• 제목/요약/키워드: Nanocrystalline Fe

검색결과 209건 처리시간 0.026초

$TiO_2$전극의 제조법에 따른 염료감응형 태양전지의 효율비교 (Comparison of Efficiency between Dye-Sensitized Solar Cells with $TiO_2$ Electrode Manufactured by different Method)

  • 한정희;백형렬;박경희;구할본
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 영호남 합동 학술대회 및 춘계학술대회 논문집 센서 박막 기술교육
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    • pp.109-110
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    • 2006
  • Nanocrystalline $TiO_2$ electrode were prepared by spray-printing in order to efficiency and improved fill factor. Different compositions of nanocrystalline $TiO_2$ pastes are described, based on $TiO_2$ powder made by ourselves. The produced by spray printing $TiO_2$ films were compare with the produced by squeeze printing $TiO_2$ films and was studied in the light of static I-V characteristics. The produced $TiO_2$ films are extensively characterized by means of spectroscopy(Ramon, XRD) and microscopy(FE-SEM).

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Electromagnetic Wave Absorption Properties in Fe-based Nanocrystalline P/M Sheets with Carbon Black and BaTiO3 Additives

  • Kim, Mi-Rae;Park, Won-Wook
    • 한국분말재료학회지
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    • 제16권1호
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    • pp.33-36
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    • 2009
  • In order to increase the magnetic loss for electromagnetic(EM) wave absorption, the soft magnetic $Fe_{73}Si_{16}B_7Nb_3Cu_1$(at%) alloy strip was used as the basic material in this study. The melt-spun strip was pulverized using an attrition mill, and the pulverized flake-shaped powder was crystallized at $540^{\circ}C$ for 1h to obtain the optimum grain size. The Fe-based powder was mixed with 2 wt% $BaTiO_3$, $0.3{\sim}0.6$ wt% carbon black, and polymer-based binders for the improvement of electromagnetic wave absorption properties. The mixture powders were tape-cast and dried to form the absorption sheets. After drying at $100^{\circ}C$ for 1h, the sheets of 0.5 mm in thickness were made by rolling at $60^{\circ}C$, and cut into toroidal shape to measure the absorption properties of samples. The characteristics including permittivity, permeability and power loss were measured using a Network Analyzer(N5230A). Consequently, the properties of electromagnetic wave absorber were improved with the addition of both $BaTiO_3$ and carbon black powder, which was caused by the increased dielectric loss of the additive powders.

THE MAGNETOSTRICTIVE PROPERTIES OF Dy-Fe-B ALLOYS WITH NANOCRYSTALLINE GRAIN STRUCTURE

  • Lim, S.H.;Kim, S.R.;Noh, T.H.;Lee, S.R.;Kang, I.K.
    • 한국자기학회지
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    • 제5권5호
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    • pp.795-799
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    • 1995
  • The magnetostriction versus field (${\lambda}-H$) curves for the melt-spun ribbons of $Dy_{x}{(Fe_{1-y}B_{y})}_{1-x}$ (x=0.2, 0.25, 0.3; y=0, 0.05, 0.1, 0.15, 0.2) alloys are measured systematically at various wheel speeds ranging from 10 to 50 m/sec. The ${\lambda}-H$ curves in most cases vary sensitively with the wheel speed and, in the wheel speed range where no amorphous phase is formed, the magnetic softness improves rather continuously with the wheel speed. This result is considered to be due to the reduced grain size with increasing wheel speed, which was confirmed by X-ray diffraction and transmission electron microscopy. In particular, homogeneous and ultrafine grains with size of about 10 nm are formed even in the as-spun state when the $Dy_{0.3}{(Fe_{1-y}B_{y})}_{0.7}$ alloys are quenched at the wheel speed of 30 m/sec (for the alloy with y=0.2) or 40 m/sec (for the alloys with $y{\leq}0.15$) and the ribbons having the nanocrystalline grain structure exhibit good magnetostrictive characteristics.

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THE MAGNETIC PROPERTIES OF ULTRATHIN $Fe_{84}B_{9}Nb_{7}$ NANOCRYSTALLINE ALLOY

  • Lee, J.S.;Park, J.Y.;Kim, K.Y.;Noh, T.H.;Kang, I.K.;Yoo, Y.C.
    • 한국자기학회지
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    • 제5권5호
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    • pp.500-503
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    • 1995
  • The magnetic properties of ultrathin $Fe_{84}B_{9}Nb_{7}$ nanocrystalline ribbon alloy with the thickness of $7-14\;\mu\textrm{m}$ were investigated. It was found that the effective permeability at the frequency over 100 kHz increased with decreasing ribbon thickness. Moreover the core loss decreased considerably with reduction of the ribbon thickness. The effective permeability at 1 MHz and the core loss at 1 MHz and 0.1 T for $Fe_{84}B_{9}Nb_{7}$ alloy with the thickness of $7\;\mu\textrm{m}$ were 3,700 and 2.7 W/cc, respectively. The reduction of thickness to less than $10\;\mu\textrm{m}$ was found to be very effective in obtaining high permeability and low core loss in the MHz frequency range. It was considered that the improvement of magnetic properties in the high frequency range was due to the reduction of the eddy current.

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Effects of Mn Doping on Structural and Magnetic Properties of Multiferroic BiFeO3 Nanograins Made by Sol-gel Method

  • Raghavender, A.T.;Hong, Nguyen Hoa
    • Journal of Magnetics
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    • 제16권1호
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    • pp.19-22
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    • 2011
  • [ $BiFeO_3$ ]is a multiferroic material that attracts attentions of many research groups due to its potential as being ferroelectric and ferromagnetic above room temperature. We have prepared both undoped- and Mn-doped $BiFeO_3$ by sol-gel auto-ignition method. Doping of Mn has resulted in decreasing grain size from 60 to 32 nm. X-ray diffraction data show that the samples are pure and single-phase. Infrared measurements on $BiFeO_3$ and Mn-doped $BiFeO_3$ revealed intrinsic stretching vibrations of tetrahedral sites of $Fe^{3+}$-O and of octahedral $Bi^{3+}$-O as well. On the other hand, as the Mn concentration increases, the magnetic moment of $BiFeO_3$ increases. It gives some suggestions in manipulating structural and magnetic properties of $BiFeO_3$ by doping Mn.

초미세결정립 $ Fe_{73.5}Cu_{1}Nb_{3}Si_{16.5}B_6$ 합금의 $M\""{o}ssbauer$ 효과 연구 ($M\""{o}ssbauer$ Effet Studies on Nanocrystalline $Fe_{73.5}Cu_{1}Nb_{3}Si_{16.5}B_6$ Alloy)

  • 신영남;김재경;양재석;조익한;강신규
    • 한국자기학회지
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    • 제4권1호
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    • pp.12-19
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    • 1994
  • 비정질 $Fe_{73.5}Cu_{1}Nb_{3}Si_{16.5}B_{6}$ 합금의 $552^{\circ}C$에서 등온열처리시간에 따른 결정화 거동을 $M\"{o}ssbauer$ 분광법으로 연구하였다. 열처리된 시료는 $Do_{3}-FeSi$ 초미세결정립, Cu-cluster 및 비정질이 공존함이 $M\"{o}ssbauer$ spectrum 분석에 의해 확인되었다. 결정화 초기단계에 Cu-cluster가 형성되기 때문에 FeSi 초미세결정립의 Si함량은 높아지며, 열처리시간이 60분이 될 때까지 Si함량은 감소하는데 이는 FeSi 초미세결정립의 평균초미세자기장의 증가를 일으키며, 이후 Si함량은 거의 일정하다. 60분 이후의 열처리에서 FeSi 초미세결정립과 잔류비정질의 체적분율이 미소하게 변화함에도 잔류비정질의 평균초미세자기장이 감소하는 것은 잔류비정질에서의 Nb, B원자의 존재비의 증가에 기인된다. $552^{\circ}C$에서 60분 열처리 할 경우 FeSi 초미세결정립과 잔류비정질의 초미세자기장의 방향이 모두 무질서하게 분포된다. FeSi 초미세결정립과 Cu-cluster의 Avrami지수는 각각 0.51, 0.65, 잠복기는 각각 2.4분, 0.8분, 활성화에너지는 각각 2.35 eV, 2.44 eV이며, Cu-cluster가 FeSi 초미세결정립보다 먼저 생성된다는 것은 Cu 원자가 FeSi 초미세결정립의 생성을 촉진시킨다는 해석과 부합한다.

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