• Applied Chemistry for Engineering
• /
• v.3 no.1
• /
• pp.1-6
• /
• 1992

In this energy and environment conscious age, methanol has come to attention increasingly since the well established process is commercially available to produce methanol from abundant low grade carbonaceous resources ; methane, carbon dioxide, coal and biomass etc. Methanol is a Clean energy source which is a readily storable and transportable liquid. It is elaborated to correlate power generation, city gas and chemical feed stocks including transportation fuel, enhancing the national efficiency of resource utilization as well as reducing the environmental problems for the future via C1 technology. It is emphasized that $CO_2$ could be used to produce methanol as a mean of hydrogen storage as in the nature, which will alleviate the environmental problem such as green house effect.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2001.11b
• /
• pp.21-25
• /
• 2001

In this study, recovery of plasma etching· damage in PZT thin film with additive gas and re-annealing after etching have been investigated. The PZT thin films were etched as a function of $Cl_2/CF_4$ with addition of Ar and $O_2$ with inductively induced plasma. The etch rates of PZT thin films were 1450 $\AA$/min at 30% additive Ar into $(Cl_2(80%)+CF_4 (20%))$ and 1100 $\AA$/min at 10% additive $O_2$ into $C(Cl_2(80%)+CF_4(20%))$. In order to recovery properties of PZT thin films after etching, the etched PZT thin films were re-annealed at various temperatures in at $O_2$ atmosphere. From the hysteresis curves, ferroelectrical properties are improved by $O_2$ re-annealing process. The improvement of ferroelectric behavior at annealed sample is consistent with the increase of the (100) and (200) PZT peaks revealed by x-ray diffraction (XRD). From x-ray photoelectron spectroscopy (XPS) analysis, intensity of Pb-O, Zr-O and Ti-O peak are increased and the chemical residue peak is reduced by $O_2$ re-annealing. The ferroelectric behavior consistent with the dielectric nature of $Ti_xO_y$ is recovered by $O_2$ recombination during rapid thermal annealing process.

• Journal of Korean Society for Atmospheric Environment
• /
• v.6 no.1
• /
• pp.85-96
• /
• 1990

Simultaneous removal efficiencies of hydrophilic and hydrophobic gaseous pollutants are experimentally determined, and the macroscopic removal mechanism of pollutants in a dry scrubber is analyzed using the extended model of three phase equilibrium distribution of pollutant at high temperatures that can describe the different morphological conditions of adsorbent and water at varying relative humidities. For the simplicity, the inside of spray dryer is divided into three regions of ; (1) absorption, (2) three-phase equilibrium, and (3) adsorption, and the removal efficiencies of each pollutants at three regions are observed at different experimental conditions to estimate the effects of important parameters of dry scrubber. The laboratory experiments simulate the three regions of spray dryer with the temperature control and thus evaporation rate of water from the slurry particle. $SO_2$ as a hydrophilic gaseous pollutant and vinyl chloride as a hydrophobic toxic gas are selected for the future field application to soid waste incineration, and the two types of slurry are made of the two sorbents ; 10 wt.% $Ca(OH)_2$, and 10 wt.% NaOH. Result of temperature effect shows the height of absorption plus three-phase region is decreased as the operation temperature is increased, which results in the lower removal efficiency of $SO_2$ but higher removal for vinyl chloride in the adsorption region of dry scrubber. The removal efficiency of $SO_2$ is higher by NaOH slurry than by $Ca(OH)_2$ slurry due to the hygroscopic nature of NaOH, while the removal of vinyl chloride is higher in $Ca(OH)_2$ case. From the analysis of redults using three-phase equilibrium distribution model, the effective two-phase partition coefficients can be obtained, and the possible extention in the application of the three-phase equilibrium model in a dry scrubber design has been demonstrated.

• Archives of Plastic Surgery
• /
• v.35 no.2
• /
• pp.201-204
• /
• 2008

Purpose: Now the CT scanner and PACS program proved to be an excellent instrument for detection and localization of most facial foreign bodies above certain minimum levels of detectability. The severity of injury in penetrating trauma on the face is often underestimated in physical examination. Wood, with its porous consistency and organic nature, provides a good medium for microbial agents. This is a report of our recent experience with wooden foreign bodies in the parotid gland imaged with CT. Methods: A 9-year-old boy was referred for evaluation of possible retained foreign body within his face. One day earlier, he had fallen, face down approximately 1 miter onto ground. He had subsequently undergone an exploration of his right parotido-masseteric area at an outside hospital with repair of a right facial laceration. Enhanced 2 mm axial and coronal CT scans were obtained through the face. Axial and coronal CT images were obtained with a General Electric(Milwaukee, Wis) 9800 CT scanner at 130 kV, 90 mA, with a 2 mm section thickness. Results: We finally decided the linear "gas" attenuation was a foreign body because of its linear configuration, which did not conform to that of an anatomic structure, and on the basis of articles that described a wood foreign body in the orbit as having the appearance of air. We found that wood was hypoattenuating($-464{\pm}27HU$). Conclusion: We recommend this type of software program for CT scanning for any patient with an injury on the face in which a foreign body is suspected.

• 한국신재생에너지학회:학술대회논문집
• /
• 2011.11a
• /
• pp.122.2-122.2
• /
• 2011

Sulfur hexafluoride ($SF_6$), one of the most potent greenhouse gases, is known as a hydrate former and has been studied at the high pressure up to 1.3 GPa with gas mixtures and with aqueous surfactant. Since we regard $SF_6$ as a potential promoter molecule that can stabilize hydrate structure more effectively compare to the other promoters, further investigation is required to verify the stabilizing ability of $SF_6$ in the hydrate structure. However, the insoluble nature of $SF_6$ in water or gases hinders fine scale analyses. This work discusses the data obtained by using molecular dynamics simulations of structure II (sII) clathrate hydrates containing $SF_6$ and $H_2$. The simulations were performed using the TIP4P/Ice model for water molecule and a previously reported $SF_6$ molecular model (optimized at the pure $SF_6$ single phase system (Olivet and Vega, 2007)), and a $H_2$ molecular model (adapted from the THF+$H_2$ hydrate system (Alavi et al., 2006)). The simulations are performed to observe the stability of $SF_6$ and $H_2$ in the sII clathrate hydrate system with varying temperature and pressure conditions and occupancies of $SF_6$ and $H_2$, which cannot be easily tuned experimentally. We observe that stability of H2 enclathrated in the hydrate structure more affected by the occupancy of $SF_6$ molecules and temperature than pressure, which ranges from 1 to 100 bar.

• The Bulletin of The Korean Astronomical Society
• /
• v.36 no.2
• /
• pp.112.2-112.2
• /
• 2011

We carry out a systematic study of HI shells and supershells in the first Galactic quadrant (l = $32^{\circ}$ to $77^{\circ}$, b = $-10^{\circ}$ to $10^{\circ}$) using the "Inner-Galaxy Arecibo L-band Feed Array (I-GALFA)" HI 21-cm survey data. The high-resolution (3.'4) and high sensitivity (0.2 K) of the survey provide us an opportunity to exploit the true nature of the sources detected in previous low-resolution studies and also to detect faint and/or small shells that were not detectable before. Our work is composed of three parts: (1) confirm the objects in the low-resolution (about 30') catalog of Heiles (1979), (2) search for fast-expanding HI shells associated with Galactic supernova remnants (SNRs), and (3) search for new shell structures. Among the 21 Heiles' supershells in the I-GALFA survey area, we confirm fourteen. The high resolution data reveal their complex morphology, and provide direct evidence for expansion in some sources. Among the 39 Galactic SNRs in the survey area, we find five with associated fast expanding HI shells, which is consistent with previous results. A remarkable result from the SNR study is the detection of HI gas at very high negative velocities in the SNR W44 that should be from the approaching part of the HI expanding shell. This is the first time to detect both the approaching and receding sides of an expanding shell in HI 21-cm emission line in SNRs. We have found 33 new shell candidates of angular sizes ranging from 0.5 to 6.5 degrees, half of which appear to be expanding. We summarize these results and discuss some individual interesting objects in detail.

• Journal of the Speleological Society of Korea
• /
• no.95
• /
• pp.15-21
• /
• 2009

Global village warming and carbon dioxide CO2 gas, and the human efforts for their healing and necessary alternative technology would be much more difficult things than that of making necessary funds and efforts to lay to sleep angry nature on the earth. The limited natural resources of fossil fuel would be dried up in several decades, and the intensity of diplomatic negotiations for natural resource guarantee among countries may be showed looking alike an war. The drain of fossil fuel called a new word of alternative policy like an environment-friendly green-growth, and the solar-cell and lighting technology for the solar energy applications were developed still more repeatedly day by day from oil lantern to LED high-tech illumination in great economy. Therefore, it was studied that the low-carbon green-growth illumination technology in cave applications with SOLAR-LED system which was produced and unified in connection with solar-cell and LED from the semiconductor production technology, and it was also clarified in necessary with useful cave lighting in heatless and with no photosynthesis of plant production in underground space.

• Journal of the Korean Chemical Society
• /
• v.62 no.3
• /
• pp.235-242
• /
• 2018

The purpose of this study is to analyze the chemistry curriculum between Korea and New Zealand. Both countries state that they want to cultivate their key competencies through the curriculum, and Korea' key competencies are similar to New Zealand'. Also, we find a strong correlation between key competencies of Korea science and achievement aims of the nature of science in New Zealand. Specially, the achievement standards that cultivate the key competencies are presented separately in New Zealand curriculum and NCEA, and confirms the achievement level through internal evaluation. By comparison, the curriculum content for chemistry is a good fit because of the overlap in the content. The Chemistry I is in the 7th level of New Zealand curriculum and the Chemistry II is in the 7th and 8th levels of New Zealand. However, there are some differences in hydrocarbon, ideal gas equation, colligative property and understanding of spectroscopic data.

• Bulletin of the Korean Chemical Society
• /
• v.30 no.11
• /
• pp.2589-2594
• /
• 2009

Aging phenomena of plasma polymer films were studied by using the surface analysis techniques of contact angle measurement, X-ray photoelectron spectroscopy (XPS), time-of-flight secondary ion mass spectrometry (TOFSIMS), and atomic force microscopy (AFM). The polymer films were grown on an aluminum substrate by using a plasma polymerization method from a gas mixture of acetylene and helium, and the films were subsequently modified to have a hydrophilic surface by oxygen plasma treatment. Aging of the polymer films was examined by exposing the samples to water and air environments. The aging process increased the hydrophobicity of the surface, as revealed by an increase in the advancing contact angle of water. XPS analysis showed that the population of oxygen-containing polar groups increased due to the uptake of oxygen during the aging, whereas TOF-SIMS analysis revealed a decrease in the polar group population in the uppermost surface layer. The results suggest that the change in surface property from hydrophilic to hydrophobic nature results from the restructuring of polymer chains near the surface, rather than compositional change of the surface. Oxidative degradation may enhance the mobility and the restructuring process of polymer chains.

• Korean Journal of Weed Science
• /
• v.14 no.2
• /
• pp.156-162
• /
• 1994

To better understand the exact nature of the major toxic compound responsible for phytotoxicity of sorghum stem, the most toxic compound from the stem extract was isolated by rapid chromatography and subsequently purified by thin-layer chromatography(TLC) and high pressure liquid chromatography(HPLC). Of the eight fractions isolated by rapid chromatography, the fraction with solvent combinations of butanol (8) : acetic acid (1) : water (1) had the highest toxicity. Further separation of the fraction by TLC in a solvent mixture of butanol (24) : acetic acid (16.4) : water (7) : propanol (1) showed that the spot with an $R_f$ 0.71 had one major peak with retention time of 20.40 minutes. Upon subjecting gas chromatography and the HPLC fraction to the mass spectrometry, the toxic compound is probably one of the four compounds ; 1-methyl-1-(2-propynyl)-hydrazine, 1-aziridineethanol, 5-chloro-2-pentanone, and 2-(methylseleno)-ethanamine.