• 대한지하수환경학회지
• /
• 제5권4호
• /
• pp.203-209
• /
• 1998

The quality of groundwater used for natural mineral water should be strictly regulated on international level by hydrogeology experts and officials because groundwater is greatly subjected to contaminations and its aquifer system may be easily destroyed by external reasons. A total of 18 natural mineral water plants exist in Precambrian metamorphic terrains of the Gyunggi massif and Yeungam massif. The g개undwater quality for the natural mineral water investigated in hydrochemical aspects shows that pH ranges from 6.85 to 8.02 with an average of 7.52. The electric conductivity (EC) and hardness average 134.1 $\mu$S/cm and 43.5, respectively, which are relatively low to the total average (151.4 $\mu$S/cm and 57.9). The contents of major cations and anions are in the order of $Ca^{2＋}$＞$Na^{＋}$＞Mg$^{2＋}$＞K$^{＋}$ and HCO$_3$$^{-}$ ＞SO$_4$$^{2－}$ ＞Cl$^{-}$ ＞F$^{-}$ , respectively. The dominant water types determined by Piper diagram are $Ca^{2＋}$－$Na^{＋}$－HCO$^{-}$ $_3$and $Ca^{2＋}$-HCO$^{-}$ $_3$, mainly due to the dissolution of plagioclase in the host rocks. Representative correlation coefficients between chemical species are $Ca^{2＋}$－HCO$^{-}$ $_3$(0.92), $Ca^{2＋}$－Cl$^{-}$ (0.63), $Na^{＋}$－F$^{-}$ (0.67), HCO$^{-}$ $_3$－Cl$^{-}$ (0.66), and $Na^{＋}$－HCO$^{-}$ $_3$(0.63). The determinative. coefficients between $Ca^{2＋}$ and HCO$^{-}$ $_3$, and (Ca$^{2＋}$＋$Na^{＋}$＋K$^{＋}$ and EC art highest among the elements. According to the saturation index, most chemical species are undersaturated with respect to major minerals, except for some silica phases. In viewpoint of phase equilibrium, the chemical evolution of the groundwater may continue to proceed with increasing pH because the groundwater is undersaturated with respect to feldspars.

• 한국지하수토양환경학회지:지하수토양환경
• /
• 제20권4호
• /
• pp.31-40
• /
• 2015

Various types of inorganic and organic colloids are present in natural water including groundwater. Previous studies showed that Fe, Mn and Al are colloid-forming elements and dissolved concentrations can be erroneous for these elements if water samples are not properly filtered. Dissolved concentrations of elements including Ca, Na, Mg, K, Fe, Mn, Si and Al in groundwater from alluvial and bedrock aquifers, and surface water near Nakdong River were determined to evaluate effects of colloids on dissolved concentrations in natural water samples using various pore sizes of filters. Groundwater is mostly anoxic and have elevated concentrations of Fe and Mn, which provides a unique opportunity to observe the effects of colloids on dissolved concentrations of colloid-forming elements. Membrane filters with four kinds of pore sizes of 1000 nm, 450 nm, 100 nm, and 15 nm were used for filtration of water samples. Concentrations of dissolved concentrations in each filtrate did not show significant differences from 1000 nm to 100 nm. However, concentrations of all elements considered were decreased in the filtrates obtained using 15 nm pore size filters by 10 to 15% compared to those using 450 nm except for bedrock groundwater. Al in surface water showed a distinct linear decrease with the decrease of filter pore sizes. These results showed that 100 nm pore size had little effect to remove colloidal particles in alluvial groundwater and surface water in our study. In contrast, significant concentration decreases in 15 nm pore size filtrates indicate that the presence of 15 to 100 nm colloidal particles may affect determination of dissolved concentrations of elements in natural water.

• 한국작물학회지
• /
• 제44권2호
• /
• pp.129-133
• /
• 1999

Excessive soil water at vegetative growth stages during the rainy season induces yield losses in soybeans. Our objectives were to obtain basic information about the cultivar differences and to understand the stress-tolerance process for due to excessive soil water. Previous experiments revealed soybean genotypic differences in tolerance to excessive soil water. A field experiment was conducted at the Research Farm of Korea University near Seoul on 21 May 1998. Soybean[Glycine max (L.) Merrill] cultivars, 'Hannamkong' (sensitive) and 'Taekwan-gkong'(tolerant) were planted in vinyl-lined plots(1.2 x 4.2 x 0.3 m deep) and control plots. Drip irrigation began at VI growth stage to submerge the soil surface. Three weeks of excessive soil water treatment reduced all growth parameters measured to soybean plants. Excessive soil water stress resulted in decreases of N, P, K, Ca, Mg and Cu, and increases of Fe and Mn contents in soybean leaves. The stress index of tolerant cultivars under excessive soil water showed no large difference in soybean growth characteristics measured at three growth stages. However, K, Ca, Mg, Fe and Mn contents in soybean leaves appeared to differ between sensitive and tolerant cultivars. From the above results, stress and tolerance indices are proposed for a method to test cultivar differences in plant responses within a species under adverse growth environments.

• 한국수자원학회논문집
• /
• 제53권spc1호
• /
• pp.827-832
• /
• 2020

본 연구에서는 천연 광천수 병입 회사인 에비앙의 유역관리 경험을 검토하였다. 에비앙은 전 세계로 수출하는 프랑스의 선도적 병입 광천수 기업으로, 장기간의 지속가능한 천연광천수 수원관리 경험이 많은 나라의 롤모델이 되고 있다. 프랑스 생수 회사의 경험에 따르면 환경 문제를 해결하기 위해 선제적이고 선진적인 아이디어를 끊임없이 제시하고 있다. 사업의 지속 가능성을 위해 기업은 효과적이고 계획된 자원 관리를 통해 환경성과를 개선하는 데 전념한다. 에비앙은 수자원을 개발·보존하고 지속 가능한 산업 기능에 대한 목표를 완수하기 위해 공동 소유 정신으로 지역 사회와 협력해 오고 있다. 이 파트너십은 천연광천수 자원 보호와 유역 내 지속가능한 농업 개발의 균형을 맞추는 것을 가장 중요한 목표로 삼고 있다.

• 환경위생공학
• /
• 제22권3호
• /
• pp.35-50
• /
• 2007

In order to investigate water pollution of spring, we carried out the experiments on mineral water, rainwater and surrounding soil of several springs collected in Incheon area from February to August in 2007. The results were as follows. 1. Soil : This study investigated the pH and organic matter contents in the soil which effect on microorganisms. The pH value was from 4.5 to 5.3 on average and organic matter contents ranged from 1.09% to 5.6% and E. coli, K. pneumoniae, S. faecalis and other microorganisms were isolated. 2. Natural mineral water : As the rainfall increased, the concentration of $No_3-N$, consumption of $KMnO_4$ and the number of microorganisms was increased while the other physicochemical items were not affected. The microorganism isolated in the natural mineral water were as follows: E. coli, K. oxytoca S. faecalis, S. facium, and so on from evacuation; E. agglomerans, E. amnigenus, E. cloacae, E. sakazakii and so on from the environments and evacuation. Detection of these microorganisms shows that the environment around the spring had been exposed to excrements of the warm blood animal. 3. Rain : The coliforms in the rain were the identical one detected from the mineral water and the soil. In conclusion the quality of natural mineral water is influenced by rain, resident bacteria of soil and surrounding environment. This study will be the basic data of characteristics of spring in Incheon area and also this result will give useful aids for the efficient control of spring.

• 에너지공학
• /
• 제27권2호
• /
• pp.70-80
• /
• 2018

Natural organic matter (NOM) is among the most common pollutant in underground and surface waters. It comprises of humic substances which contains anionic macromolecules such as aliphatic and aromatic compounds of a wide range of molecular weights along with carboxylic, phenolic functional groups. Although the concentration of NOM in potable water usually lies in the range of 1-10 ppm. Conventional treatment technologies are facing challenge in removing NOM effectively. The main issues are concentrated to low efficiency, membrane fouling, and harmful by-product formation. Ion-exchangers can be considered as an efficient and economic pretreatment technology for the removal of NOM. It not only consumes less time for pretreatment but also resist formation of trihalomethanes (THMs), an unwanted harmful by-product. This article provides a comprehensive review of ion exchange processes for the removal of NOM.

• 분석과학
• /
• 제8권4호
• /
• pp.759-770
• /
• 1995

By extensive studies with the quantitative status of the mineral constituents of thousands of water samples, it was found that almost in all natural waters irrespective of the surface or sub-surface sources, minimum 99.5% of the total amount of the cationic constituents are generally the contributions of 3 commonly present parameters viz. Ca, Mg and Na and that of the anionic species are same and contributed by $HCO_3$, Cl and $SO_4$ only. In the field of water works, all these major mineral substances are conventionally measured as their individual ions. But till now, no reliable and generalised methods or rules have been developed for the determination of the exact kinds of the individual salt components and their amounts from these ionic constituents normally present in water. As salt content, only the TDS (Total Dissolved Solids) parameter is frequently measured by evaporation of the water sample. But TDS can tell nothing about the kinds and amounts of the individual salts present in it. Considering the analytical importance of the estimation of the mineral substances as their individual salts, some generalised mathematical models have been developed by this research which are based on the 'hypothetical order of chemical combinations' as may occur among the ionic constituents. With the help of these models, one can easily assume the most probable salts with approximate quantities derived from the ionic constituents. In addition, approximate amount of Na content can also be estimated mathematically with simultaneous verification of the correctness of the water analysis results. The models are stated in this paper with practical illustrations and descriptions of the method of applications.

• 자원환경지질
• /
• 제43권1호
• /
• pp.33-42
• /
• 2010

마을상수도 지하수의 라돈의 자연저감 정도를 파악하기 위하여 6개 지점을 대상으로 지하수공의 제원, 저수조의 크기, 지하수 사용량, 원수로부터 꼭지수까지의 거리를 측정하고 원수와 3개 꼭지수의 라돈함량을 분석하고 비교하였다. 5개 마을상수도 지하수(A-E)에서 2회에 걸친 원수와 꼭지수의 라돈 자연저감은 2006년 11월에는 26.0%, 2006년 12월에는 45.6%로 나타나 계절별 지하수 사용량에 따른 자연저감율에 차이가 있는 것으로 나타났다. 그러나 마을상수도 F에서 2007년 4월 일주일 간격으로 3회 분석된 꼭지수의 라돈함량은 원수의 44.1-49.0%로 나타나 단기간에 걸친 라돈 자연저감에는 큰 변화가 없는 것으로 나타났다. 한편 꼭지수에서의 라돈의 저감은 원수로부터의 거리, 저수조의 크기보다는 지하수의 사용량에 더 영향을 받는 것으로 나타났다.

• 한국지하수토양환경학회지:지하수토양환경
• /
• 제24권3호
• /
• pp.24-35
• /
• 2019

It is known that ${\delta}^{13}C_{DIC}$ (carbon-13 isotope of dissolved inorganic carbonate (DIC) ions) of water increases when dissolved $CO_2$ degases. However, ${\delta}^{13}C_{DIC}$ could decrease when the pH of water is lower than 5.5 at the early stage of degassing. Laboratory experiments were performed to observe the changes of ${\delta}^{13}C_{DIC}$ as $CO_2$ degassed from three different artificial $CO_2$-rich waters (ACWs) in which the initial pH was 4.9, 5.4, and 6.4, respectively. The pH, alkalinity and ${\delta}^{13}C_{DIC}$ were measured until 240 hours after degassing began and those data were compared with kinetic isotope fractionation calculations. Furthermore, same experiment was conducted with the natural $CO_2$-rich water (pH 4.9) from Daepyeong, Sejong City. As a result of experiments, we could observe the decrease of DIC and increase of pH as the degassing progressed. ACW with an initial pH of 6.4, ${\delta}^{13}C_{DIC}$ kept increasing but, in cases where the initial pH was lower than 5.5, ${\delta}^{13}C_{DIC}$ decreased until 6 hours. After 6 hours ${\delta}^{13}C_{DIC}$ increased within all cases because the $CO_2$ degassing caused pH increase and subsequently the ratio of $HCO_3{^-}$ in solution. In the early stage of $CO_2$ degassing, the laboratory measurements were well matched with the calculations, but after about 48 hours, the experiment results were deviated from the calculations, probably due to the equilibrium interaction with the atmosphere and precipitation of carbonates. The result of this study may be not applicable to all natural environments because the pressure and $CO_2$ concentration in headspace of reaction vessels was not maintained constant as well as the temperature. Nevertheless, this study provides fundamental knowledge on the ${\delta}^{13}C_{DIC}$ evolution during $CO_2$ degassing, and therefore it can be utilized in the studies about carbonated water with low pH and the monitoring of geologic carbon sequestration.

• 한국안전학회지
• /
• 제16권1호
• /
• pp.65-72
• /
• 2001

Portland cement concrete is made with coarse aggregate, fine aggregate, portland cement, water and, in some cases, selected chemical admixture such as air-entraining agents, water reducer, superplasticizer, and so on, and mineral admixture such as fly ash, silica fume, slags, etc. Typically, in the concrete, the coarse aggregate and fine aggregate will occupy approximately 80 percent of the total volume of the finished mixture. Therefore, the coarse and fine aggregates affect to the properties of the portland cement concrete. As the deposits of natural sands have slowly been depleted, it has become necessary and economical to produce crushed sand(manufactured fine aggregate). It is reported that crushed sand differs from natural sands in gradation, particle shape and texture, and that the content of micro fines in the crushed sand affect to the quality of the portland cement concrete. Therefore, the purpose of this paper is to investigate the characteristics of fresh and hardened concrete with higher micro fines. This study provides a firm data to apply crushed sand with higher micro fines.