• Proceedings of the Korean Geotechical Society Conference
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• 2002.03a
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• pp.343-346
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• 2002

The chemical compatibility of leachate with the two natural materials was analyzed by performing the hydraulic conductivity test. The selected liner materials were natural marine clay and weathered soil sampled from Kimpo wastefill and Daehwa Dong, Kyonggi Do, respectively. PARAFIX, which is mainly composed of paraffin, cement, stearic acid, PVA etc., was used as solidifying agent. The chemical solutions used in the test were 10% acetic acid, 10% methanol, and real leachate from Kimpo wastefill and the results of tests were compared with that of distilled water. The results of tests show that hydraulic conductivity of solidified clay was increased slightly with permeation of acetic acid, methanol and the increase of hydraulic conductivity was not shown with permeation of leachate, distilled water and in case of weathered soil. Based on the tests, it is ascertained that the tested liner materials can be stable with the solution of low concentration.

• Korean Journal of Soil Science and Fertilizer
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• v.37 no.5
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• pp.293-303
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• 2004

This experiment was conducted to investigate the direction or orientation of clay particle movement in argillic horizons (Bt) for clarifying the soil classification of soils. Soil samples were collected from 22 soil series containing Bt horizons. Physical and chemical characteristics and mineral and chemical compositions of clay in the soils were analyzed. Micoromorphological characteristics of the Bt horizons were also investigated with thin sections of the natural undisturbed and oriented soil samples. Average clay content in the Bt horizons was 28% and 1.33 times higher comparing to that in the surface layer. Soil pH was higher, but cation exchange capacity (CEC) and organic matter content were lower in Bt horizon than those in the surface layer. There was an evidence of clay accumulation in Bt horizons of all soil series examined except Bangog series. Although there was an increase of clay content in the horizons in Bangog series, the clay was not originated from illuviation process. The translocation of clay was in the order of an 2:1 expandable clay minerals > 2:1 non-expandable clay minerals > 1:1 clay minerals. The illuvial substances in argillic horizon were composed with clay, amorphous iron and opaque mineral. The micoromorphological features of Bt horizon were void coating, channel infilling and grain coating. There was an apparent boundary between clay coating and the groundmass in residuum and colluvium, but Bt horizon of alluvium was composed of a skew plane amputated by the physical operation.

• Korean Journal of Mineralogy and Petrology
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• v.33 no.3
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• pp.175-183
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• 2020

There have rarely been performed for the clay mineralogy of the East Sea sediments except for few studies about paleoenvironmental aspect. This study inferred the provenance of sediments based on the clay mineral characteristics and distribution pattern for the 120 sediment samples collected by the box corer from the Gangneung-Donghae area between 2017-2019. The relative proportions of the four major clay minerals are abundant in the order of illite, chlorite, kaolinite, and smectite. The continental shelf sediments below water depth 150 m have more chlorite and kaolinite content and better illite crystallinity, but less illite and smectite content, and S/I index than those of continental slope sediments. Clay mineral composition of the continental shelf sediments are influenced by the adjacent continental geology, because north site (Gangneung area) has more chlorite but south site (Donghae area) has more kaolinite. These characteristics and distribution pattern of clay minerals indicate that the provenance of sediments are different between continental shelf and continental slop. The continental shelf sediments may be introduced the study area by the adjacent small rivers whereas the continental slope sediment might be supplied by current from the south of the study area.

• Journal of the Korean Geotechnical Society
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• v.20 no.6
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• pp.61-73
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• 2004

The coefficient of permeability of natural clay shows a nonlinear property which is related to various stress level of soils, and this nonlinear property has effect on the period of consolidation and the property of deformation in clay soils under loading. Thus, in this paper the numerical analysis was conducted by FEM-using coupled theory which incorporated Biot's consolidation theory into modified Cam-clay model- to consider the effects of nonlinear permeability on the behavior of clay soils under loading. The result of this paper showed that nonlinear permeability had different effects on the deformation and excess pore water pressure in clay soils according to the change of ratios of coefficients of permeability which was presented a degree of nonlinear property, and average coefficients of permeability of soils. Therefore, it was concluded that nonlinear permeability should be considered according to both the change of ratios of coefficients of permeability and average coefficients of permeability to conduct more simultaneous analyses to field conditions.

• Geomechanics and Engineering
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• v.12 no.3
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• pp.523-539
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• 2017

Clay soils are typical for their swelling properties upon absorption of water during rains and development of cracks during summer time owing to the profile desorption of water through the inter-connected soil pores by water vapour diffusion leading to evaporation. This type of unstable soil phenomenon by and large poses a serious threat to the strength and stability of structures when rest on such type of soils. Even as lime and cement are extensively used for stabilization of clay soils it has become imperative to find relatively cheaper alternative materials to bring out the desired properties within the clay soil domain. In the present era of catastrophic environmental degradation as a side effect to modernized manufacturing processes, industrialization and urbanization the creative idea would be treating the waste products in a beneficial way for reuse and recycling. Bottom ash and ecosand are construed as a waste product from cement industry. An optimal combination of bottom ash-eco sand can be thought of as a viable alternative to stabilize the clay soils by means of an effective dispersion dynamics associated with the inter connected network of pore spaces. A CATIA model was created and imported to ANSYS Fluent to study the dispersion dynamics. Ion migration from the bottom ash-ecosand pile was facilitated through natural formation of cracks in clay soil subjected to atmospheric conditions. Treated samples collected at different curing days from inner and outer zones at different depths were tested for, plasticity index, Unconfined Compressive Strength (UCS), free swell index, water content, Cation Exchange Capacity (CEC), pH and ion concentration to show the effectiveness of the method in improving the clay soil.

• Magazine of the Korean Society of Agricultural Engineers
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• v.39 no.1
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• pp.102-111
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• 1997

Experiments both in laboratory and field were performed to compare and analyze the characteristics of alluvial clay. The alluvial clay was sampled in test site in which large-scaled tests for the part of the site are under process to suggest the rational method for alluvial clay and the criterion for ground settlement monitoring system. The followings were observed through the experiments : 1. Natural water content, plastic limit, and liquid limit of alluvial clay composed of highly fine grains were 40~80%, 10~20%, and 30~55%, respectively. The values of these properties were relatively small at the ground surface, while the values showed maximum at G.L.- l0m and gradually decreased below the level. 2. Shear strength of alluvial clay was proportionally increased to the depth. Unconfined and triaxial compressive strengths were 0.2~0.6kgf/$cm^2$ and 0.1~0.3kgf/$cm^2$, respectively. 3. Compression index and secondary compression index showed maximum values at G.L.-l0m and gradually decreased below the level. The value of consolidation coefficient was relatively large at the ground surface, constant with decreasing the depth, and incresed when G.L. was below -20m. 4. Piezocone test appeared that alluvial clay with N value of 2~4 was uniformly distributed with 20~ 30m thickness from the ground surface, sand seam was nonuniformly distributed, and penetration pore pressure was 0.8 ~ 1 times of the hydrostatic pressure. Undrained shear strength and consolidation coefficient were 0.04 ~ 0.76kgf / $cm^2$ and $2.88{\times} 10{^-4}~1.3{\times} 10{^-2} cm^2/s$ respectively.

• Applied Chemistry for Engineering
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• v.22 no.5
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• pp.490-494
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• 2011

Nanocomposites of blends of polyethyleneterephthalate (PET) and polyamide66 (Nylon66) containing natural and organically modified montmorillonite clays (PM, $Cloisite^{(R)}$ 25A and 15A) were prepared by melt mixing. DSC results showed that the addition of clay changed the crystallization behavior of PET/Nylon66 nanocomposites. Clay C25A was observed to most significantly change the crystallization temperature than other clays in blends of PET and Nylon66, which may be caused by the difference in interaction with matrix polymers. AFM results also showed that the lowest value of surface roughness was observed for nanocomposites containing C25A indicating the smooth and relatively homogenous surface. Mechanical properties measurement showed the similar results. Contact angle was measured to study the difference in hydrophobicity. An increase in contact angle was observed for nanocomposites with C25A or C15A due to the increased hydrophobicity.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2010.04a
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• pp.163-163
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• 2010

• Journal of Soil and Groundwater Environment
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• v.6 no.4
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• pp.41-50
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• 2001

The use of clay has been the favored method of reducing or eliminating hazardous contaminants in the leachate from landfills. But, neither natural clays nor organoclays modified with surfactants are able to effectively sorb both heavy metals and organic contaminants. Therefore, the objective of this study is to determine the optimal amount of surfactant added on the clay mineral to effectively remove both of them. For this purpose, Na-Bentonite as the natural clay, and hexadecyltrimethylammonium (HDTMA) as the cationic surfactant were used, Chlorobenzene and lead ($Pb^{2-}$) were selected as representative contaminants. Experimental result showed that chlorobenzene sorption increased with increasing HDTMA to bentonite, ratios. On the contrary, the removal rate of lead decreased as the amount of HDTMA increased. The removal of chlorobenzene was influenced by the amount of HDTMA added to the bentonites rather than initial concentration of chlorobenzene, but the removal of lead was much more influenced by the initial concentration of lead. The adsorption of lead was not affected by chlorobenzene, and vice versa. The competitive sorption between the heavy metal and the organic contaminant was not present.

• Proceedings of the Korean Society of Agricultural Engineers Conference
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• 2002.10a
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• pp.353-356
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• 2002

In this study, the clay samples collected in the area Mokpo carry out laboratory soil test. Under three different curing $temperature-20^{\circ}C,\;50^{\circ}C,\;80^{\circ}C$ and 4 terms of curing day -1day, 7days, 14days, 40days for each, the remolded and reconsolidated samples had been made. To find out an aging effects and geotechnical characteristics between undisturbed samples and reconsolidated samples, laboratory tests were preformed. In the results, it was found that mechanical properties of undisturbed natural samples were similar to high temperature reconsolidation clay. The curing temperature influence on simulating aging effect more than the curing day does and the best curing condition are $80^{\circ}C$, 27days.