• Title/Summary/Keyword: Nano-Sized

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Explosion Properties of Nano and Micro-sized Aluminium Particles (나노 및 마이크로 입자 알루미늄의 폭발 특성)

  • Han, Ou-Sup;Lee, Keun-Won
    • Journal of the Korean Institute of Gas
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    • v.18 no.5
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    • pp.20-25
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    • 2014
  • Explosion characteristics of micro-sized aluminum dusts had been studied by many researchers, but the research of nano-sized aluminum dusts were very insufficient. In this study, an experimental investigation was carried out on the influences of nano and micro-sized aluminum dusts (70 nm, 100 nm, $6{\mu}m$, $15{\mu}m$) on dust explosion properties of aluminum particles by using 20 L explosion apparatus. With decreasing of particle size in suspended aluminum dusts, the LEC (lower explosion concentration) of nano-sized aluminum is lower than that of micro-sized aluminum. The particle size change of nano-sized aluminum dusts seems no obvious explosion differences than that of micro-sized aluminum dusts. From the observation of nano-sized aluminum particles by TEM (Transmission Electron Microscopy), it is estimated that increase of particles aggregation may have effects on the explosion characteristics of aluminum nanopowders.

Synthesis of PMMA Plate with Nano-Sized Pattern on Anodized Aluminum Oxide Template (AAO 나노기공을 형틀로 이용한 PMMA 나노패턴 형성 기술)

  • Lee, B.W.;Lee, K.W.;Lee, C.H.;Lee, T.S.;Hong, C.;Chung, Jae-Hoon;Kim, C.K.;Lee, J.H.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.382-383
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    • 2007
  • PMMA plate with nano-sized pattern was synthesized on anodized aluminum oxide template by bluk polymerization method. Anodized aluminum oxide was used as a template to synthesize the PMMA plate with nano-sized pattern. The polymerization of MMA was performed at $75-79^{\circ}C$. It is verified from SPM results that the nano-sized pattern on synthesized PMMA plate was well transferred from that of anodized aluminum oxide template.

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Fabrication of Nanometer-sized Pattern on PMMA Plate Using AAO Membrane As a Template for Nano Imprint Lithography (AAO 나노기공을 나노 임프린트 리소그래피의 형틀로 이용한 PMMA 나노패턴 형성 기술)

  • Lee, Byoung-Wook;Hong, Chin-Soo;Kim, Chang-Kyo
    • Journal of Institute of Control, Robotics and Systems
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    • v.14 no.5
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    • pp.420-425
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    • 2008
  • PMMA light guiding plate with nano-sized pattern was fabricated using anodized aluminum oxide membrane as a template for nano imprint lithography. Nano-sized pore arrays were prepared by the self-organization processes of the anodic oxidation using the aluminum plate with 99.999% purity. Since the aluminum plate has a rough surface, the aluminum plate with thickness of 1mm was anodized after the pre-treatments of chemical polishing, and electrochemical polishing. The surface morphology of the alumina obtained by the first anodization process was controlled by the concentration of electrochemical solution during the first anodization. The surface morphology of the alumina was also changed according to temperature of the solution during chemical polishing performed after first anodization. The pore widening process was employed for obtaining the one-channel with flat surface and height of the channel because the pores of the alumina membrane prepared by the fixed voltage method shows the structure of two-channel with rough surface. It is shown from SPM results that the nano-sized pattern on PMMA light guiding plate fabricated by nano imprint lithography method was well transferred from that of anodized aluminum oxide template.

Stability/instability of the graphene reinforced nano-sized shell employing modified couple stress model

  • Yao, Zhigang;Xie, Hui;Wang, Yulei
    • Wind and Structures
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    • v.32 no.1
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    • pp.31-46
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    • 2021
  • The current research deals with, stability/instability and cylindrical composite nano-scaled shell's resonance frequency filled by graphene nanoplatelets (GPLs) under various thermal conditions (linear and nonlinear thermal loadings). The piece-wise GPL-reinforced composites' material properties change through the orientation of cylindrical nano-sized shell's thickness as the temperature changes. Moreover, in order to model all layers' efficient material properties, nanomechanical model of Halpin-Tsai has been applied. A functionally modified couple stress model (FMCS) has been employed to simulate GPLRC nano-sized shell's size dependency. It is firstly investigated that reaching the relative frequency's percentage to 30% would lead to thermal buckling. The current study's originality is in considering the multifarious influences of GPLRC and thermal loading along with FMCS on GPLRC nano-scaled shell's resonance frequencies, relative frequency, dynamic deflection, and thermal buckling. Furthermore, Hamilton's principle is applied to achieve boundary conditions (BCs) and governing motion equations, while the mentioned equations are solved using an analytical approach. The outcomes reveal that a range of distributions in temperature and other mechanical and configurational characteristics have an essential contribution in GPLRC cylindrical nano-scaled shell's relative frequency change, resonance frequency, stability/instability, and dynamic deflection. The current study's outcomes are practical assumptions for materials science designing, nano-mechanical, and micromechanical systems such as micro-sized sensors and actuators.

Nano-sized Drug Carriers and Key Factors for Lymphatic Delivery

  • Choi, Ji-Hoon;Lee, Yong-Bok
    • Journal of Pharmaceutical Investigation
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    • v.40 no.spc
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    • pp.75-82
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    • 2010
  • Specific diseases like cancer and acquired immune deficiency syndrome (AIDS) occur at various organs including lymphatics and spread through lymphatic system. Thus, if therapeutic agents for such diseases are more distributed or targeted to lymphatic system, we can obtain several advantages like reduction of systemic side effect and increase of efficacy. For these reasons, much interest has been focused on the nature of lymphatics and a lot of studies for lymphatic delivery of drugs have been carried out. Because lymphatics consist of single layer endothelium and have high permeability compared with blood capillaries, especially, the studies using nano-sized carriers have been performed. Polymeric nano-particle, liposome, and lipid-based vehicle have been adopted for lymphatic delivery as carriers. According to the administration route and the kind of carrier, the extent of lymphatic delivery efficiency of nano-sized carriers has been changed and influenced by several factors such as size, charge, hydrophobicity and surface feature of carrier. In this review, we summarized the key factors which affect lymphatic uptake and the major features of carriers for achieving the lymphatic delivery. Lymphatic delivery of drug using nano-sized carriers has many fold improved ability of lymphatic delivery compared with that of conventional dosage forms, but it has not shown whole lymph selectivity yet. Even though nano-sized carriers still have the potential and worth to study as lymphatic drug delivery technology as before, full understanding of delivery mechanism and influencing factors, and setting of pharmacokinetic model are required for more ideal lymphatic delivery of drug.

Technology to Form Nano-sized Pattern on Light Guiding Plate Using MmSH Injection Molding Method (MmSH 사출성형법을 이용한 도광판용 나노패턴 형성기술 개발)

  • Lee, B.W.;Lee, J.H.;Lee, T.S.;Lee, K.W.;Kim, D.H.;Kim, Y.K.;Hong, C.;Jung, J.H.;Kim, C.K.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.416-417
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    • 2007
  • MmSH injection molding method to fabricate light guiding plate with nano-sized pattern was developed. A stamper was fabricated through photolithography, dry etching, and electroplating processes. While the stamper with nano-sized pattern in mold was kept at $180^{\circ}C$ during injection process, that was cooled down to $90^{\circ}C$ quickly after the injection process. The nano-sized pattern on light guiding plate processed by MmSH injection molding method was well transferred from stamper compared to that processed by conventional injection molding process.

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A study on the synthesis and characterization of PI/$\textrm{TiO}_2$ nano-composite (폴리이미드/$\textrm{TiO}_2$ 나노 복합재의 합성 및 특성에 관한 연구)

  • 이중희;이봉신;허석봉
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2001.10a
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    • pp.137-140
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    • 2001
  • Oragnic/inorganic hybrid materials prepared by sol-gel method have rapidly become a fasci nating research field in materials science. In this study, Polyimide/$\textrm{TiO}_2$ composites were synthesized from nano-sized anatase $\textrm{TiO}_2$ and two types of Polyimide (BTDA-PPD, PMDA-ODA) by Sol-gel method. Nano-sized $\textrm{TiO}_2$ particles were prepared from $\textrm{TiOEt}_4$ solution. The composites were charcaterized by using XRD, TGA, IR, TEM, and Atomic Force Microscope(AFM). $\textrm{TiO}_2$ nano particles were dispersed well in polyimide matrix and the thermal stability of polyimide was improved with $\textrm{TiO}_2$ nano-sized particles.

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High power lithium ion polymer batteries (IV): Nano-sized cathode materials manufactured in a single synthetic step using united eutectic self-mixing method

  • An, Uk;Ra, Dong-Il;Lee, Beom-Jae;Han, Gyu-Seung
    • Rubber Technology
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    • v.6 no.2
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    • pp.91-98
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    • 2005
  • Nano-sized cathode materials for high power lithium ion polymer battery are easily and economically prepared using united eutectic self-mixing method without any artificial mixing procedures of reactants and ultra-miniaturization of products. While the micro-sized $LiNi_{0.7}Co_{0.3}O_2$ exhibits the discharge capacities of 167.8 mAh/g at 0.1C and 142.5 mAh/g at 3.0C, those of the nano-sized $LiNi_{0.7}Co_{0.3}O_2$ are 170.8 mAh/g at 0.1C and 159.3 mAh/g at 3.0C. In the case of $LiCoO_2$, the micro-sized $LiCoO_2$ exhibits the discharge capacities of 134.8 mAh/g at 0.1C and 118.6 mAh/g at 5.0C. Differently, the nano-sized $LiCoO_2$ exhibits the discharge capacities of 137.2 mAh/g at 0.1C and 131.7 mAh/g at 5.0C.

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Mechanism for Ni/YSZ Nano-composite Anode from Spherical Core-shell Formation

  • An, Yong-Tae;Choe, Byeong-Hyeon;Ji, Mi-Jeong;Gu, Ja-Bin;Hwang, Hae-Jin
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.10a
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    • pp.31.2-31.2
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    • 2011
  • We studied a method of manufacturing an anode to restrict contraction in reducing NiO/YSZ by uniformly mixing. In order to mix Ni and YSZ, a sub-micron Ni core surface was coated at high-speed by a mixture of nano-sized YSZ and a spherical core-shell was subsequently formed. The micron-sized core-shell anode powder was then heat treated at $400{\sim}1,450^{\circ}C$ in an air atmosphere and Ni was extruded and synthesized in nano-size. Subsequently, when the nano-sized mixture of the anode was heat treated and maintained at a temperature of $1,450^{\circ}C$, the anode was manufactured, where Ni and YSZ were uniformly distributed with the nano-structure. According to the nano-sized anode powder synthesis process, Ni particles were oxidized at $400{\sim}500^{\circ}C$ and became spherical by surface tension. In the case of the spherical core Ni powder, the heat treatment temperature rose to $1,250^{\circ}C$ and then a gap between the internal and external pressures occurred due to thermal and tensile stresses. A crack subsequently appeared on the surface, and the heat treatment temperature was increased continuously to increase the pressure gap and then the core Ni extruded as a nano-sized powder, Ni and YSZ uniformly distributed. It was found that the anode of 50~200 nm with a consistent structure obtained in this study has electric conductivity that is approximately 3 times larger than that of a commercial anode.

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Nano-sized $Gd_{2}O_{3}:Eu$ phosphor particles of high brightness

  • Lee, Chang-Hee;Roh, Hyun-Sook;Kang, Yun-Chan;Park, Hee-Dong;Park, Seung-Bin
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.791-794
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    • 2003
  • To synthesize $Gd_{2}O_{3}:Eu$ phosphor powder of nano size and high luminescence efficiency under UV (ultraviolet) and VUV (vacuum ultraviolet) light, organic additives such as citric acid and ethylene glycol and $Na_{2}CO_{3}$ flux were introduced in large-scale spray pyrolysis and critical conditions for forming nano-sized particles were investigated. The $Gd_{2}O_{3}:Eu$ phosphor particles prepared from solutions with organic additives such as citric acid and ethylene glycol had micron size and spherical shape. However, the particles prepared from polymeric precursor solution with $Na_{2}CO_{3}$ flux had nano size and non-aggregation characteristics. The as-prepared spherical particles with micron size turned into nano-sized particles during post-treatment by recrystallization process. The nano-sized $Gd_{2}O_{3}:Eu$ phosphor particles showed higher brightness than the commercial $Y_2O_3:Eu$ phosphor product under both UV light of 254nm and VUV light of 147 nm.

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