• Title/Summary/Keyword: Nanoscience

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Electrically Driven Quantum Dot/wire/well Hybrid Light-emitting Diodes via GaN Nano-sized Pyramid Structure

  • Go, Yeong-Ho;Kim, Je-Hyeong;Kim, Ryeo-Hwa;Go, Seok-Min;Gwon, Bong-Jun;Kim, Ju-Seong;Kim, Taek;Jo, Yong-Hun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.47-47
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    • 2011
  • There have been numerous efforts to enhance the efficiency of light-emitting diodes (LEDs) by using low dimensional structures such as quantum dots (QDs), wire (QWRs), and wells (QWs). We demonstrate QD/QWR/QW hybrid structured LEDs by using nano-scaled pyramid structures of GaN with ~260 nm height. Photoluminescence (PL) showed three multi-peak spectra centered at around 535 nm, 600 nm, 665 nm for QWs, QWRs, and QDs, respectively. The QD emission survived at room temperature due to carrier localization, whereas the QW emission diminished from 10 K to 300 K. We confirmed that hybrid LEDs had zero-, one-, and two-dimensional behavior from a temperature-dependent time-resolved PL study. The radiative lifetime of the QDs was nearly constant over the temperature, while that of the QWs increased with increasing temperature, due to low dimensional behavior. Cathodoluminescence revealed spatial distributions of InGaN QDs, QWRs, and QWs on the vertices, edges, and sidewalls, respectively. We investigated the blue-shifted electroluminescence with increasing current due to the band-filling effect. The hybrid LEDs provided broad-band spectra with high internal quantum efficiency, and color-tunability for visible light-emitting sources.

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Highly Sensitive Fluorescent Probes for the Quantitative Determination of Singlet Oxygen (1O2)

  • Ahmed, Syed Rahin;Koh, Kwang-Nak;Kang, Nam-Lyong;Lee, Jae-Beom
    • Bulletin of the Korean Chemical Society
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    • v.33 no.5
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    • pp.1608-1612
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    • 2012
  • Singlet oxygen ($^1O_2$) is an important species for oxidation in biological processes. $^1O_2$ is implicated in the genotoxic effect, and plays an important role in the cell-signaling cascade and in the induction of gene expression. However, the rapid detection of $^1O_2$ in biological environments with sufficient specificity and sensitivity is hampered by its extremely low emission probability. Here, a layer-by-layer (LbL) film of CdTe quantum dots (QDs), polymers, and ascorbate have been designed as a rapid, highly selective, and sensitive fluorescence probe for $^1O_2$ detection. Upon reaction with $^1O_2$, the probe exhibits a strong photoluminescence (PL) response even at trace levels. This remarkable PL change should enable the probe to be used for $^1O_2$ detection in many chemical and biological systems and as an environmental sensor.

A Novel Approach to Controlling CaCO3 Crystalline Assembly by Changing the Concentration of Poly(aspartic acid)

  • Zhou, Hongjian;Gao, Yanmin;Hwang, Sun-Gu;Lee, Dong-Yun;Park, Jung-Youn;Lee, Jae-Beom
    • Bulletin of the Korean Chemical Society
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    • v.32 no.11
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    • pp.4027-4034
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    • 2011
  • $CaCO_3$ crystalline structures having novel assemblies were in situ fabricated as analogs of naturally occurring proteins and polysaccharides for biomineralization. The calcite crystal was mineralized in a poly(vinyl alcohol)-$Ca^{2+}$ complex film immersed in a $Na_2CO_3$ solution containing poly(aspartic acid). The morphology and size of the $CaCO_3$ crystals were tuned by varying the concentration of poly(aspartic acid). The mechanisms of their nucleation orientation and formation were investigated experimentally and through molecular dynamics (MD) simulations in order to obtain a better understanding of the interactions between the polymers and the crystal at the molecular level. Both the MD results and experimental results indicate that the interaction between PVA and calcite mainly depends on the concentration of the polymer. The novel approach proposed herein for the fabrication of inorganic crystalline assembly structures can be used to fabricate precise crystalline structures.

Effect of Aluminum, Manganese, and Zirconium on the Content of Nickel in Molten Magnesium (마그네슘용탕의 니켈 함량에 미치는 알루미늄, 망간 및 지르코늄의 영향)

  • Jeong, Dae-Yeong;Moon, Young-Hoon;Moon, Byoung-Gi;Park, Won-Wook;Sohn, Keun-Yong
    • Journal of Korea Foundry Society
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    • v.35 no.1
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    • pp.8-14
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    • 2015
  • Variations of nickel contents and microstructures in molten magnesium alloys on the addition of aluminum, zirconium, and manganese have been investigated. Specimens were prepared by melting under $SF_6$ and $CO_2$ atmosphere and casting into a disc of 29 mm diameter with 7~10 mm thickness from the melt acquired at the top of crucible. Before casting, the molten metal was stirred for 3 minutes after each addition of alloying elements and maintained for 30 minutes for settling down. Results showed that zirconium did not significantly affect the content of nickel while aluminum remarkably reduced it by forming $Al_3Ni_2$ phase. When manganese are added to Mg-1wt%Ni alloy along with aluminum, both elements remarkably reduced the content of nickel. The addition of 1.5 wt% manganese to Mg-1wt%Ni alloy containing aluminum further reduced the content of nickel by more than 30%, during which an additional intermetallic phase $Al_{10}Mn_3Ni$ was precipitated in the molten magnesium.

Microcontroller based Chaotic Lorenz System for secure communication applications (암호통신 응용을 위한 마이크로 컨트로러 기반 로렌츠 카오스 시스템)

  • Jayawickrama, Chamindra;Kang, Bogyeong;Al-Shidaifat, AlaaDdin;Park, Yongsu;Song, Hanjung
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2018.10a
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    • pp.487-489
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    • 2018
  • This paper presents chaotic Lorenz system implementation for secure data communication applications. In this work chaotic signal is generated by a PIC18F family based microcontroller, XC8 compilers have been utilized for the compilation of C code of microcontroller program. For simulation work Matlab and Proteus platforms were utilized and finally, chaotic time waveforms, 2D and 3D chaotic attractor were obtained and secure communication waveforms were achieved successfully.

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