• Title/Summary/Keyword: Nanophosphor

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Hydrothermal Synthesis of Red-Emitting Y(V0.5,P0.5)O4:Eu Nanophosphors and their Application to Transparent Plasma Display Fabrication (적색발광 Y(V0.5,P0.5)O4:Eu 나노형광체의 수열 합성 및 투명 플라즈마 디스플레이 소자 제작으로의 응용)

  • Song, Woo-Seuk;Yang, Hee-Sun
    • Journal of the Korean Ceramic Society
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    • v.48 no.1
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    • pp.86-93
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    • 2011
  • Transparent plasma display can be realized by developing the synthetic chemistry of appropriate nanophosphors and generating nanophosphor-based transparent luminescent layers. For this goal, red-emitting $Y(V_{0.5},\;P_{0.5})O_4$:Eu nanophosphors were synthesized by a facile hydrothermal route at $200^{\circ}C$ for 48 h and the resulting nanophosphors were subsequently annealed at $800^{\circ}C$ at an ambient atmosphere. The crystallographic structure, morphology, and emission property of the as-synthesized and annealed nanophosphors were compared. Choosing 2-methoxyethanol as a dispersion medium and applying a standard sonication, well-dispersed nanophosphor solutions could be prepared. Using these dispersions, visible transparent nanophosphor layers were spin-deposited on glass substrates. By combining $Y(V_{0.5},\;P_{0.5})O_4$:Eu nanophosphor layer/glass substrate as a rear plate with a front plate used in a conventional plasma display panels (PDPs), mini-sized transparent red-emitting PDPs were constructed. Transmittance and luminance properties of two transparent test panels using as-synthesized versus $800^{\circ}C$-annealed nanophosphors were characterized and compared.

Synthesis and characterization of $Y_2O_3$:Eu nano phosphor powder by a new technique

  • Kwak, Min-Gi;Hong, Sung-Jei;Han, Jeong-In
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1367-1369
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    • 2006
  • In this paper, a new technique has been adopted for synthesis of nanophosphor particles of $Y_2O_3:Eu$ at low temperature. The optical properties of the prepared nanophosphor particles have been measured and the results have been compared with the properties of its bulk phosphor particles. The particle sizes of $Y_2O_3:Eu$ nanophosphor powder with doped-Eu concentration of 10wt% synthesized by our procedure is about 40nm. When the concentration of Eu was 10wt%, intensity of PL appeared the highest and 95% efficient as compared with bulk phosphor.

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Aerosol Synthesis of Gd2O3:Eu/Bi Nanophosphor for Preparation of Photofunctional Pearl Pigment as Security Material

  • Jung, Kyeong Youl;Han, Jang Hoon;Kim, Dae Sung;Choi, Byung-Ki;Kang, Wkang-Jung
    • Journal of the Korean Ceramic Society
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    • v.55 no.5
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    • pp.461-472
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    • 2018
  • $Gd_2O_3:Eu/Bi$ nanoparticles were synthesized via spray pyrolysis and applied for the preparation of a luminescent pearl pigment as an anti-counterfeiting material. The luminescence properties were optimized by changing the $Eu^{3+}$ and $Bi^{3+}$ concentration. Ethylene glycol was used as an organic additive to prepare the $Gd_2O_3:Eu/Bi$ nanoparticles. The highest emission intensity was achieved when the total dopant content was 10.0 at.% and the mole fraction of Bi was 0.1. The concentration quenching was mainly due to dipole-dipole interactions between the same activators, and the critical distances were 9.0 and $19.6{\AA}$ for $Eu^{3+}$ and $Bi^{3+}$, respectively. The prepared $Gd_2O_3:Eu/Bi$ powder exhibited an average size of approximately 82.5 nm and a narrow size distribution. Finally, the $Gd_2O_3:Eu/Bi$ nanophosphor coated on the surface of the pearl pigment was confirmed to have good red emission under irradiation from a portable ultraviolet light-emitting diode lamp (365 nm).

Influence of HMDS additive on the properties of YAG:Ce nanophosphor

  • Choi, Kyu-Man;Kim, Yeo-Hwan;Lim, Hae-Jin;Yoon, Sang-Ok
    • The Journal of Korea Institute of Information, Electronics, and Communication Technology
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    • v.4 no.1
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    • pp.61-67
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    • 2011
  • Influence of hexamethyldisilazane(HMDS) in post processing technique by using n-butanol azeotropic distillation on the luminescence properties of YAG:Ce nanophosphor were studied. The organic solvent(n-butanol) azeotropic distillation which prevent powders from conglobation since lager molecules decrease the surface tension and more complete replace the residual water in the precipitate. HMDS that had larger molecules than that of n-butanol was added in azeotropic distillation. The phosphor synthesized from n-butanol azeotropic distillation exhibited lower agglomerate and better photoluminescence properties than that from HMDS added heterogeneous azeotropic distillation.

Fluorescent Nanoparticles: Synthesis and Applications (형광 나노입자: 합성 및 응용)

  • Kim, Y.K.;Song, B.K.;Lee, J.G.;Baek, Y.K.
    • Journal of Powder Materials
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    • v.27 no.2
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    • pp.154-163
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    • 2020
  • Fluorescent nanoparticles are characterized by their unique properties such as luminescence, optical transparency, and sensitivity to various chemical environments. For example, semiconductor nanocrystals (quantum dots), which are nanophosphors doped with transition metal or rare earth ions, can be classified as fluorescent nanoparticles. Tuning their optical and physico-chemical properties can be carried out by considering and taking advantage of nanoscale effects. For instance, quantum confinement causes a much higher fluorescence with nanoparticles than with their bulk counterparts. Recently, various types of fluorescent nanoparticles have been synthesized to extend their applications to other fields. In this study, State-of-the-art fluorescent nanoparticles are reviewed with emphasis on their analytical and anti-counterfeiting applications and synthesis processes. Moreover, the fundamental principles behind the exceptional properties of fluorescent nanoparticles are discussed.

Photoluminescence properties of core/shell-type $LnPO_4:Eu/LnPO_4$ (Ln=La, Gd) nanophosphors

  • Oh, Jae-Suk;Jung, Ha-Kyun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08b
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    • pp.1551-1554
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    • 2007
  • To overcome defect due to large surface of nanoparticle, a redispersible Eu doped $LnPO_4:LnPO_4$ core/shell nanoparticles were prepared in a highboiling coordinating solvent. The particle size of the synthesized core/shell nanophosphors was estimated to be about 8 nm by TEM. In this core/shell nanoparticle, the concentration of Eu ion was optimized on the basis of the emission intensity under UV ray excitation. Also, the PL properties of the nanophosphors have been compared with those of the $LnPO_4:Eu$ nanoparticles.

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