• 한국자기학회지
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• 제1권1호
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• pp.12-16
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• 1991

F $e_{76-x}$ C $u_{1}$M $o_{x}$S $i_{14}$ $B_{9}$(x=2, 3)비정질합금의 열처리에 따른 자기적특성과 미세구조의 변화에 대해 조사하였다. 이들합금을 500 .deg. C에서 1시간 열처리한 경우, 결정화에 의해 약 20mm의 입경을 갖는 .alpha. -Fe의 초미세결정립 조직으로 변태하였으며, 이때 얻어진 합금의 실효투자율은 8~9*$10^{3}$, 보자력은 3~4A/m정도이었다. 초미세결정합금의 연자기특성을 크게 좌우하는 요소중의 하나가 입경의 크기이며, 우수 한 자성특성을 얻기위해서는 결정립의 미세화가 요구되는 것으로 알려져 있다. 이에 따라 Fe-Cu-Mo-Si-B계 합금의 경우보다 우수한 연자기특성을 얻기 위하여 2단 열처리를 행하였다. 즉, 400 .deg. C에서 1~3시간 저온 열처리 후 500 .deg. C에서 1시간 고온열처리를 하면 입경이 10nm이하로 감소하였으며, 이때 얻어진 합금의 실효투자율은 1.2~ 1.7*$10^{4}$이고 보자력은 ~2A/m이었다. 이와 같은 연자기특성의 향상은 .alpha. -Fe(Si)결정립의 미세화에 따른 평균결정자기이방성 의 감소에 기인하는 것으로 믿어진다.

• Bulletin of the Korean Chemical Society
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• 제30권12호
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• pp.3011-3015
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• 2009

Structural and thermo-analytical studies were carried out to understand the phase formation kinetics of the single phase $Bi_5Ti_3FeO_{15}$ (BTFO) nanocrystals in $Bi_2O_3-Fe_2O_3-TiO_2$, during the polymerized complex (PC) synthesis method. The crystallization of Aurivillius phase $Bi_5Ti_3FeO_{15}$ layered perovskite was found to be initiated and achieved under the temperature conditions in the range of ${\sim}$800 to 1050$^{\circ}C$. The activation energy for grain growth of $Bi_5Ti_3FeO_{15}$ nanocrystals (NCs) was very low in case of NCs formed by PC (2.61 kJ/mol) than that formed by the solid state reaction (SSR) method (10.9 kJ/mol). The energy involved in the phase transformation of Aurivillius phase $Bi_5Ti_3FeO_{15}$ from $Bi_2O_3-Fe_2O_3-TiO_2$ system was ${\sim}$ 69.8 kJ/mol. The formation kinetics study of $Bi_5Ti_3FeO_{15}$ synthesized by SSR and PC methods would not only render a large impact in the nanocrystalline material development but also in achieving highly efficient visible photocatalysts.

• 한국자기학회지
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• 제7권3호
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• pp.140-145
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• 1997

단롤법으로 제조된 비정질 합금 NdFe$_{10.7}$TiB$_{0.3}$의 비정질상과 나노결정상을 X-선 회절법, Mossbauer 분광법, VSM(Vibrating sample magnetometer)을 이용하여 자기적 성질을 연구하였다. 비정질 합금 NdFe$_{10.7}$TiB$_{0.3}$의 Mossbauer spectrum을 13 K 부터 800 K 까지 취하였다. spin파 들뜸에 의한 T/T$_{c}$<0.7 이하에서의 평균초미세 자기장 H$_{hf}$(T)의 변화는 [H$_{hf}$(T)-H$_{hf}$(0)]/H$_{hf}$(0)=-0.46(T/T$_{c}$)$^{5}$ 2/ 같이 나타났다. 전기사중극자 분열값은 Curie 온도 이상의 온도에서 모두 0.46 .+-. 0.01 mm/s로 나타났으며 Curie 온도 미만의 온도에서는 zero임을 알 수 있었다. Curie 온도 (T$_{c}$)와 결정화 온도(T$_{x}$)는 sample을 5 K/min의 비율로 heating 시키며 확인한 결과 T$_{c}$=380 K, T$_{x}$=490 K 임을 알았으며, 770 K에서 .alpha. -Fe 나노 결정상은 약 65%의 면적을 차지하였다. VSM 측정결과 Curie 온도 이상에서 자기 Moment 값의 증가는 .alpha. -Fe 상의 존재 때문이며 이는 Mossbauer 분석결과와 잘 일치하였다.r 분석결과와 잘 일치하였다.

• 한국자기학회:학술대회 개요집
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• 한국자기학회 2006년도 동계학술연구발표회 및 자성 스핀트로닉스 국제학술대회
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• pp.64-65
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• 2006

• 한국세라믹학회지
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• 제49권5호
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• pp.454-460
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• 2012

The nano-sized zirconia powders were synthesized in an impregnation method using pulp and $ZrOCl_2{\cdot}8H_2O$ as an initial material. The synthesized powders were characterized by XRD and FE-SEM. The particle size of the powder was controlled by preparation conditions, such as drying temperature and time. As a result of the various drying and calcination conditions, 30~50 nm sized homogeneous zirconia particles were obtained at $800^{\circ}C$ for 1 h. Crystallization and the rapid growth of particles were accelerated with increasing calcination temperature and time. Tetragonal phase generated below $800^{\circ}C$ were transferred to monoclinic phase with increasing calcination temperature and time. Moreover, above $800^{\circ}C$, heat treatment time had very large influence on the particle growth, and the change of drying condition also had large influence on the growth of a crystal.

• Journal of Magnetics
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• 제9권2호
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• pp.65-68
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• 2004

Magnetically soft nanomaterials obtained by controlled crystallisation of metallic glasses are the newest group of materials for inductive components. In particular, research is carried out in the field of alloys for high temperature applications. This kind of materials must meet two basic requirements: good magnetic properties and stability of properties and structure. In the present work the magnetic properties and structure of Fe-Co-Hf-Zr-Cu-B (HIDTPERM-type) alloys were investigated, as well as their stability. Differential thermal analysis, (DTA), X-ray diffractometry (XRD), transmission electron microscopy (TEM), magnetometry (VSM) and quasistatic hysteresis loop recording were used to characterise structure and properties of the alloys investigated. Optimisation against properties and their stability was performed, resulting in formulation of chemical composition of the optimum alloy, as well as its heat treatment.

• 한국세라믹학회지
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• 제50권3호
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• pp.212-217
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• 2013

Ultra hard TiN coatings were fabricated by DC and ICP (inductively coupled plasma) magnetron sputtering techniques. The effects of ICP power, ranging from 0 to 300 W, on the coating microstructure, crystallographic, and mechanical properties were systematically investigated with FE-SEM, AFM, HR-XRD and nanoindentation. The results show that ICP power has a significant influence on the coating microstructure and mechanical properties of TiN coatings. With an increasing ICP power, the film microstructure evolves from an apparent columnar structure to a highly dense one. Grain sizes of TiN coatings decreased from 12.6 nm to 8.7 nm with an increase of the ICP power. A maximum nanohardness of 67.6 GPa was obtained for the coatings deposited at an ICP power of 300 W. The crystal structure and preferred orientation in the TiN coatings also varied with the ICP power, exerting an effective influence on film nanohardness.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2017년도 춘계학술대회 논문집
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• pp.103.2-103.2
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• 2017

Nanocrystalline HfN coatings were prepared by reactively sputtering Hf metal target with N2 gas using a magnetron sputtering system operated in DC and ABPP (asymmetric bipolar pulsed plasma) condition with various duties and frequencies. The effects of duty and frequency, ranging from 75 to 100 % and 5 to 50 kHz, on the coating microstructure, crystallographic and mechanical properties were systematically investigated with FE-SEM, AFM, XRD and nanoindentation. The results show that pulsed plasma has a significant influence on coating microstructure and mechanical properties of HfN coatings. Coating microstructure evolves from the columnar structure to a highly dense one as duty decreases. Average grain size and nano hardness of HfN coatings were also investigated with various pulsed conditions.

• 센서학회지
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• 제16권5호
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• pp.355-360
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• 2007

Highly sensitive thick film ethanol gas sensors based on a nanocrystalline $In_{2}O_{3}$ were fabricated by painting method on alumina substrates. The crystal structure of the $In_{2}O_{3}$ powder was characterised by XRD analysis. The microstructure of the films were characterised using FE-SEM. The experimental results of the ethanol gas sensing characteristics indicated that the undoped $In_{2}O_{3}$ thick film has a high sensitivity. The sensitivity of the film heat treated at $400^{\circ}C$ for 2 hrs. was as high as 32.73 at an operating temperature of $200^{\circ}C$ to 1000 ppm ethanol gas in air.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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• pp.457-457
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• 2012

We presented plasma processing using a DC Arc Plasmatron for diamond deposition on Al2O3 ceramic substrates. Plasma surface treatments were conducted to improve deposition condition before processing for diamond deposition. The Al2O3 ceramic substrates deposited, $5{\times}15mm^2$, were investigated by Scanning Electron Microscopy (SEM), Fourier Transform Infrared Spectroscopy (FTIR) and X-ray Diffraction (XRD). Properties of diamond (111), (220) and (311) peaks were shown in XRD. We identified nanocrystalline diamond films on substrates. The results showed that deposition rate was approximately $2.2{\mu}m/h$ after plasma surface treatments. Comparing the above result with a common processing, deposition rate was improved. Also, the surface condition was improved more than a common processing for diamond deposition on Al2O3 ceramic substrates.