• 한국전산유체공학회:학술대회논문집
• /
• 2011.05a
• /
• pp.112-116
• /
• 2011

In this paper, a preconverter of MCFC for an emergence electric power supplier is numerically simulated to increase the hydrogen production from natural gas (methane). Commercial code is used to simulated the porous catalyst with user subroutine to model three dominant chemical reactions which are Stream Reforming(SR), Water-Gas Shift(WGS), and Direct Stram Reforming(DSR). To get 10% fuel conversion rate in preconverter. the required external heat flux is supplied from outer wall of preconverter. The calculated results show that very nonuniform temperature distribution and chemical reaction happen near the wall of preconverter. These phenomena can be explained by the low heat conductivity of porous catalyst and the endothermic reforming reaction.

• Journal of Hydrogen and New Energy
• /
• v.15 no.1
• /
• pp.54-61
• /
• 2004

Temperature characteristics in a stack of molten carbonate fuel cell (MCFC) have been investigated with simulation based on the computational fluid dynamics (CFD) codes and experimental way. The MCFC has generally two stack structures when the natural gas is used as fuel; one is the external reforming type and the other is internal reforming type. Computer simulation at the external reforming stack suggests that the maximum temperature in the stack depends on the gas flow length. The 2 kW MCFC stack with 25 cm gas flow length showed about $675^\circ{C}$ of maximum temperature.

• Journal of the Korean Society of Combustion
• /
• v.15 no.3
• /
• pp.8-14
• /
• 2010

Fuel processing systems which convert fuel into rich gas (such as stream reforming, partial oxidation, autothermal reforming) need high temperature environment ($600{\sim}1,000^{\circ}$). Generally, anode-off gas or mixture of anode-off gas and LNG is used as input gas of fuel reformer. In order to make efficient and low emission burner system for fuel reformer, it is necessary to elucidate the combustion and emission characteristic of fuel reformer burner. The purpose of this study is to develop a porous premixed flat ceramic burner that can be used for 1~5 kW fuel cell reformer. Ceramic burner experiments using natural gas, hydrogen gas, anode off gas, mixture of natural gas & anode off gas were carried out respectively to investigate the flame characteristics by heating capacity and equivalence ratio. Results show that the stable flat flames can be established for natural gas, hydrogen gas, anode off gas and mixture of natural gas & anode off gas as reformer fuel in the porous ceramic burner. For all of fuels, their burning velocities become smaller as the equivalence ratio goes to the lean mixture ratio, and a lift-off occurs at lean limit. Flame length in hydrogen and anode off gas became longer with increasing the heat capacity. In particular, the blue surface flame is found to be very stable at a very lean equivalence ratio at heat capacity and different fuels. The exhausted NOx and CO measurement shows that the blue surface flame represents the lowest NOx and CO emissions since it remains very stable at a lean equivalence ratio.

• 한국신재생에너지학회:학술대회논문집
• /
• 2009.06a
• /
• pp.888-888
• /
• 2009

A simulation study on SCR (Steam Carbon dioxide Reforming) process in gas-to-liquid (natural gas to Fischer-Tropsch synthetic fuel) process was carried out in order to find optimum reaction conditions for GTL (gas-to-liquid) process reaction. Optimum SCR operating conditions for synthesis gas to FT (Fischer-Tropsch) process were determined by changing reaction variables such as feed temperature and pressure. During the simulation, overall synthesis process was assumed to proceed under steady-state conditions. It was also assumed that physical properties of reaction medium were governed by RKS (Redlich-Kwong-Soave) equation. SCR process was considered as reaction models for synthesis gas in GTL proess. The effect of temperature and pressure on SCR process $H_2$/CO ratio and the effect of reaction pressure on SCR reaction were mainly examined. Simulation results were also compared to experimental results to confirm the reliability of simulation model. Simulation results were reasonably well matched with experimental results.

• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• 2011.11a
• /
• pp.717-720
• /
• 2011

Due to the depletion of fossil fuel, high oil price and global warming issue by green house gas such as CO2, clean synthetic fuel technologies using biomass, especially GTL(Gas To Liquid) technology, have been greatly attracted. This paper has examined and compared the worldwide technologies trend of natural gas reforming reaction, F-T(Fisher-Tropsch) synthesis and upgrading process which are three backbones of GTL technology.

• Journal of Hydrogen and New Energy
• /
• v.23 no.1
• /
• pp.73-82
• /
• 2012

A 2-dimensional heterogeneous reactor model was developed and simulated for a tube reactor of packed bed where the steam-$CO_2$ combined reforming reaction of natural gas proceeded to produce synthesis gas. Under the reactor feeding rate, 45 $Nm^3$/h, of the reactant gas stream, the 2-dimensional heterogeneous reactor model showed the similar results to those from the ASPEN simulator although there were some discrepancies between the two in the temperature and the $H_2$/CO ratio of the reformed gas at the reactor exit. The calculated enthalpy difference between the reformed gas at the reactor exit and the reactant gas fed to the reactor was closely correspondent to the total amount of heat transferred to the reactor interior from the furnace. This supports that the 2-dimensional heterogeneous reactor model was reasonably established and the numerical solution was properly obtained.

• Journal of Hydrogen and New Energy
• /
• v.26 no.5
• /
• pp.445-452
• /
• 2015

A tubular packed bed reactor for the steam-$CO_2$ combined reforming of natural gas to produce the synthesis gas of a target $H_2/CO$ ratio 2.0 was simulated. The effects of the reactor dimension, the feed gas composition, and the gas feeding temperature upon the possibility of coke formation across the catalyst bed were investigated. For this purpose, 2-dimensional heterogeneous reactor model was used to determine the local gas concentrations and temperatures over the catalyst bed. The thermodynamic potential distribution of coke formation was determined by comparing the extent of reaction with the equilibrium constant given by the reaction, $CH_4+2CO{\Leftrightarrow}3C+2H_2O$. The simulation showed that catalysts packed in the central region nearer the entrance of the reactor were more prone to coking because of the regional characteristics of lower temperature, lower concentration of $H_2O$, and higher concentration of CO. With the higher feeding temperature, the feed gas composition of the increased $H_2O$ and correspondingly decreased $CO_2$, or the decrease in the reactor diameter, the volume fraction of the catalyst bed subsequent to coking could be diminished. Throughout the simulation, reactor dimension and reaction condition for coking-free operation were suggested.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.30 no.9 s.252
• /
• pp.850-857
• /
• 2006

Hydrogen production using current fueling facilities is essential for near-term applications of fuel cells. A preliminary process for developing a natural gas autothermal reforming (ATR) reactor for fuel cells is presented in this paper. A experimental reactor for methane ATR was constructed and used for characterization of Jin reactor. Temperature profiles of the reactor were observed, and reformed gas compositions were analyzed to evaluate efficiency, conversion and reaction heat with varying amounts of $O_2/CH_4$ at selected furnace temperature and $H_2O/CH_4$. The amount of $O_2/CH_4$ showed strong offsets on reactor temperature, efficiency and conversion indicating that $O_2/CH_4$ is a crucial operation condition. Operation conditions which result in thermal neutrality of ATR reactor system were determined for two cases of an ATR system based on the estimation of enthalpy difference between reactants of assumed inlet temperatures and the products from experimental results. The determined conditions for thermally neutral operations could be used for guidelines to design reformers and for determining the operation parameters of a self sustaining ATR reactor.

• 한국신재생에너지학회:학술대회논문집
• /
• 2011.11a
• /
• pp.136.2-136.2
• /
• 2011

A dynamic simulation study on SCR process in GTL process was carried out in order to find optimum operation conditions for pilot plant operation. Optimum operating conditions for SCR synthesis gas process were determined by changing operation variables such as feed temperature and pressure. It was also assumed that physical properties of reaction medium were governed by RKS (Redlich-Kwong-Soave) equation. The effect of temperature and pressure on synthesis gas process $H_2$/CO ratio were mainly examined. Dynamic simulation results were fed back to feed operation condition for optimizing productivity, especially for appropriate condition to FT (Fischer-Tropsch) synthesis unit.

• Journal of Institute of Convergence Technology
• /
• v.12 no.1
• /
• pp.19-23
• /
• 2022

Interest in hydrogen production to respond to climate change is increasing. Until now, hydrogen has been mainly produced through the SMR (Steam Methane Reforming) process using natural gas. A large amount of CO₂ is emitted in the hydrogen production process through SMR, and the gas flow including CO₂ generated in the SMR process has different characteristics for each emission source, so it is important to apply a suitable CO₂ capture process. In the case of PSA tail gas or synthesis gas, the applicability of an amine-based process has been confirmed or demonstrated close to a commercial level. However, in the case of the flue gas generated from the reformer, it is still difficult to apply the conventional amine-based process because the partial pressure of CO₂ is relatively low. Energy-saving innovative absorbents such as phase separation absorbents can be a solution to these difficulties.