. 희토류원소의 분포도를 보면 경희토류(La-Sm)와 중희토류(Gd-Lu)의 변화 및 Eu의 부(-)의 이상이 매우 다양하다. Sm-Nd 동위원소자료에 따른 등시선에 의하면 $2,026{\pm}230(2{\sigma})$ Ma의 연대를 보여주며, 이때의 Nd 초기치는 $0.50979{\pm}0.00028(2{\sigma})$이다. 그리고 ${\epsilon}_{Nd}$(2.0 Ga)값은 -4.4로 연구지역 변성암류의 기원물질이 고기의 지각물질임을 지시해준다. 이 값은 북중국지괴 시생대 기반암의 진화영역에 속하며, 특히 Lee et al.(2005)이 제안한 영남육괴내 Nd 동위원소 초기치의 진화와 일치하는 상관성을 갖는다. 그리고 앰피볼라이트의 희토류원소 분포도와 Nd 초기치는 앰피볼라이트의 기원물질이 결핍된 맨틀과 지각을 형성하기 시작한 초기마그마와 매우 유사함을 지시해준다.

• 한국지구과학회:학술대회논문집
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• 한국지구과학회 2002년도 춘계학술발표 논문요약집
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• pp.35-35
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• 2002

• 자원환경지질
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• 제31권2호
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• pp.149-158
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• 1998

Volcanic rocks including rhyolitic tuff, rhyolite and welded tuff in the Bupyeong silver mine area form a topographic circular structure known as a resurgent caldera. Granitic rocks are emplaced inside and outside area of the circular structure. K-Ar dating and Nd-Sr isotope studies were carried out to invesitigate the origin and petrogenetic evolution of the rhyolitic and granitic magma in the Bupeong silver mine area. Whole rock K-Ar age ranges from 208 to 131 Ma for rhyolitic rocks. Radiometric ages for the granitic rocks are 167.6 Ma for pink feldspar biotite granite from inside granitic pluton of the circular volcanic body, 178.8 Ma for the Kimpo hornblende biotite granite and 111.8 Ma for the Songdo foliated granite from outside granitic plutons of the volcanic body. The radiometric age data indicates that the volcanic activities which are partly overlapped by granite plutonic activities in the Bupyeong mine area had recorded early Jurassic and early Cretaceous in age. Initial Sr and Nd isotopic ratios of the rhyolitic rocks ($^{87}Sr/^{86}Sr$=0.710~0.719 and $^{143}Nd/^{144}Nd$=0.5115~0.5118) are similar to those of granitic rocks ($^{87}Sr/^{86}Sr$=0.709~0.716 and $^{143}Nd/^{144}Nd$=0.5115~0.5116) from inside granite stock. This means that similar source materials of felsic magma responsibles for the Bupyeong volcanic rocks and inside plutonic rocks. Based on the Nd and Sr isotopic compositions, rhyolitic and granitic magmas in the Bupyeong area originated from the partial melting of the old continental crust which has Nd model age ranging from 1500 to 2900 Ma. This is analogous to those of the other Jurassic granitoids in South Korea.

• 대한자원환경지질학회:학술대회논문집
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• 대한자원환경지질학회 2001년도 춘계 공동학술발표회
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• pp.218-218
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• 2001

• 암석학회지
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• 제2권2호
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• pp.130-138
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• 1993

주로 연대측정이 어려운 변성최적암류로 이루어진 선캠브리아의 경기육괴에 대해 정량적 연대측정 방법을 개발하기 위하여 대리암에 대한 연대측정법의 적용 가능성에 대해 연구하였다. 이 지역의 대리암은 대부분 규산염 광물을 함유하고 있으므로 염산을 사용한 선별용해 실험을 하였다. 미량원소 분석결과 Zr과 Rb은 거의 대부분 잔류물에 함유되어 있으며 U도 염산용해 부분보다는 잔류물에 많이 포함되어 있음을 알 수 있었다. 또한 Pb, Sr, Sm, Nd은 양쪽에 비슷하게 포함되며 Th은 다소 복잡한 양상을 보인다. 선별용해에 의한 Sr 동위원소 분석시에는 Sr 동위원소비가 높은 규산염 광물의 영향을 쉽게 영향을 받기 때문에 많은 주의와 연구가 요구된다. 탄산염 광물로만 구성된 순수한 대리암 시료를 골라 여러 조각으로 나눈 후 각각에 대해 분석된 Pb 동위원소비로부터 연대를 구하는 방법이 Sr 동위원소 분석에 의한 연대측정보다 성공 가능성이 높은 연대측정법으로 판단된다.

• 한국광물학회:학술대회논문집
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• 한국광물학회.한국암석학회 2001년도 공동학술발표회 논문집
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• pp.75-75
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• 2001

We report Sr, Nd and Pb isotope data of clinopyroxene separates from ultramafic xenoliths and their host basaltic rocks in Jeju Island, Baekryeong Island, Boeun and Ganseong, Korea. The isotopic data of the xenoliths and host basalts are distinctly different from those of Korean basement rocks. Except for two xenoliths from Ganseong, all samples in this study have isotopic ratios within the combined range of MORB-OIB data. All basaltic rocks have Nd-Sr-Pb isotope compositions different from those of xenoliths, indicating that the host basaltic magma did not derive from the lithospheric mantle where the xenoliths originated. The range of isotopic composition of xenoliths is much greater than that observed in host basalts, which reflects small-scale heterogeneity of the lithospheric mantle. The greater isotopic heterogeneity of the lithospheric mantle probably reflects its long-term stability. The spinel peridotite xenolith data of Jeju Island, Baekryeong Island and Boeun display mixing hyperbolas between DMM and EM II end members. Since Jeju basalts have EM II-like isotopic signature, the mixing relationship shown by the isotopic data of the Jeju xenoliths can be interpreted as the result of infiltration of metasomatic fluid or melt derived from basaltic magma into DMM-like lithospheric mantle. In contrast to other xenolith sites, the Ganseong xenoliths are dominantly clinopyroxene megacryst and pyroxenite. Clinopyroxene megacrysts have different isotopic ratios from their host basalt, reflecting its exotic origin. Two Ganseong xenoliths (wherlite and clinopyroxenite) have much enriched Sr and Nd isotopic ratios and Nd model ages of 2.5-2.9 Ga, and plot in an array away from the MORB-OIB field. The mantle xenoliths from Korean Peninsula have similar $\^$87/Sr/$\^$86/Sr,$\^$143/Nd/$\^$144/Nd and $\^$207/Pb/$\^$204/Pb ratios to, but higher $\^$208/Pb/$\^$204/Pb ratios than, those from eastern China, indicating that Korean xenoliths are derived from the lithospheric mantle with higher Th/U ratio compared with Chinese ones. The isotopic data of xenolith-bearing basalts of Baekryeong Island and Ganseong, along with Ulreung and Dok Islands, show a mixing trend betlveen DMM and EM I in Sr-Nd-Pb isotopic correlation diagrams, which is also observed in tile northeastern Chinese basalts. However, the Jeju volcanic rocks show an EM II signature that is observed in southeastern Chinese basalts. The isotopic variations in volcanic rocks from the northern and southern portions of the East Asia reflect a large-scale isotopic heterogeneity in their source mantle.