• Title/Summary/Keyword: Natural Mineral

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Experimental Study on the Mitigation of Harmful Algal Blooms by Mono-Minerals (환경친화성 단일 광물질에 의한 적조구제 실험)

  • 장영남;채수천;배인국;박맹언;김필근;김선옥
    • Economic and Environmental Geology
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    • v.36 no.6
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    • pp.557-561
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    • 2003
  • It is important to find out a new material having high removal efficiency for the harmful algal blooms because the dispersion of Hwangto in a large amount to the sea water may bring some ecologically unfavorable problems. For this purpose, the efficiency of several natural and synthetic mineral species for the mitigation of algal blooms was measured. The mixing ratio of monominerals and the sea water with 3,000∼5,000 cells/$m\ell$ of Cochlodinium polykrikoides was 10 g/${\ell}$ and the removal ratio was measured by counting the living cells after the dispersion time of 10, 30 and 60 min., respectively. According to the experimental results, the removal ratio by illite, kaolinite, montmonmorillonite, red mud, Na-A type of zeolite ranged 84-92% after 1hr of contact time, which is comparable to that of Hwangto. The size of above monominerals ranged 3∼50${\mu}m$. Meanwhile, the amorphose material and hematite with the size of 50∼100 nm showed excellent removal ratio of more than 99% after 30min. of dispersion. The results of the study showed that the removal ratio was not related to the chemical composition and pH of the minerals applied but to the grain size. The experimental results strongly suggest that the main mitigation mechanism would be the contact and coagulation.

Volcanological History of the Baengnokdam Summit Crater Area, Mt. Halla in Jeju Island, Korea (제주도 한라산 백록담 일대의 화산활동사)

  • Ahn, Ung San;Hong, Sei Sun
    • The Journal of the Petrological Society of Korea
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    • v.26 no.3
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    • pp.221-234
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    • 2017
  • The Baengnokdam, the summit crater of Mt. Halla, is one of the representative geosites of World Natural Heritage and Global Geopark in Jeju Island. The crater is marked by two distinctive volcanic lithofacies that comprise: 1) a trachytic lava dome to the west of the crater and 2) trachybasaltic lava flow units covering the gentle eastern slope of the mountain. This study focuses on understanding the formative process of this peculiar volcanic lithofacies association at the summit of Mt. Halla through field observation and optically stimulated luminescence (OSL) dating of the sediments underlying the craterforming volcanics. The trachyte dome to the west of the crater is subdivided into 3 facies units that include: 1) the trachyte breccias originating from initial dome collapse, 2) the trachyte lava-flow unit and 3) the domal main body. On the other side, the trachybasalt is subdivided into 2 facies units that include: 1) the spatter and scoria deposit from the early explosive eruption and 2) lava-flow unit from the later effusion eruption. Quartz OSL dating on the sediments underlying the trachyte breccias and the trachybasaltic lava-flow unit reveals ages of ca. 37 ka and ca. 21 ka, respectively. The results point toward that the Baengnokdam summit crater was formed by eruption of trachybasaltic magma at about 19~21 ka after the trachyte dome formed later than 37 ka.

Adsorption and Catalytic Characteristics of Acid-Treated Clinoptilolite Zeolite (산처리한 Clinoptilolite Zeolite 의 흡착 및 촉매특성)

  • Chon Hakze;Seo Gon
    • Journal of the Korean Chemical Society
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    • v.20 no.6
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    • pp.469-478
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    • 1976
  • Clinoptilolite zeolite samples were treated with hydrochloric acid, sulfuric acid and phosphoric acid of different strength and the adsorption characteristics and crystal structures of the original and acid-treated clinoptilolites were studied. By treating with hydrochloric acid, the adsorbed amount increased to 5-fold for nitrogen, to 3-fold for benzene, but for methanol no significant change was observed. As acid strength increased further, there were declines both in adsorption capacity and crystallinity. The results showed that the increase of adsorbed amount was caused by the rearrangement of the pore entrance and cation exchange. A method for determination of clinoptilolite content in natural mineral based on benzene adsorption on acid-treated sample is proposed. By this method, the original sample used in this study was found to contain approximately 40% of clinoptilolite. Using pulse technique in micro-catalytic reactor system, the catalytic activities of hydrochloric acid-treated clinoptilolites in cumene cracking and toluene disproportionation reactions were measured. For cumene cracking reaction, the maximum conversion was observed for the 0.5 N hydrochloric acid-treated sample. It is instructive to note that the maximum benzene adsorption was also observed for the sample treated with 0.5 N HCl. This suggest that the conversion rate was determined mainly by the rate of transport of reactants and the products through the pore structure. In the toluene disproportionation reaction, the same trend was observed. But the rate of deactivation was high for samples with strong acid sites. Since catalyst having higher activity was deactivated more easily, the conversion maximum was shifted to the sample treated with higher concentration of acid, -1N. The catalytic activity of $Ca^{2+} and La^{3+} ion exchanged samples for the toluene disproportion was much lower than that of acid-treated samples. Introduction of Ca^{2+} and La^{3+}$ into the pore structure apparently decreases the effective pore diameter of acid-treated clinoptilolite thus limiting the diffusion of reactants and products.

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Petrological and Mineralogical Characteristics of Amphibolite Used as Rock Bowl and Pot: Implications for Its Utility and Stability (음식 용기로 사용하는 각섬암의 암석-광물학적 특성: 그 효용성과 안정성에 대한 고찰)

  • Kim, Hyeong-Soo;Choi, Ho-Jeong
    • The Journal of the Petrological Society of Korea
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    • v.17 no.3
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    • pp.154-165
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    • 2008
  • Rock bowls and pots used in restaurants are one of the popular usages of natural rocks in Korea. Most rock bowls and pots are made of Mg- and Ca-rich amphibolite composed of hornblende, actinolite, tremolite, diopside, plagioclase. Hornblende occurs as prismatic crystal habit, and belongs to Mg-hornblende to tschermakite. Actinolite and tremolite occur as acicular form (aspect ratio $0.10{\sim}0.13$), and ranges 0.65 to 0.90 in Mg/(Mg+Fe) ratio. These acicular actinolite and tremolite are non-asbestos minerals. However to use of rocks containing these minerals as tableware it is needed to regulatory guidelines for stability and utility based on petrological and mineralogical characteristics. Discrepancy of rock occurrence and mineral chemistry between commercial rock bowls and original rocks indicate that most rock bowls are made of uncertain amphibolite in original location. Consequently, there is a potential risk to use inappropriate amphibolites as tableware. Therefore, it is needed to systematically research on geology and biology, and manage commercial rock bowls and pots used in Korean restaurants.

Chemical Components and Anti-oxidant Activities of Black Currant (블랙 커런트의 화학성분 및 항산화 활성)

  • Jeong, Chang-Ho;Jang, Chi-Weon;Lee, Koo-Yul;Kim, Il-Hun;Shim, Ki-Hwan
    • Food Science and Preservation
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    • v.19 no.2
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    • pp.263-270
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    • 2012
  • The chemical components and anti-oxidant activities of black currant were investigated. The pH, soluble solid and total acidity values were 3.36, 15.11 $^{\circ}Brix$, and 1.65%, respectively. The Hunter L, a, and b values were 18.20, 5.13, and 1.08, respectively. The proximate compositions were as follows; moisture, 77.64%; nitrogen free extract, 17.41%; crude fiber, 3.08%; crude protein, 1.28%; crude ash, 0.31%; and crude lipid, 0.28%, respectively. The mineral elements were K (177.36 mg/100 g), P (54.74 mg/100 g), and Ca (26.45 mg/100 g). The free sugar components were glucose (7.71%) and fructose (5.88%). The amino acid contents of the black currant were very rich in glutamic acid (105.73 mg/100 g) and deficient in cystine (5.29 mg/100 g). The ascorbic acid and total phenolic contents were 112.19 mg/100 g and 34.48 mg GAE/g, respectively. The ABTS and DPPH radical scavenging activity levels were 99.48% and 89.03% at the 10 and 1.25 mg/mL concentrations. The reducing power and FRAP of the black currant were dose-dependent. Thus, black currant can be an effective source of functional food substances, i.e., natural anti-oxidants.

Behaviors of Trace Elements Caused by the Precipitation of Minerals in Acid Mine Drainage (산성광산배수에서 광물의 침전에 따른 미량 원소의 거동)

  • Yoon, Young Jin;Lee, Ji Eun;Bang, Sang Je;Baek, Young Doo;Kim, Yeongkyoo
    • Journal of the Mineralogical Society of Korea
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    • v.31 no.3
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    • pp.173-182
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    • 2018
  • The precipitation and phase transformation processes of iron minerals in acid mine drainage have a great influence on the behavior of trace elements in drainage. However, it is not easy to accurately trace these processes in natural environments, and therefore, most studies have carried out in the laboratory to obtain the information on the precipitation and transformation of those minerals. In this study, the precipitation of minerals and the changes of trace elements in drainage water were investigated at different pH values in actual acid mine drainage collected from the Dalsung mine. The amount of some precipitated minerals was not enough for the mineral identification. However, from the minerals identified, amorphous minerals were formed first, and then goethite was precipitated probably from schwertmannite. When the pH of the sample was high (10), amorphous phases of minerals were still observed at even high pH (pH 10). With increasing time, the pH values decreased by precipitation and transformation of minerals. All the elements showed low concentrations at high pH (8, 10), which might be due to the precipitation of minerals at high pH and the effect of surface charge, and the concentrations of elements gradually increased with time. In the case of sulfur, it also increased in water due to the transformation of schwertmannite to goethite.

The Influences of Thailand's Import and FDI on Lao PDR's Economic Growth (태국의 수입 및 FDI가 라오스의 경제성장에 미친 영향)

  • Kim, Kyu;Kwon, KiChul
    • The Journal of the Korea Contents Association
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    • v.20 no.1
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    • pp.304-316
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    • 2020
  • Laos is rich in natural resources but lacks the capital to develop them. Partly alleviating the shortage is FDI from neighboring countries, especially Thailand. Not only does this contribute to directly increasing GDP by increasing effective demand, it also has an additional GDP increase effect by expanding Laos' production capacity. Laos' exports mostly consist of mineral resources and electricity. This, too, contributes to an increase in GDP by increasing the effective demand. Thailand accounts for more than 40 percent of Laos' exports. This paper tries to confirm the economic impact on Laos in Thailand through a econometric analysis of Laos' GDP, Laos' exports to Thailand and Thailand's FDI to Laos. It turns out that economic ties with Thailand, including exports to Thailand and Thailand's FDI, play a very important role in Laos' economic growth. Laos recently recorded relatively robust economic growth, but its driving force is weak. That's because Laos' growth engines are very limited and have no resilience to external shocks. Moreover, economic growth has not been linked to an increase in employment because the economy is not diversified and growth in the hydroelectric power sector does not lead to growth in other sectors. Given this, Laos needs to actively take advantage of its geographical proximity to Thailand. It is necessary to create a more active environment for the inflow of FDI in Thailand, to foster resource-based and labor-based manufacturing to take advantage of the Thai market.

Studies for Component Analysis and Antioxidative Evaluation in Acorn Powders (도토리 가루의 성분분석과 항산화능 평가)

  • Shim, Tae-Heum;Jin, Ying-Shan;Sa, Jae-Hoon;Shin, In-Cheol;Heo, Seong-Il;Wang, Myeong-Hyeon
    • Korean Journal of Food Science and Technology
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    • v.36 no.5
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    • pp.800-803
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    • 2004
  • Chemical components and physiological activities of acorn powders were investigated to develop functional food. Proximate components were 87.29% crude fiber, 1.18% crude fat, 0.84% crude protein, and 0.12% crude ash. Potassium was most predominant mineral, followed by phosphorus, calcium, magnesium, and sodium. Contents of unsaturated fatty acids, such as oleic, linoleic, and linolenic acids, were higher than those of saturated fatty acids. Water and 75% ethanol extracts of acorn powders showed higher absorbency at 285 nm. Water and 75% ethanol extracts exhibited antioxidative activity with $IC_{50}$ of 19.0 and $21.4\;{\mu}g/mL$, respectively, indicating they are the major biological component in acorn powders. Results suggest water extract of acorn can be used as new material for natural antioxidant and functional food.

Chemical Composition and Antimicrobial Activities of Houttuynia cordata Thunb. (어성초의 화학성분 및 항미생물 활성)

  • Kim, Keun-Young;Chung, Dong-Ok;Chung, Hee-Jong
    • Korean Journal of Food Science and Technology
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    • v.29 no.3
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    • pp.400-406
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    • 1997
  • Chemical composition and antimicrobial activity of Houttuynia cordata Thunb. were investigated to develop a natural food preservative from it. Aspartic acid, glutamic acid, glycine and arginine were major amino acids of Houttuynia cordata Thunb., but were present in a trace amount. Free sugars were composed of glucose, fructose, sucrose and maltose and major fatty acids were linolenic acid, linoleic acid, oleic acid, and palmitic acid. Mineral elements were potassium, calcium, magnesium, iron, zinc, and copper. Antimicrobial activities were shown in acidic, neutral and phenolic fraction of Houttuynia cordata Thunb., but not in basic fraction. Among the four fractions, neutral fraction showed the strongest antimicrobial activities against microorganisms tested, such as Pseudomnas aeruginosa, Micrococcus luteus, Bacillus subtilis, Aspergillus parasiticus and Aspergillus flavus. Minimum inhibitory concentration (MIC) and minimum lethal concentration (MLC) of the neutral fraction varied according to microoganisms tested. The lowest values of MIC (0.0075 g eq./mL) and MLC (0.10 g eq./mL) were obtained from Pseudomonas aeruginosa.

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Ecological Indicators of Forest Degradation after Forest Fire and Clear-cutting in the Siberian Larch (Larix sibirica) Stand of Mongolia

  • Park, Yeong Dae;Lee, Don Koo;Stanturf, John A.;Woo, Su Young;Zoyo, Damdinjav
    • Journal of Korean Society of Forest Science
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    • v.98 no.5
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    • pp.609-617
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    • 2009
  • This study was conducted to investigate ecological indicators of forest degradation after forest fire and clear-cutting in the Siberian larch (Larix sibirica Ledeb.) stand of Mongolia. The species abundance and biodiversity indices were higher in burned and clear-cut stands than those of reference stand, but boreal understory species, such as Vaccinium vitis-idaea, Pyrola incarnata, Linnea borealis and Maianthemum bifolium, completely disappeared and was replaced by sedge species, such as Carex duriuscula, C. lanceolata, C. pediformis, Poa attenuata and P. pratensis. During the research period, temperature increased by an average of $1.6^{\circ}C$ in burned stand and $1.7^{\circ}C$ in clear-cut stand compared to reference stand, but RH sharply decreased up to 15.7% in clear-cut stand. This result indicates that Larix sibirica stand became warmer and drier after forest fire and clear-cutting, and contributed to the abundance of sedge and grass species in the understory. Moreover, intense occupation of tall sedge grass after forest fire and clear-cutting had a vital role as obstacle on natural regeneration of Larix sibirica. The similarity of species composition between reference and burned stands was higher (73.6%) than between reference and clear-cut stands (63.8%). Soil moisture significantly decreased after forest fire and clear-cutting, and the extent of decrease was more severe in the clear-cut stand. The chemical properties at soil organic layer were significantly affected by forest fire and clear-cutting but not the mineral horizons. Inorganic nitrogen of the forest floor significantly decreased in the clear-cut stand ($1.1{\pm}0.4mg{\cdot}kg^{-1}$) than that of the burned ($4.5{\pm}2.3mg{\cdot}kg^{-1}$) and reference stands ($5.0{\pm}2.3mg{\cdot}kg^{-1}$). Available P of the forest floor significantly increased after fire, whereas it decreased after clear-cutting. These results indicate that existence of boreal understory vegetation, and changes in soil moisture and available P are distinct attributes applicable as ecological indicators for identifying forest degradation in Mongolia.