• Bulletin of the Korean Chemical Society
• /
• v.35 no.9
• /
• pp.2758-2764
• /
• 2014

We demonstrated the synthesis of organic carbonates using alkyl/aryl 4,5-dichloro-6-oxopyridazine-1(6H)-carboxylates and alcohol in the presence of aluminum chloride. Alkyl/aryl 4,5-dichloro-6-oxopyridazine-1(6H)-carboxylates were reacted with alcohol in the presence of $AlCl_3$ in toluene at room temperature to afford the corresponding unsymmetric and symmetric organic carbonates in good to excellent yields. These are efficient and convenient processes. Alkyl/aryl 4,5-dichloro-6-oxopyridazine-1(6H)-carboxylates are solid, stable and non-toxic $CO_2/CO_2R$(Ar) source. It is noteworthy that the reaction is carry out under an ambient and acidic conditions, the easy-to prepare and readily available starting materials and the quantitative isolation of reusable 4,5-dichloropyridazin-3(2H)-one.

• Journal of the Mineralogical Society of Korea
• /
• v.22 no.4
• /
• pp.325-330
• /
• 2009

High pressure x-ray diffraction study was performed on a synthetic FeOOH-goethite to check out its compressibility at room temperature. Angular dispersive x-ray diffraction method was employed using a symmetrical diamond anvil cell with synchrotron radiation. Bulk modulus was determined to be 222.8 GPa under assumption of $K_{T'}$ of 4.0. This value is too high comparing with the previously published values from natural samples. It has been discussed the possible causes to incur its high bulk modulus value according to the production conditions.

• Journal of Microbiology and Biotechnology
• /
• v.20 no.2
• /
• pp.254-264
• /
• 2010

To obtain an efficient natural lignocellulolytic complex enzyme, we screened an efficient lignocellulose-degrading composite microbial system (XDC-2) from composted agricultural and animal wastes amended soil following a long-term directed acclimation. Not only could the XDC-2 degrade natural lignocelluloses, but it could also secrete extracellular xylanase efficiently in liquid culture under static conditions at room temperature. The XDC-2 degraded rice straw by 60.3% after fermentation for 15 days. Hemicelluloses were decomposed effectively, whereas the extracellular xylanase activity was dominant with an activity of 8.357 U/ml on day 6 of the fermentation period. The extracellular crude enzyme noticeably hydrolyzed natural lignocelluloses. The optimum temperature and pH for the xylanase activity were $40^{\circ}C$ and 6.0. However, the xylanase was activated in a wide pH range of 3.0-10.0, and retained more than 80% of its activity at $25-35^{\circ}C$ and pH 5.0-8.0 after three days of incubation in liquid culture under static conditions. PCR-DGGE analysis of successive subcultures indicated that the XDC-2 was structurally stable over long-term restricted and directed cultivation. Analysis of the 168 rRNA gene clone library showed that the XDC-2 was mainly composed of mesophilic bacteria related to the genera Clostridium, Bacteroides, Alcaligenes, Pseudomonas, etc. Our results offer a new approach to exploring efficient lignocellulolytic enzymes by constructing a high-performance composite microbial system with synergistic complex enzymes.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.20 no.11
• /
• pp.711-717
• /
• 2008

Despite the fact that UFAD(Under Floor Air Distribution) systems have many benefits and are being applied in the field in increasing numbers, there is a strong need for an improved fundamental understanding of several key performance features of these systems. This study numerically investigates the effect of supplied air temperature and supplied flow rate on the performance of UFAD, especially focused on thermal comfort. Also this study has compared UFAD with conventional overhead air distribution system. In contrast to the well-mixed room air conditions of the conventional overheat system, UFAD system produces an overall floor-to-ceiling airflow pattern that takes advantage of the natural buoyancy produced by heat sources in the occupied zone and more efficiently removes heat loads and contaminants from the space. Thermal comfort parameters were evaluated by CFD approach and then PMV was computed to detect the occupants' thermal sensation. Results show that radiative mean temperature plays crucial role on the evaluating PMV. Until now, the radiative temperature has been the missing link between CFD and thermal comfort, but the present study paves the way for overcoming this weakness.

• Advances in environmental research
• /
• v.2 no.3
• /
• pp.203-227
• /
• 2013

Global demand for dwelling energy and implications of changing climatic conditions on buildings confront the built environment to build sustainable dwellings. This study investigates the variability of future climatic conditions on newly built detached dwellings in the UK. Series of energy modelling and simulations are performed on ten detached houses to evaluate and predict the impact of varying future climatic patterns on five building performance indicators. The study identifies and quantifies a consistent declining trend of building performance which is in consonance with current scientific knowledge of annual temperature change prediction in relations to long term climatic variation. The average percentage decrease for the annual energy consumption was predicted to be 2.80, 6.60 and 10.56 for 2020s, 2050s and 2080s time lines respectively. A similar declining trend in the case of annual natural gas consumption was 4.24, 9.98 and 16.1, and that for building emission rate and heating demand were 2.27, 5.49 and 8.72 and 7.82, 18.43 and 29.46 respectively. The study further analyse future heating and cooling demands of the three warmest months of the year and ascertain future variance in relative humidity and indoor temperature which might necessitate the use of room cooling systems to provide thermal comfort.

• Korean Journal of Fisheries and Aquatic Sciences
• /
• v.39 no.2
• /
• pp.85-93
• /
• 2006

This study was conducted to evaluate the optimal processing conditions of smoke-dried powdered oysters and to determine their shelf-life during storage for development of a natural oyster flavoring substance. The optimal conditions for processing of smoke-dried oyster powder with freshy oyster were as follows. Raw shelled oysters were rinsed with 3% saline solution, drained, boiled for 10 minutes at $98^{\circ}C$, and then smoked for 1 hour at $50^{\circ}C$, followed by drying for 4 hours at $80^{\circ}C$ Smoke-dried oyster powder with oyster scraps were prepared as flavoring material. The smoked oyster scraps were submerged in oyster sauce far 10 minutes at room temperature and then dried with hot air for 5 hours at $50^{\circ}C$. The smoke-dried oysters and smoke-dried oyster scraps were then pulverized to 50 mesh and packed in tea bags or vacuum-packed in laminated plastic film bags (PE/PVDC/CPP, $12{\mu}m/15{\mu}m/50{\mu}m$). Compared to non smoke-dried powdered oysters, the smoking and dipping in oyster sauce enhanced the flavor and prevented lipid oxidation of the smoke-dried powdered oyster product. Shelf-life tests indicated that the vacuum-packaging method preserved the quality of smoke-dried powdered oysters stored for 150 days at room temperature.

• Journal of the Society of Naval Architects of Korea
• /
• v.51 no.6
• /
• pp.495-502
• /
• 2014

Glass-reinforced polyurethane foam (R-PUF) is widely used as the primary and secondary insulation of Mark-III type liquefied natural gas (LNG) cargo system. And, polyurethane foam (PUF) and polyisocyanurate foam (PIR) are often used for insulation of onshore structures or LNG storage and pipeline system. These polymeric foam materials are known for the characteristics that mechanical properties are dependent on strain rate and temperature. In this study, compression tests for R-PUF, PIR, and PUF were carried out for the estimation of mechanical behaviors under the cryogenic environment. The range of thermal condition was from room temperature to 110K and strain rates were $10^{-3}s^{-1}$ and $10^{-4}s^{-1}$. The test results were analyzed based on the conditions of strain-rate and temperature.

• Journal of Soil and Groundwater Environment
• /
• v.20 no.6
• /
• pp.103-110
• /
• 2015

Nitro-aromatic Compounds (NACs) of explosives are structurally non-degradable materials that have an adverse effect to humans and ecosystems in case of emissions in natural due to the strong toxicity. In this study, batch test in the laboratory-scale has been conducted to find some process parameters of alkaline hydrolysis by considering the characteristics of NACs which are unstable in a base status and field application evaluation have been performed on the batch test results. Based on the experimental results of both laboratory and pilot-scale test, the optimum conditions of parameters for the alkaline hydrolysis of soils contaminated with explosives were pH 12.5, above the solid-liquid ratio 1 : 3, above the room temperature and 30 minute reaction time. In these four process parameters, the most important influencing factor was pH, and the condition of above pH 12.0 was necessary for high contaminated soils (more than 60 mg/kg). In the case of above pH 12.5, the efficiency of alkaline hydrolysis was very high regardless of the concentrations of contaminated soils. At pH 11.5, the removal efficiency of TNT was increased from 76.5% to 97.5% when the temperature in reactor was elevated from room temperature to 80℃. This result shows that it is possible to operate the alkaline hydrolysis at even pH 11.5 due to increased reaction rate depending on temperature adjustment. The results found in above experiments will be able to be used in alkaline hydrolysis for process improvement considering the economy.

• Current Optics and Photonics
• /
• v.5 no.4
• /
• pp.458-465
• /
• 2021

Borate nonlinear optical crystals have been used as frequency conversion devices in many fields due to their unique transparency and nonlinearity from ultraviolet to visible spectral range. In this study, we theoretically and numerically investigate the properties of broadband second harmonic generation (SHG) in the recently reported Pna2₁-Ba₃Mg₃(BO₃)₃F₃ (BMBF) crystal. The technique is based on the simultaneous achievement of birefringence phase matching and group velocity matching between interacting waves. We discussed all factors required for broadband SHG in the BMBF in terms of two types of phase matching and group velocity matching conditions, the beam propagation direction and the corresponding effective nonlinearity and spatial walk-off, and the spectral responses. The results show that bandwidths calculated in the broadband SHG scheme are 220.90 nm (for Type I) and 165.85 nm (for Type II) in full-width-half-maximum (FWHM). The central wavelength in each case is 2047.76 nm for Type I and 1828.66 nm for Type II at room temperature. The results were compared with the non-broadband scheme at the telecom C-band.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.29 no.2
• /
• pp.74-81
• /
• 2017

In this study, the combined-type diffuser developed by the Authors, in a previous study, was applied to a residential space. The performance of a ventilation and thermal environment, created by the use of a combined-type diffuser was compared to the pan-type diffuser widely used in apartment houses. In cooling conditions, because of the relatively high air flow rate of ceiling cassette-type air conditioners, the characteristics of airflow distribution in a room were governed by the air conditioner's airflow. In heating conditions, because of the low air flow rate of the diffuser, the characteristics of airflow distribution were governed by the buoyancy effect created by cold external walls and a hot floor. In terms of the Air Diffusion Performance Index (ADPI), which is a thermal environmental index, the result of a combined-type diffuser was greater than a pan-type diffuser in both of cooling and heating conditions. Consequently, the combined-type diffuser showed equal or superior ventilation and thermal environment performance compared to a pan-type diffuser.