• Title/Summary/Keyword: Natural occurring particles

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Dissolved Organic Matter (DOM) Leaching from Microplastics under UV-Irradiation and Its Fluorescence P roperties: Comparison with Natural P articles (UV 광풍화에 의한 미세플라스틱 기원 유기물 용출과 형광 특성: 자연유래 유기성 입자와의 비교)

  • Choi, Na Eun;Lee, Yun Kyung;Hur, Jin
    • Journal of Korean Society on Water Environment
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    • v.38 no.2
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    • pp.72-81
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    • 2022
  • Numerous studies have investigated the occurrence and fate of microplastics in the environment; however, only limited effort has been devoted to exploring the characteristics of dissolved organic matter (DOM) leached from microplastics. In microplastic (MP)-contaminated environment, MPs are typically mixed with naturally-occurring particles, which interferes with their detection in the environment. Thus, it is necessary to distinguish between the DOM leached from MPs and those leached from natural particles and also to characterize their properties. This study investigated DOM leaching behavior from MPs (polystyrene: PS, polyvinylchloride: PVC) and natural particulates (forest soil: FS, litter leaves: LL) under light, which is considered one of the main weathering processes that affect MPs in the environment. The leached DOM concentrations and fluorescence characteristics were compared under dark versus light conditions. Regardless of the origins, UV light promoted DOM release from all the particulates. More DOM was released from natural particles than from MPs under both conditions. However, the effect of promoting DOM release by UV was more pronounced for MPs than for natural particles. It was observed from fluorescence spectra that the intensity of the humic-like region was substantially reduced when MP-derived DOM was exposed to UV light, whereas the change of intensity was very little for natural particles. Under light conditions, the ratio of protein-like to humic-like fluorescence of MP-derived DOM was higher than that of DOM from natural particles. This study implies that a substantial amount of DOM could be leached from MPs even in MP-polluted environment under UV irradiation. Protein/humic fluorescence ratio could be utilized as a fast probing indicator to separate the two sources of particles under light.

Use of a Combined Photocatalysis/Microfiltration System for Natural Organic Matter Removal (광촉매 반응과 침지형 정밀여과를 이용한 자연산 유기물의 제거)

  • 추광호;박경원;김문현
    • Membrane Journal
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    • v.14 no.2
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    • pp.149-156
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    • 2004
  • This work focused on the degradation of natural organic matter (NOM) present in lake water using a combined pkotocatalysisimicrofiltration (MF) process. The system performances were investigated in terms of organic removal efficiency and membrane permeability. The addition of iron oxide particles (IOP) into the photocatalytic membrane reactor improved initial NOM removal by sorption, but during photocatalysis the removal efficiency was reversed, probably due to the scattering of UV light by IOP. The modification of TiO$_2$ surfaces by IOP deposition was conducted to enhance the photocatalytic NOM removal efficiency. A minimal amount of Impregnation of IOP on TiO$_2$ surfaces was required to prevent the light scattering effect as well. The coating of MF membranes with IOP helped to improve the NOM removal efficiency while sorbing NOM by IOP. Regardless of tile operating conditions and particles addition examined, no significant fouling was occurring at a flux of 15 L/$m^2$-h during entire MF operation.

Natural Iminosugar Derivatives of 1-Deoxynojirimycin Inhibit Glycosylation of Hepatitis Viral Envelope Proteins

  • Jacob, James R.;Mansfield, Keith;You, Jung-Eun;Tennant, Bud C.;Kim, Young-Ho
    • Journal of Microbiology
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    • v.45 no.5
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    • pp.431-440
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    • 2007
  • A silkworm (Bombyx mori L.) extract known to contain naturally occurring iminosugars, including 1-deoxynojirimycin (1-DNJ) derived from the mulberry tree (Morus alba L.), was evaluated in surrogate HCV and HBV in vitro assays. Antiviral activity of the silkworm extract and one of its purified constituents, 1-DNJ, was demonstrated against bovine viral diarrhea virus (BVDV) and GB virus-B (GBV-B), both members of the Flaviviridae family, and against woodchuck hepatitis virus (WHV) and hepatitis B virus (HBV), both members of the Hepadnaviridae family of viruses. The silkworm extract exhibited a 1,300 fold greater antiviral effect against BVDV in comparison to purified 1-DNJ. Glycoprotein processing of BVDV envelope proteins was disrupted upon treatment with the naturally derived components. The glycosylation of the WHV envelope proteins was affected largely by treatment with the silkworm extract than with purified 1-DNJ as well. The mechanism of action for this therapy may lie in the generation of defective particles that are unable to initiate the next cycle of infection as demonstrated by inhibition of GBV-B in vitro. We postulate that the five constituent iminosugars present in the silkworm extract contribute, in a synergistic manner, toward the antiviral effects observed for the inhibition of intact maturation of hepatitis viral particles and may complement conventional therapies. These results indicate that pre-clinical testing of the natural silkworm extract with regards to the efficacy of treatment against viral hepatitis infections can be evaluated in the respective animal models, in preparation for clinical trials in humans.

Morphological Diversity of Tremolite-actinolite Series Amphiboles with Implications to the Evaluation of Naturally Occurring Asbestos (투각섬석-양기석 계열 각섬석의 형태적 다양성과 자연 석면 평가에서의 의미)

  • Jeong, Gi-Young;Choi, Jin-Beom
    • Journal of the Mineralogical Society of Korea
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    • v.25 no.2
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    • pp.95-104
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    • 2012
  • Electron microscopy of the tremolite-actinolite series amphiboles from the naturally occurring asbestos locality showed the morphological diversity including fibrous, acicular, and prismatic. Very thin, long, and flexible fibers of constant width form ropy bundles or mats. Acicular particles are slightly thick, long, elastic, and easily separated from the bundle of parallel rods. Acicular fragments of lower aspect ratio are formed during the crushing of the amphibole prism. Morphological features of the amphiboles are different depending on their localities and vary in a specimen. Morphological continuum between amphibole fiber and prism requires the establishment of reliable identification criterions and sample preparation protocol based on the relation between carcinogenicity and morphological features.

Stability Evaluation on Particle Size Characteristics of Bed Materials at High-Velocity Flow (고유속 흐름에서 하상재료의 입도특성에 따른 안정성 평가연구)

  • Kim, Gwang Soo;Jung, Dong Gyu;Kim, Young Do;Park, Yong Sung
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.41 no.4
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    • pp.365-376
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    • 2021
  • In general, domestic streams and rivers are composed of alluvial rivers consisting of sand and gravel beds. These rivers can cause erosion and riverbed changes due to sudden changes in flow rates, such as floods, torrential rains, and heavy rains. In particular, there are various types of erosion, such as contraction erosion caused by changes in river shape, or local erosion occurring around obstacles such as piers, abutments or embankments. In addition, river changes can occur in various forms, such as static or dynamic periods, due to limitations such as flow rate, velocity, and shear stress. This study focused on the erosions of embankments directly related to human casualties among various river structures, and evaluated limit velocities and critical shear stress in order to identify changes in strength of natural materials by identifying the characteristics of natural hoan materials and resistance to erosions. In particular, the limitations of materials according to the type of materials in the river, characteristics of particles, and size of particles were studied using Soil loss, which is a change in the volume of the revetment material, and it is intended to be used as basic data for river design and restoration.

Asbestiform Tremolite Formed by Chert-Dolomite Reaction and Its Morphological Characteristics (처트-백운석 반응에 의한 석면상 투각섬석의 생성과 형태적 특성)

  • Jeong, Gi Young;Choi, Jin Beom
    • Journal of the Mineralogical Society of Korea
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    • v.26 no.2
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    • pp.111-118
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    • 2013
  • Diagenetic black chert nodules occur in the Paleozoic dolostone in Susan, Jecheon, Korea. They reacted with dolomite to form alteration rim around the nodules during the contact metamorphism probably related to the intrusion of biotite granite. In the earlier stage of alteration, talc and calcite replaced both the chert and dolomite, which were subsequently replaced by tremolite. Significant mass of tremolite occurs along the horizon enriched with chert nodules. Scanning electron microscopy and optical microscopy of the tremolite specimens revealed the elongated morphology of diverse aspect ratios coexisting in several mm scale. Non-asbestiform tremolite columns were also common as well as asbestiform fibrous bundles. Quantitative estimation of asbestos should be more cautious for naturally occurring materials because all the tremolite particles in the outcrop are not asbestiform. The occurrence of asbestiform tremolite in the Susan area indicates that a combination of chert-bearing dolostone, heat source, and aqueous fluids is one of the geological environments for the formation of asbestiform tremolite.

Characterization of Particulates Containing Naturally Occurring Radioactive Materials in Phosphate Processing Facility (인광석 취급 산업체에서 발생하는 천연방사성물질 함유 입자의 특성 평가)

  • Lim, HaYan;Choi, Won Chul;Kim, Kwang Pyo
    • Journal of Radiation Protection and Research
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    • v.39 no.1
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    • pp.7-13
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    • 2014
  • Phosphate rock, phosphogypsum, and products in phosphate processing facility contain naturally occurring radioactive materials (NORM). Therefore, they may give rise to enhanced radiation dose to workers due to inhalation of airborne particulates. Internal dose due to particle inhalation varies depending on particle properties. The objective of the present study was to characterize particle properties at the largest phosphate processing facility in Korea. A cascade impactor was employed to sample airborne particulates at various processing areas in the plant. The collected samples were used for characterization of particle size distribution, particle concentration in the air, and shape analysis. Aerodynamic diameters of airborne particulates ranged 0.03-100 ${\mu}m$ with the highest concentration at the particle size range of 4.7-5.8 ${\mu}m$ (geometric mean = 5.22 ${\mu}m$) or 5.8-9.0 ${\mu}m$ (geometric mean = 7.22 ${\mu}m$). Particle concentrations in the air varied widely by sampling area up to more than two orders of magnitude. The large variation resulted from the variability of mechanical operations and building ventilations. The airborne particulates appeared as spheroids or rough spherical fragments across all sampling areas and sampled size intervals. Average mass densities of phosphate rocks, phosphogypsums, and fertilizers were 3.1-3.4, 2.1-2.6, and 1.7 $gcm^{-3}$, respectively. Radioactivity concentration of uranium series in phosphate rocks varied with country of origin, ranging 94-866 $Bqkg^{-1}$. Among the uranium series, uranium was mostly concentrated on products, including phosphoric acid or fertilizers whereas radium was concentrated on byproducts or phosphogypsum. No significant radioactivity of $^{226}Ra$ and $^{228}Ra$ were found in fertilizer. However, $^{40}K$ concentration in fertilizer was up to 5,000 Bq $g^{-1}$. The database established in this study can be used for the accurate risk assessment of workers due to inhalation of airborne particles containing NORM. In addition, the findings can be used as a basic data for development of safety standard and guide and for practical radiation safety management at the facility.

Biology and Health Aspects of Molds in Foods and the Environment

  • Bullerman, Lloyd-B.
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.22 no.3
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    • pp.359-366
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    • 1993
  • Molds are eucaryotic, multicellular, multinucleate, filamentous organisms that reproduce by forming asexual and sexual spores. The spores are readily spread through the air and because they are very light-weight and tend to behave like dust particles, they are easily disseminated on air currents. Molds therefore are ubiquitous organisms that are found everywhere, throughout the environment. The natural habitat of most molds is the soil where they grow on and break down decaying vegetable matter. Thus, where there is decaying organic matter in an area, there are often high numbers of mold spores in the atmosphere of the environment. Molds are common contaminants of plant materials, including grains and seeds, and therefore readily contaminate human foods and animal feeds. Molds can tolerate relatively harsh environments and adapt to more severe stresses than most microorganisms. They require less available moisture for growth than bacteria and yeasts and can grow on substrates containing concentrations of sugar or salt that bacteria can not tolerate. Most molds are highly aerobic, requiring oxygen for growth. Molds grow over a wide temperature range, but few can grow at extremely high temperatures. Molds have simple nutritional requirements, requiring primarily a source of carbon and simple organic nitrogen. Because of this, molds can grow on many foods and feed materials and cause spoilage and deterioration. Some molds ran produce toxic substances known as mycotoxins, which are toxic to humans and animals. Mold growth in foods can be controlled by manipulating factors such as atmosphere, moisture content, water activity, relative humidity and temperature. The presence of other microorganisms tends to restrict mold growth, especially if conditions are favorable for growth of bacteria or yeasts. Certain chemicals in the substrate may also inhibit mold growth. These may be naturally occurring or added for the purpose of preservation. Only a relatively few of the approximately 100,000 different species of fungi are involved in the deterioration of food and agricultural commodities and production of mycotoxins. Deteriorative and toxic mold species are found primarily in the genera Aspergillus, Penicillium, Fusarium, Alternaria, Trichothecium, Trichoderma, Rhizopus, Mucor and Cladosporium. While many molds can be observed as surface growth on foods, they also often occur as internal contaminants of nuts, seeds and grains. Mold deterioration of foods and agricultural commodities is a serious problem world-wide. However, molds also pose hazards to human and animal health in the form of mycotoxins, as infectious agents and as respiratory irritants and allergens. Thus, molds are involved in a number of human and animal diseases with serious implication for health.

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