• Title/Summary/Keyword: Nanowires synthesis

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Atomic structure and crystallography of joints in SnO2 nanowire networks

  • Hrkac, Viktor;Wolff, Niklas;Duppel, Viola;Paulowicz, Ingo;Adelung, Rainer;Mishra, Yogendra Kumar;Kienle, Lorenz
    • Applied Microscopy
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    • v.49
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    • pp.1.1-1.10
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    • 2019
  • Joints of three-dimensional (3D) rutile-type (r) tin dioxide ($SnO_2$) nanowire networks, produced by the flame transport synthesis (FTS), are formed by coherent twin boundaries at $(101)^r$ serving for the interpenetration of the nanowires. Transmission electron microscopy (TEM) methods, i.e. high resolution and (precession) electron diffraction (PED), were utilized to collect information of the atomic interface structure along the edge-on zone axes $[010]^r$, $[111]^r$ and superposition directions $[001]^r$, $[101]^r$. A model of the twin boundary is generated by a supercell approach, serving as base for simulations of all given real and reciprocal space data as for the elaboration of three-dimensional, i.e. relrod and higher order Laue zones (HOLZ), contributions to the intensity distribution of PED patterns. Confirmed by the comparison of simulated and experimental findings, details of the structural distortion at the twin boundary can be demonstrated.

Synthesis of Lead Selenide Nanowires by Photolithography and Electrodeposition Process (포토리소그래피와 도금을 사용한 셀레늄화 납 나노와이어 합성)

  • Song, Yeong-Seop;Lee, Ju-Yeol;Lee, Gyu-Hwan;Im, Jae-Hong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2014.11a
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    • pp.305-305
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    • 2014
  • 포토리소그래피와 도금 공정을 통해 PbSe 나노와이어를 합성하였다. PbSe은 광센서 및 열전 물질로 많이 알려져있다. 이러한 응용처에의 향상된 성능을 위해 본 연구에서는 PbSe 나노와이를 합성하였다. 합성에 사용된 방법인 포토리소그래피와 도금 공정은 반도체 산업 전반에 인프라가 잘 구축된 공정이며, 병렬 공정이다. 따라서 본 연구는 경제적이며 대량생산이 가능한 PbSe 나노와이어의 합성법을 제안한다.

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Synthesis of Single-Crystalline InSb Nanowires Using CVD Method and Study of Growth Mechanism in Open and Close System (CVD 방법을 이용한 단결정 InSb 나노와이어의 성장과 Open/Close 시스템에서의 반응 메커니즘 연구)

  • Kang, Eun Ji;Park, Yi-Seul;Lee, Jin Seok
    • Journal of the Korean Vacuum Society
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    • v.22 no.6
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    • pp.306-312
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    • 2013
  • Single-crystalline InSb nanowire was synthesized on $SiO_2$ wafer via vapor-liquid-solid (VLS) mechanism using chemical vapor deposition method. According to the source container system (open or close) which contain InSb powder and $SiO_2$ wafer, the single-crystalline InSb nanowires have different growth mechanisms. Structural characterization of the InSb nanowires was examined by scanning electron microscope (SEM). Composition of the nanowires was investigated using x-ray diffraction (XRD) and energy dispersive x-ray spectroscopy (EDS). This study demonstrates that length and diameter of the InSb nanowires are long and thick using open-boat system by VLS and additional vapor-solid (VS) mechanisms, because open-boat system can carry a large amount of vapor-phase InSb precursor than close-boat system.

Fabrication of flexible sponge electrodes using Ag nanowires (은나노와이어 함침 유연 스펀지 전극 제조)

  • Park, Kyoung Ryeol;Yoo, Sehoon;Ryu, Jeong Ho;Mhin, Sungwook
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.30 no.5
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    • pp.189-193
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    • 2020
  • Recently, various methods for preparing a flexible electrode for implementing a wearable sensor have been introduced. Wearable sensors show similar tendency to use various polymer substrates, which provides elasticity suitable to the motion of human body. In this paper, a highly elastic silver nanowire based electrode was prepared on a sponge-based stretchable substrate, and electrical properties were evaluated. Silver nanowires were grown using a wet chemical synthesis, impregnated into a plasma-treated sponge, and then heat treated at a low temperature. In particular, the plasma surface treatment of the sponge enables uniform coating of silver nanowires. The flexible sponge electrode showed reliable electrical resistance changes over 160 repeated tensile-compression cycles.

Structural characteristics of ZnO nanostructures synthesized by the thermal evaporation method (열증착법으로 합성된 ZnO 나노 구조체의 구조적 특성)

  • Bang, Sin-Young;Kim, Woo-Sik;Chung, Jun-Ho;Choi, Bong-Geun;Shim, Kwang-Bo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.18 no.2
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    • pp.81-86
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    • 2008
  • ZnO nanowires were synthesized by the thermal evaporation method and their growth mechanisms were confirmed by the characterization of the structural features depending on the growth conditions. The increase of vaporization temperature accelerates the growth rate and morphologies of ZnO nanowires were drastically changed at the temperature over 1000$^{\circ}C$, because of changed $CO/CO_2$ partial pressure. Au particles play their role on growth of ZnO nanowire as catalyst at growth temperature over 700$^{\circ}C$. The synthesized ZnO nanowires exhibit blue emission at 380 nm.

Synthesis of Fe-Doped TiO2/α-Fe2O3 Core-Shell Nanowires Using Co-Electrospinning and Their Magnetic Property (복합 전기방사법을 이용한 Fe-doped TiO2/α-Fe2O3 이중구조 나노와이어의 합성 및 자성 특성)

  • Koo, Bon-Ryul;Ahn, Hyo-Jin
    • Korean Journal of Materials Research
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    • v.24 no.8
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    • pp.423-428
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    • 2014
  • We synthesized Fe-doped $TiO_2/{\alpha}-Fe_2O_3$ core-shell nanowires(NWs) by means of a co-electrospinning method and demonstrated their magnetic properties. To investigate the structural, morphological, chemical, and magnetic properties of the samples, X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and X-ray photoelectron spectroscopy were used, as was a vibrating sample magnetometer. The morphology of the nanostructures obtained after calcination at $500^{\circ}C$ exhibited core/shell NWs consisting of $TiO_2$ in the core region and ${\alpha}-Fe_2O_3$ in the shell region. In addition, the XPS results confirmed the formation of Fe-doped $TiO_2$ by the doping effect of $Fe^{3+}$ ions into the $TiO_2$ lattice, which can affect the ferromagnetic properties in the core region. For comparison, pure ${\alpha}-Fe_2O_3$ NWs were also fabricated using an electrospinning method. With regard to the magnetic properties, the Fe-doped $TiO_2/{\alpha}-Fe_2O_3$ core-shell NWs exhibited improved saturation magnetization(Ms) of approximately ~2.96 emu/g, which is approximately 6.1 times larger than that of pure ${\alpha}-Fe_2O_3$ NWs. The performance enhancement can be explained by three main mechanisms: the doping effect of Fe ions into the $TiO_2$ lattice, the size effect of the $Fe_2O3_$ nanoparticles, and the structural effect of the core-shell nanostructures.