• Title/Summary/Keyword: Nano-Droplet

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Ostwald Ripening in Hydrogenated Lecithin-stabilized Oil-in-Water Nano-emulsions (수첨 레시틴으로 안정화된 오일/물 나노에멀젼에서의 Ostwald Ripening)

  • Cho, Wan-Goo;Yang, Hee-Jung;Park, Soo-Nam
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.34 no.1
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    • pp.9-14
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    • 2008
  • Formation of oil-in-water nano-emulsions has been studied in oil/hydrogenated lecithin/water systems by two shear different instrument. The influence of surfactant concentration on nano-emulsion droplet size and stability has been studied. Droplet size was determined by dynamic light scattering, and nano-emulsion stability was evaluated by measuring the variation of droplet size as a function of time. The results obtained showed that the breakdown process of nano-emulsions studied could be attributed to Ostwald ripening. An increase of nano-emulsion instability with increase in surfactant concentration was found in the droplet size in the range of 100~200nm, however, an decrease of instability was found in the droplet size in the range of 300~400nm.

The Movement Characteristic of Micro Droplet by BZN in EWOD structure (EWOD 구조에서 상유전체 BZN에 의한 micro droplet의 이동 특성)

  • Kim, Nah-Young;Hong, Sung-Min;Park, Soon-Sup
    • Proceedings of the KIEE Conference
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    • 2005.11a
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    • pp.36-38
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    • 2005
  • This study is about how to lower the driving voltage that enables to move the micro droplet by the EWOD (Electro Wetting On Dielectric) mechanism. EWOD is well known that it is used ${\mu}-TAS$ digital micro fluidics system. As the device which is fabricated with dielectric layer between electrode and micro droplet is applied voltage, the hydrophobic surface is changed into the hydrophilic surface by electrical property. Therefore, EWOD induces the movement of micro droplet with reducing contact angle of micro droplet. The driving voltage was depended on the dielectric constant of dielectric layer, thus it can be reduced by increase of dielectric constant. Typically, very high voltage ($100V{\sim}$) is used to move the micro droplet. In previous study, we used $Ta_{2}O_{5}$ as the dielectric layer and driving voltage was 23V that reduced 24 percent compared with $SiO_2$. In this study, we used $BZN(Bi_{2}O_{3}ZnO-Nb_{2}O_{5})$ layer which had high dielectric constant. It was operated the just 12V. And micro droplet was moved within Is on 15V. It was reduced the voltage until 35 percents compare with $Ta_{2}O_{5}$ and 50 percents compare with $SiO_2$. The movement of micro droplet within 1s was achieved with BZN (ferroelectrics)just on 15V.

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Release of Oxygen from a Nano-sized Water Droplet Observed using Molecular Dynamics

  • Lee, Chang-Han;Ambrosia, Matthew Stanley
    • Journal of Environmental Science International
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    • v.25 no.7
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    • pp.927-935
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    • 2016
  • Dissolved oxygen is necessary for many biological processes as well as many industrial practices. Dissolved oxygen released from water in dissolved air flotation (DAF) systems can be have many different applications. However, DAF systems are very costly to operate. To develop more efficient DAF systems, a deeper understanding of the process of oxygen being released from water is required. In this study, molecular dynamics (MD) simulations were used to simulate 100 oxygen molecules surrounded by 31002 water molecules at temperatures ranging from $0^{\circ}C$ to $100^{\circ}C$. Simulations were carried out for 10 ns, during which, in most cases, all the oxygen molecules were released from the water droplet. With MD simulations, visualization of the molecules escaping the water droplet was possible, which aided the understanding of the interactions between molecules at the nano-scale. The results showed that as the oxygen molecules moved near the edge of the water droplet that the oxygen molecules hesitated before escaping the water droplet or returned to the interior of the water droplet. This was because of the attractive forces between the water and oxygen molecules. Moreover, after most of the oxygen molecules were released from the droplet, some were found to return to the droplet's edge or even the interior of the droplet. It was also confirmed that oxygen molecules were released at a faster rate at higher temperatures.

Rapid Fabrication of Micro-nano Structured Thin Film for Water Droplet Separation using 355nm UV Laser Ablation (355 nm UV 레이저 어블레이션을 이용한 마이크로-나노 구조의 액적 분리용 박막 필터 쾌속 제작)

  • Shin, Bo-Sung
    • Journal of the Korean Society for Precision Engineering
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    • v.29 no.7
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    • pp.799-804
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    • 2012
  • Recently micro-nano structures has widely been reported to improve the performance of waterproof, heat isolation, sound and light absorption in various fields of electric devices such as mobiles, battery, display and solar panels. A lot of micro-sized holes on the surface of thin film provide excellent sound, or heat, or light transmission efficiency more than solid film and simultaneously nano-sized protrusions around micro hole increase the hydrophobicity of the surface of thin film because of lotus leaf effects as generally known previously. In this paper new rapid fabrication process with 355 nm UV laser ablation was proposed to get micro-nano structures on the surface of thin film, which have only been observed at higher laser fluence. Developed thin micro-nano structured film was also investigated the hydrophobic property by measuring the contact angle and demonstrated the possibility to apply to water droplet separation.

Fabrication of a Micro/Nano-scaled Super-water-repellent Surface and Its Impact Behaviors of a Shooting Water Droplet (마이크로/나노 구조를 갖는 초발수성 표면의 제작 및 분사 액적의 충돌 특성 연구)

  • Kim, Hyung-Mo;Lee, Sang-Min;Lee, Chan;Kim, Moo-Hwan;Kim, Joon-Won
    • Journal of the Korean Society for Precision Engineering
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    • v.29 no.9
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    • pp.1020-1025
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    • 2012
  • In this study, we fabricated the superhydrophobic and super-water-repellent surface with the micro/nano scale structures using simple conventional silicon wet-etching technique and the black silicon method by deep reactive ion etching. These fabrication methods are simple but very effective. Also we reported the droplet impact experimental results on the micro/nano-scaled surface. There are two representative impact behaviors as "rebound" and "fragmentation". We found the transition Weber number between "rebound" and "fragmentation" statements, experimentally. Additionally, we concerned about the dimensionless spreading diameters for our super-water-repellent surface. The novel characterization method was introduced for analysis including the "fragmentation" region. As a result, our super-water-repellent surface with the micro/nano-scaled structures shows the different impact behaviors compared with a reference smooth surface, by some meaningful experiments.

A Study of a Hydrophobic Surface: Comparing Pure Water and Contaminated Water

  • Ambrosia, Matthew Stanley;Lee, Chang-Han
    • Journal of Environmental Science International
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    • v.22 no.4
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    • pp.407-413
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    • 2013
  • The flow of sewage has been studied for hundreds of years. Reducing drag in pipes can allow sewer to be removed easily and quickly. Drag reduction is not only a macroscale issue. Physical and chemical properties of the nano-scale can affect flow at the macroscopic scale. In this paper the predictability of hydrophobicity at the nano-scale is studied. Molecular dynamics simulations were used to calculate the range of contact angles of water droplets in equilibrium on a pillared graphite surface. It was found that at a pillar height of two graphite layers there was the largest range of contact angles. It is observed that at this height the droplet begins to transition from the Wenzel state to the Cassie-Baxter state. Surfaces with larger pillar heights have much larger contact angles corresponding to a more hydrophobic surface. Silicon dioxide was also simulated in the water droplet. The contaminant slight decreased the contact angle of the water droplet.

A Study on the Behavior of Nano-fluid Droplet Impacting Upon a Hot Surface (고온벽과 충돌하는 나노유체 액적 거동에 관한 연구)

  • Kim, E.DD.;Park, I.H.;Bae, N.H.;Kang, B.S.
    • Journal of ILASS-Korea
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    • v.20 no.1
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    • pp.7-13
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    • 2015
  • In this study, the behavior of water or nanofluid droplets impacting upon a hot surface was investigated by visualization of impacting phenomena with time-delayed photographic technique. Changing the mass ratio of nanofluid and the temperature of the heated surface, the characteristics of the spreading behavior and the diameter of spreading liquid film was compared between water and nanofluid droplets. The impacting droplet spreaded as a liquid film after impact and nanofluid droplets spreaded more widely than water droplets. After reaching the maximum diameter, water droplets shrinked more than nanofluid droplets. Based on this, the heat transfer area from a hot surface to impacting nanofluid droplets would be wider than that of impacting water droplets. Considering individual impacting droplet only, spray cooling using nanofluid would be better than using water.

A Study for the Water Droplet on a Stripe-patterned Surface (주기적 줄무늬 구조물 위의 물 액적에 관한 연구)

  • Choi, Ho-Jin;Hong, Seung-Do;Ha, Man-Yeong;Yoon, Hyun-Sik
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.22 no.2
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    • pp.64-69
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    • 2010
  • We investigated the variation in contact angle of a nano-sized water droplet on a nano stripe-patterned surface using molecular dynamics simulation. By changing the height and width of the stripe pillar, and the gap width of the stripes, we observed the contact angle of water droplet in equilibrium. When the surface energies were 0.1 and 0.3 kcal/mol, the calculated contact angles were in good agreement with the Cassie and Baxter equation. However, when the surface energy is 0.5 kcal/mol, the contact angles are observed to be perturbed along the Cassie and Baxter equation.

Comparison of the Characteristics of Sprays between Water and Nanofluid Sprays (물과 나노유체의 분무 특성 비교)

  • Kang, B.S.;Lee, S.P.
    • Journal of ILASS-Korea
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    • v.19 no.2
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    • pp.82-87
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    • 2014
  • Nanofluids are that metallic or nonmetallic nanometer-sized particles are dispersed in liquid. They can be used in various fields to increase the heat transfer rate because the thermal conductivity of nanofluids can be increased significantly. Nanofluids may be used as a good alternative of coolants in spray cooling. This study conducted experiments to compare the characteristics of sprays between water and nanofluid sprays. The radial distributions of droplet velocities and diameters of water, 0.2% wt.(weight), and 0.5% wt. $Al_2O_3$ nanofluids at the pressure of 0.2 and 0.3 MPa were measured by laser doppler instruments. The radial distributions of droplet diameters and velocities at two axial positions with water and 0.2% wt. nanofluid sprays didn't show much difference. A big difference, however, was observed between 0.5% wt. nanofluid and water sprays. With the increase of the mass of nano-particles, the average droplet diameters were increased and the average droplet velocities were decreased.

Properties of Oil-in-Water Nano-emulsions Prepared from Hydrogenated Lecithin with High Pressure Homogenizer

  • Cho, Wan-Goo;Bae, Duck-Whan
    • Journal of the Korean Applied Science and Technology
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    • v.28 no.1
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    • pp.1-5
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    • 2011
  • In this study, We investigated the properites of nano-emulsions containing hydrogenated lecithin prepared by high pressure homogenizer. The size of droplet of emulsions prepared by homogenizer at various rpm (rotation per minute) was not measured due to the unstability of emulsions, however, the size of droplet of nano-emulsions prepared by high pressure homogenizer was around 300 nm and the appearance of emulsions was bluish. The stability of emulsions with various lecithin concentration was tested against time. POV (Peroxide value) of emulsions were plotted against time. POVs of emulsions prepared with an egg lecithin and a soy lecithin were increased with time, however, POV of emulsion with Lecinol S-$10^{(R)}$ was kept constant within 60 hours and at $60^{\circ}C$. In consumer test, the nano-emulsion showed higher affinity regardless of skin type. Both of irritation scores of emulsions were similar.