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http://dx.doi.org/10.4191/kcers.2012.49.5.454

Preparation of Nano-sized Zirconia Powders by the Impregnation Method  

Han, Cheong-Hwa (Department of Advanced Materials & Chemical Engineering, Halla University)
Kim, Soo-Jong (Department of Advanced Materials & Chemical Engineering, Halla University)
Publication Information
Journal of the Korean Ceramic Society / v.49, no.5, 2012 , pp. 454-460 More about this Journal
Abstract
The nano-sized zirconia powders were synthesized in an impregnation method using pulp and $ZrOCl_2{\cdot}8H_2O$ as an initial material. The synthesized powders were characterized by XRD and FE-SEM. The particle size of the powder was controlled by preparation conditions, such as drying temperature and time. As a result of the various drying and calcination conditions, 30~50 nm sized homogeneous zirconia particles were obtained at $800^{\circ}C$ for 1 h. Crystallization and the rapid growth of particles were accelerated with increasing calcination temperature and time. Tetragonal phase generated below $800^{\circ}C$ were transferred to monoclinic phase with increasing calcination temperature and time. Moreover, above $800^{\circ}C$, heat treatment time had very large influence on the particle growth, and the change of drying condition also had large influence on the growth of a crystal.
Keywords
$ZrO_2$; Nanocrystalline; Impregnation method;
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Times Cited By KSCI : 11  (Citation Analysis)
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1 B. Y. Sung, C. H. Han, and H. D. Park, "Effect of pH and Drying Temperature on Luminescent Properties of $Zn_2SiO_4$:Mn,Al Green Phophors by Sol-Gel Technique (in Korean)," J. Kor. Ceram. Soc., 42 [5] 333-37 (2005).   DOI
2 W. J. Park, M. K. Jung, J. W. Moon, T. Masaki, S. J. Im, and D. H. Yoon, "Enhanced Luminescent of Y(P,V)$O_4:Eu^{3+}$ Nano Phosphors in Porous Cellulose Fibers by Facile Liquid Phase Precursor Synthesis," J. Nanosci. Nanotechnol., 9 4371-75 (2009).   DOI
3 C. H. Han, and S. J. Kim, "Preparation and Luminescence Properties of Y(P,V)$O_4:Eu^{3+}$ Phosphor using Impregnation Method (in Korean)," J. Kor. Ceram. Soc., 48 [6] 565-70 (2011).   과학기술학회마을   DOI
4 S. Y. Han, D. K. Lee, S. J. Kim, C. H. Han, and T. Masaki, "Preparation of PDP Red Phosphors by Impregnation Method and their Luminescence Properties," Trans. Electr. Electron. Mater., 9 [2] 57-61 (2008).   과학기술학회마을   DOI
5 S. J. Kim, and H. S. Kwon, "Synthesis and Photo Luminescent Characteristics of $SrAl_2O_4:Eu^{2+},\;Dy^{3+}$ Phosphor using Polymer Matrix (in Korean)," J. Kor. Inst. Electr. Electron. Mater. Eng., 20 [8] 671-79 (2007).   과학기술학회마을   DOI   ScienceOn
6 C. Y. Tai, and B. Y. Hsiao, "Characterization of Zirconia Powder Synthesized via Reverse Microemulsion Precipitation," Chem. Eng. Commun., 192 1525-40 (2005).   DOI
7 J. Feng, J. Wang, S. C. Ng, C. H. Chew, and L. M. Gan, "Ultrafine Zirconia Powders Via Microemulsion Processing Route," Nanostruct. Mater., 8 [4] 499-505 (1997).   DOI
8 G. R. Duan, X. J. Yang, G. H. Huang, L. D. Lu, and X. Wang, "Water/span80/Triton X-100/n-hexyl Alcohol/noctane Microemulsion System and the Study of Its Application for Preparing Nanosized Zirconia," Mater Lett., 60 1582-87 (2006).   DOI
9 S. B. Jun, D. K. Lee, S. J. Kim, T. Masaki, and C. H. Han, "Preparation and Luminescence Properties of PDP Green Phosphors using Polymer Matrix Technique," Electr. Electron. Mater., 8 [3] 121-24 (2007).   DOI
10 G. G. Hong, and H. L. Lee, "Properties of $Al_2O_3-15v/oZrO_2(+3m/o\;Y_2O_3)$ Powder Prepared by Co-Precipitation Method (in Korean)," J. Kor. Ceram. Soc., 26 [2] 210-20 (1989).
11 N. Chandra, D. K. Singh, M. Sharma, R. K. Upadhyay, S. S. Amritphale, and S. K. Sanghi, "Synthesis and Characterization of Nano-sized Zirconia Powder Synthesized by Single Emulsion-assisted Diredct Precipitation," J. Colloid and Interface Sci., 342 327-32 (2010).   DOI
12 C. Y. Tai, B. Y. Hsiao, and H. Y. Chiu, "Preparation of Silazane Grafted Yttria-stabilized Zirconia Nanocrystals via water/CTAB/hexanol Reverse Microemulsion," Mater. Lett., 61 834-36 (2007).   DOI
13 J. S. Yoon, D. I. Lee, Y. J. Oh, and H. S. Lee, "A Synthesis and Characteristics for Zirconia Powders by Coprecipitation Method: III. The Properties and Sinterabilities of $ZrO_2-Y_2O_3-Bi_2O_3$ (in Korean.)," J. Kor. Ceram. Soc., 26 [5] 655- 60 (1989).   과학기술학회마을
14 C. Y. Tai, M. H. Lee, and Y. C. Wu, "Control of Zirconia Particle Size by Using Two-emulsion Precipitation Technique," Chem. Eng. Sci., 56 2389-98 (2001).   DOI
15 J. S. Yoon, and H. S. Lee, "A Synthesis and Characteristics for Zirconia Powders by Coprecipitation Method: II. The Properties and Sinterabilites of $ZrO_2-3m/oY_2O_3$ (in Korean)," J. Kor. Ceram. Soc., 27 [4] 532-38 (1989).
16 D. G. Bang, J. S. Yoon, and H. S. Lee, "Synthesis and Characteristics for $ZrO_2-Y_2O_3 $ System Powders by Correcipitation Method: . The Properties and Sinterabilities of $ZrO_2-8m/oY_2O_3$ (in Korean)," J. Kor. Ceram. Soc., 26 [2] 242-48 (1989).
17 K. Y. Oh, "Properties of Yittria Stabilized Zirconia-Alumina Powders Prepared by Coprecipitation Method (in Korean)," J. Kor. Ceram. Soc., 34 [11] 1113-20 (1997).
18 M. Dechamps1, B. Djuriçic, and S. Pickering, "Structure of Zirconia Prepared by Homogeneous Precipitation," J. Am. Ceram. Soc., 78 [11] 2873-80 (1995).   DOI
19 K. Matsui, H. Suzuki, and M. Ohagi, "Raman Spectroscopic Studies on the Formation Mechanism of Hydrous-Zirconia Fine Particles," J. Am. Ceram. Soc., 78 [1] 146-52 (1995).   DOI
20 F. Haase, and F. Sauer, "The Surface Structure of Sulfated Zirconia:Periodic ab Initio Study of Sulfuric Acid Adsorbed on $ZrO_2$(101) and $ZrO_2$(001)," J. Am. Ceram. Soc., 120 13503-12 (1998).   DOI
21 E. Tani, M. Yoshimura, and S. Somiya, "Hydrothermal Preparation of Ultrafine Monoclinic $ZrO_2$ Powder," J. Am. Ceram. Soc., 64 [12] C-181 (1981).
22 H. Yoon, M. Y. Shin, and J. J. Ahn, "Properties of Yttria Partially Stabilized Zirconia Nano-Powders Prepared by Coprecipitation Method (in Korean)," J. Miner. Soc. Kor., 19 [2] 81-8 (2006).   과학기술학회마을
23 J. T. Kim, G. G. Hong, and H. L. Lee, "Properties of the Powders of the System $Al_2O_3-ZrO_2-Y_2O_3$ Prepared by Precipitation Method (in Korean)," J. Kor. Ceram. Soc., 25 [2] 117-24 (1988)   과학기술학회마을
24 G. Dell'Agli and G. Mascolo, "Hydrothermal Synthesis of $ZrO_2-Y_2O_3$ Solid Solutions at Low Temperature," J. Eur. Ceram. Soc., 20 139-45 (2000).   DOI
25 E. Tani, M. Yoshimura, and S. Somiya, "Formation of Ultrafine Tetragonal $ZrO_2$ Powder Under Hydrothermal Conditions," J. Am. Ceram. Soc., 66 [1] 11-14 (1983).   DOI
26 K. H. Lee, B. H. Le, D. Masaki, A. Kiyosi, W. H. Kang, and H. S. Park., "Hydrothermal Precipitation of PZT Powder (in Korean)," J. Kor. Ceram. Soc., 24 [4] 397-403 (1987).   과학기술학회마을
27 H. Kumazawa, T. Inoue, and E. Sada, "Synthesis of Fine Spherical Zirconia Particles by Controlled Hydrolysis of Zirconium Alkoxide in the High Temperature Range Above 50," Chem. Eng. J., 55 93-96 (1994).
28 H. J. Noh, J. K. Lee, D. S. Seo, and K. H. Hwang, "Preparation of Zirconia Nanocrystalline Powder by the Hydrothermal Treatment at Low Temperature (in Korean)," J. Kor. Ceram. Soc., 39 [3] 308-14 (2002).   DOI
29 W. Pyda, K. Haberko, and M. M. Bucko, "Hydrothermal Crystallization of Zirconia and Zirconia Solid Solutions," J. Am. Ceram. Soc., 74 [10] 2422-29 (1991).
30 H. Nishzawa, N. Yamasaki, and K. Matsuoka, "Crystallization and Transformation of Zirconia Under Hydrothermal Conditions," J. Am. Ceram. Soc., 65 [7] 343-46 (1982).   DOI
31 B. Fegley, Jr. P. White, and H. K. Bowen, "Processing and Characterization of $ZrO_2$ and Y-Doped $ZrO_2$ Powders," J. Am. Ceram. Soc., 64 [8] 1115-20 (1985).
32 W. Stober, A. Fink, and E. Bohn "Controlled Growth of Monodisperse Silica Spheres in the Micron Size Range," J. Colloid and Interface Sci., 26 62-69 (1968).   DOI   ScienceOn
33 M. Laurent, U. Schreiner, P. A. Langjahr, A. E. Glazounov, and M. J. Hoffman, "Microstructural and Electrical Characterization of La-doped PZT Ceramics Prepared by a Precursor Route," J. Eur. Ceram. Soc., 21 1495-98 (2001).   DOI
34 B. L. Kirsch, and S. H. Tolbert, "Stabilization of Isolated Hydrous Amorphous and Tetragonal Zirconia Nanoparticles Through the Formation of a Passivating Alumina Shell," Adv. Funct. Mater., 13 [4] 281-88 (2003).   DOI
35 J. Rhee, and D. S. Jo, "Synthesis of Monodispersed Zirconia Powder by Hydrolysis of Zirconium Alkoxides (in Korean)," J. Kor. Ceram. Soc., 28 [2] 167-75 (1991).   과학기술학회마을
36 G. K. Chuah, S. Jaenicke, S. A. Cheong, and K. S. Chan, "The Influence of Preparation Conditions on the Surface Area of Zirconia," Appl. Catalysis A, 145 267-84 (1996).   DOI   ScienceOn
37 J. D. Kim, S. Hana, S. Kawagoe, K. Sasaki, and T. Hata, "Preparation of Perovskite, Pb(Zr, Ti)$O_3$ Thin-films on YSZ(111)/Si(111) Substrates by Post-deposition Annealing," Thin Solid Films, 385 293-97 (2001).   DOI
38 S. Shukla and S. Seal, "Mechanisms of Room Temperature Metastable Tetragonal Phase Stabilisation in Zirconia," Int. Mater. Rev., 50 [1] 45-64 (2005).   DOI
39 G. K. Chuah, "An Investigation into the Preparation of High Surface Area Zirconia," Catalysis Today, 49 131-39 (1999).   DOI
40 Nguyen Q. Minh, "Ceramic Fuel Cells," J. Am. Ceram. Soc., 76 [3] 563-88 (1993).   DOI