• Title/Summary/Keyword: Nanomaterial

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A Mini-Review on Non-Aqueous Lithium-Oxygen Batteries - Electrochemistry and Cathode Materials

  • Riaz, Ahmer;Jung, Kyu-Nam;Lee, Jong-Won
    • Journal of Electrochemical Science and Technology
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    • v.6 no.2
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    • pp.50-58
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    • 2015
  • There is a great deal of current interest in the development of rechargeable batteries with high energy storage capability due to an increasing demand for electric vehicles (EVs) with driving ranges comparable to those of gasoline-powered vehicles. Among various types of batteries under development, a Li-O2 battery delivers the highest theoretical energy density; thus, it is considered a promising energy storage technology for EV applications. Despite the fact that extensive research efforts have been made in the field of Li-O2 batteries in recent years, there are still many technical challenges to be addressed, such as low round-trip efficiency, poor reversibility, and poor power capability. In this article, we provide a short review on the fundamental electrochemistry of Li-O2 batteries with non-aqueous electrolytes and on electrode materials that have been employed in cathodes (oxygen electrodes). The major aim of this mini-review is to highlight the physical and electrochemical origins of scientific challenges facing Li-O2 battery technology and to overview the strategies proposed to overcome them.

Reinforcing Efficiencies of Two Different Cellulose Nanocrystals in Polyvinyl Alcohol-Based Nanocomposites

  • Park, Byung-Dae;Causin, Valerio
    • Current Research on Agriculture and Life Sciences
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    • v.31 no.4
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    • pp.250-255
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    • 2013
  • As a renewable nanomaterial, cellulose nanocrystal (CNC) isolated from wood grants excellent mechanical properties in developing high performance nanocomposites. This study was undertaken to compare the reinforcing efficiency of two different CNCs, i.e., cellulose nanowhiskers (CNWs) and cellulose nanofibrils (CNFs) from hardwood bleached kraft pulp (HW-BKP) as reinforcing agent in polyvinyl alcohol (PVA)-based nanocomposite. The CNWs were isolated by sulfuric acid hydrolysis while the CNFs were isolated by 2,2,6,6-tetramethylpiperidine-1-oxyl radical (TEMPO)-mediated oxidation. Based on measurements using transmission electron microscopy, the individual CNWs were about $6.96{\pm}0.87nm$ wide and $178{\pm}55nm$ long, while CNFs were $7.07{\pm}0.99nm$ wide. The incorporation of CNWs and CNFs into the PVA matrix at 5% and 1% levels, respectively, resulted in the maximum tensile strength, indicating different efficiencies of these CNCs in the nanocomposites. Therefore, these results suggest a relationship between the reinforcing potential of CNCs and their physical characteristics, such as their morphology, dimensions, and aspect ratio.

Fabrication of Nanostructured $5Cu_{0.6}Fe_{0.4}-Al_2O_3$ Composite by Pulsed Current Activated Sintering from Mechanically Synthesized Powder (기계적으로 합성한 분말로부터 펄스전류 활성 소결에 의한 나노구조 $5Cu_{0.6}Fe_{0.4}-Al_2O_3$ 복합재료제조)

  • Park, Na-Ra;Song, Jun-Young;Nam, Kee-Seok;Shon, In-Jin
    • Journal of the Korean Society for Heat Treatment
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    • v.22 no.3
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    • pp.149-154
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    • 2009
  • Dense $5Cu_{0.6}Fe_{0.4}-Al_2O_3$ composite was consolidated from mechanically synthesized powders by pulsed current activated sintering method within 1 min. $5Cu_{0.6}Fe_{0.4}-Al_2O_3$ powder was synthesized from 3CuO and 2FeAI using the high energy ball milling. Dense $5Cu_{0.6}Fe_{0.4}-Al_2O_3$ with relative density of up to 95% was produced under simultaneous application of a 80 MPa pressure and the pulsed current. Mechanical properties and grain size of the composite were investigated.

Development and Performance of Water Purifier with the Auto-Disinfected on a simple Drinking Water (간이상수도 자동소독 정수기의 개발 및 성능에 관한 연구)

  • Cho, Byeung-Rak;Lee, Bae-Bok;Choi, Myeung-Bu
    • Journal of the Korean Society of Industry Convergence
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    • v.16 no.2
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    • pp.41-46
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    • 2013
  • On the purpose of helping the inhabitants living in farming, fishing villages, and islands for more safe and hygienic water from simple waterworks, experimental investigations were performed concerning the development of a water purifier with silver nanomaterial packed, having a function of the auto-disinfection. The results show as follows through such filteration and auto-disinfection processes. It is possible to get hygienic and safe water, for example, more than 95% of general bacteria, total coliforms, and fecal coliforms were removed. It is also possible to get good-quality water, for 49.4% of spent potassium permanganate and 85% and 63% of turbidity and conductivity were removed respectively. It is a very effective equipment, for 100% cost reduction of used chemicals was achieved by no-chemical disinfection process and THM was not generated.

Research Trend of Trophic Transfer of Nanoparticles in Aquatic Ecosystems (나노입자의 수생태계 영양단계전이 연구동향)

  • Lee, Woo-Mi;An, Youn-Joo
    • Korean Journal of Ecology and Environment
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    • v.44 no.4
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    • pp.317-326
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    • 2011
  • With its recent advances, nanotechnology is now being applied to various areas. Despite the benefits of nanoparticles, their risk in the environment has caused controversy, which is now becoming an international issue. Nanoparticles can easily infiltrate into cells, accumulate in biota, and may cause adverse effects in the levels of molecules, cells and organisms, and in the community. If nanoparticles are released into the environment, they can be transferred to organisms in the ecosystem, and eventually to the human body through the food chain. In this study, the research trend of the trophic transfer of nanoparticles in the food chain was investigated. Although a few investigations have been conducted regarding this topic, the trophic transfer of nanoparticles is becoming a significant issue in the area of nanotoxicology due to the potential risk to humans via the biomagnification process. While previous studies have demonstrated evidence of the trophic transfer of nanoparticles intensive future studies are needed to provide further information on the properties of nanomaterials, the exposure media, and the in vivo mechanisms such as uptake, accumulation, and depuration.

Development and Prospect of Nanomaterials Industries from the Perspective of Mechanical Engineering (기계공학 관점에서 살펴본 나노소재 산업의 발전 및 비전)

  • Kim, Dae Seong;Choi, Mansoo
    • Transactions of the KSME C: Technology and Education
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    • v.5 no.1
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    • pp.69-77
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    • 2017
  • Nanotechnology, along with Information Technology (IT) and Bio-technology (BT), has been regarded as a core area that will drive technological revolution of $21^{st}$ century. South Korea and other countries with advanced scientific and technological research programs are investing heavily in the field, and among its various aspects, nanomaterial industry is considered to be at the heart of this global competition. In this review, we look at nanomaterials industry from the perspective of mechanical engineering. Nanomaterials exhibit unique characteristics differing from those of micron, or sub-micron sized materials, and hence are potentially able to open up new opportunities. Specifically, environmental and biological sciences, energy, and catalysis are areas that are expected to benefit from these developments.

Conceptual Design of Sandglass-like Separator for Immobilized Anionic Radionuclides Using Particle Tracking Based on Computational Fluid Dynamics

  • Park, Tae-Jin;Choi, Young-Chul;Ham, Jiwoong
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.18 no.3
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    • pp.363-372
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    • 2020
  • Anionic radionuclides pose one of the highest risks to the long-term safety assessments of disposal repositories. Therefore, techniques to immobilize and separate such anionic radionuclides are of crucial importance from the viewpoints of safety and waste volume reduction. The main objective of this study is to design a separator with minimum pressure disturbance, based on the concept of a conventional cyclone separator. We hypothesize that the anionic radionuclides can be immobilized onto a nanomaterial-based substrate and that the particles generated in the process can flow via water. These particles are denser than water; hence, they can be trapped within the cyclone-type separator because of its design. We conducted particle tracking analysis using computational fluid dynamics (CFD) for the conventional cyclone separator and studied the effects due to the morphology of the separator. The proposed sandglass-like design of the separator shows promising results (i.e., only one out of 10,000 particles escaped to the outlet from the separation zone). To validate the design, we manufactured a laboratory-scale prototype separator and tested it for iron particles; the efficiency was ca. 99%. Furthermore, using an additional magnetic effect with the separator, we could effectively separate particles with ~100% efficiency. The proposed sandglass-like separator can thus be used for effective separation and recovery of immobilized anionic radionuclides.

Recent Research Progresses in 2D Nanomaterial-based Photodetectors (2D 나노소재기반 광 센서 소자의 최근 연구 동향)

  • Jang, Hye Yeon;Nam, Jae Hyeon;Cho, Byungjin
    • Ceramist
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    • v.22 no.1
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    • pp.36-55
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    • 2019
  • Atomically thin two-dimensional (2D) nanomaterials, including transition metal dichalcogenides (TMDs), graphene, boron nitride, and black phosphorus, have opened up new opportunities for the next generation optoelectronics owing to their unique properties such as high absorbance coefficient, high carrier mobility, tunable band gap, strong light-matter interaction, and flexibility. In this review, photodetectors based on 2D nanomaterials are classified with respect to critical element technology (e.g., active channel, contact, interface, and passivation). We discuss key ideas for improving the performance of the 2D photodetectors. In addition, figure-of-merits (responsivity, detectivity, response speed, and wavelength spectrum range) are compared to evaluate the performance of diverse 2D photodetectors. In order to achieve highly reliable 2D photodetectors, in-depth studies on material synthesis, device structure, and integration process are still essential. We hope that this review article is able to render the inspiration for the breakthrough of the 2D photodetector research field.

Conformal $Al_{2}O_{3}$ nano-coating of ZnO nanowires (ZnO 나노와이어에 ALD 방법으로 균일하게 코팅된 $Al_{2}O_{3}$)

  • Hwang, Joo-Won;Min, Byung-Don;Lee, Jong-Su;Keem, Ki-Hyun;Kang, Myung-Il;Kim, Sang-Sig
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.47-50
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    • 2002
  • ZnO nanowires were coated conformally with aluminum oxide ($Al_{2}O_{3}$) material by atomic layer deposition (ALD). The ZnO nanowires were first synthesized on a Si (100) substrate at $1380^{\circ}C$ from ball-milled ZnO powders by a thermal evaporation procedure with an argon carrier gas without any catalysts; the length and diameter of these ZnO nanowires are $20\sim30{\mu}m$ and $50{\sim}200$ nm, respectively. $Al_{2}O_{3}$ films were then deposited on these ZnO nanowires by ALD at a substrate temperature of $300^{\circ}C$ using trimethylaluminum (TMA) and distilled water ($H_{2}O$). Transmission electron microscopy (TEM) images of the deposited ZnO nanowires revealed that 40nm-thick $Al_{2}O_{3}$ cylindrical shells surround the ZnO nanowires.

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A Synthesis of Spherical Shape $TiO_2-SiO_2$ Complex via Solvothermal Process and Thermal Properties at Non-Isothermal (용매열합성을 이용한 구형 $TiO_2-SiO_2$ 복합체 제조 및 열적특성)

  • Cho Tae-Hwan;Park Seong-Jin
    • Journal of the Microelectronics and Packaging Society
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    • v.12 no.2 s.35
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    • pp.141-147
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    • 2005
  • Nanomaterial $TiO_2-SiO_2$ was synthesized by hydrolysis and condensation process using 2-propanol(2-PrOH) and was characterized by FT-IR, DSC, XRD and FE-SEM. FT-IR spectra were measured to investigate Ti-0-Si absorption peak. DSC thermal analysis results appllied to Ozawa equation were used to calculate to activation energy of crystallization. It was found that the changes of X-ray diffraction patterns and FWHM obtained XRD measurement depended on calcination temperature. In FE-SEM analysis, particle size changed by quantity changes of Ti-alkokide.

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