• 공업화학
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• 제21권6호
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• pp.676-679
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• 2010

이송식 직류 열플라즈마를 이용하여 ZrVFe 합금모재로부터 복합 나노 입자를 제조하여 플라즈마 가스 유량이 제조된 입자의 특성에 미치는 영향을 분석하였다. 입자의 특성은 전계방출 주사전자 현미경(FE-SEM), 입도 분석기(PSA), X선 분광기(EDS), X선 회절계(XRD), Brunauer-Emmett-Teller (BET) 비표면적 측정기를 사용하여 분석하였다. 플라즈마 가스 유량을 20 L/min에서 40 L/min으로 증가시키면 평균입자크기가 91 nm에서 55 nm로 감소하며 입도분포의 기하학적 편차가 줄어들었고 비표면적은 $200m^2/g$에서 $255m^2/g$으로 증가하였으며 제조된 입자의 조성에는 큰 영향을 미치지 못했지만 결정성이 향상되었다.

• 한국환경보건학회지
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• 제32권6호
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• pp.533-538
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• 2006

The nano-particles are known to influence the environmental protection and human health. The relationships between transient vehicle operation and nano-particle emissions are not well-known, especially for diesel passenger vehicles with DPF(Diesel Particulate Filter). In this study, two diesel passenger vehicles were measured on a chassis dynamometer test bench. The particulate matter (PM) emission of these vehicles was investigated by number and mass measurement. The mass of the total PM was evaluated using the standard gravimetric measurement method, and the total number concentrations were measured on a ECE15+EUDC driving cycle using Condensation Particle Counter (CPC). According to the investigation results, total number concentration was $1.14{\times}10^{11}$M and mass concentration was 0.71mg/km. About 99% of total number concentration was emitted during the $0{\sim}400s$ because of engine cold condition. In high temperature and high speed duration, the particulate matter was increased but particle concentration was emitted not yet except initial engine cold condition According to DPF performance deterioration, the particulate matter was emitted 2 times and particle concentration was emitted 32 times. Thus DPF performance deterioration affects particle concentration more than PM.

• 한국자동차공학회논문집
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• 제15권6호
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• pp.128-136
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• 2007

It is well known that two representative methods satisfy EURO-IV regulation from EURO-III. The first method is to achieve the regulation through the reduction of NOx in an engine by utilizing relatively high EGR rate and the elimination of subsequently increased PM by DPF. However, it results in the deterioration of fuel economy due to relatively high EGR rate. The second is to use the high combustion strategy to reduce PM emission by high oxidation rate and trap the high NOx emissions with DeNOx catalysts such as Urea-SCR. While it has good fuel economy relative to the first method mentioned above, its infrastructure is demanded. In this paper, the number distribution of nano PM has been evaluated by Electrical Low Pressure Impactor(ELPI) and CPC in case of Urea-SCR system in second method. From the results, the particle number was increased slightly in proportion to the amount of urea injection on Fine Particle Region, whether AOC is used or not. Especially, in case of different urea injection pressure, the trends of increasing was distinguished from low and high injection pressure. As low injection pressure, the particle number was increased largely in accordance with the amount of injected urea solution on Fine Particle Region. But Nano Particle Region was not. The other side, in case of high pressure, increasing rate of particle number was larger than low pressure injection on Nano Particle Region. From the results, the reason of particle number increase due to urea injection is supposed that new products are composited from HCNO, sulfate, NH3 on urea decomposition process.

• Bulletin of the Korean Chemical Society
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• 제33권9호
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• pp.2966-2970
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• 2012

Fullerene/polystyrene ($C_{60}$/PS) nano particle was prepared by using emulsion polymerization. Styrene and fullerene were emulsified in aqueous media in the presence of poly(N-vinyl pyridine) as an emulsion stabilizer, and polymerization was initiated by water soluble radical initiator, potassium persulfate. The obtained nano particles have an average diameter in the range of 400-500 nm. The fullerene contents in the nano particle can be controlled up to 15 wt % by varying the feed ratio, which was confirmed by themogravimetric analysis (TGA) and elemental analysis (EA). The structure and morphologies of the $C_{60}$/PS nano particles were examined by various analytical techniques such as dynamic light scattering (DLS), scanning electron microscope (SEM), transmission electron microscope (TEM), electron diffraction (ED) pattern, X-ray powder diffraction (XRD), and UV spectroscopy. Unlike conventional $C_{60}$/PS particles initiated by organic free radical initiators, in which the fullerene is copolymerized forming a covalent bond with styrene monomer, the prepared $C_{60}$/PS nano particles contain pristine fullerene as secondary particles homogeneously distributed in the polystyrene matrix.

• 한국자동차공학회논문집
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• 제16권1호
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• pp.114-120
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• 2008

Recently, the nano-PM's number concentration emitted by diesel internal combustion engine has focused on attention because this particulate matters are suspected being hazardous of human health. In this study, The nano-PM mass and size of diesel passenger vehicles were measured on chassis dynamometer test bench. The particulate matters(PM) emissions of these vehicles were investigated by number concentration too. A condensation particle counter(CPC) system was applied to measure the particle number and size concentration of diesel exhaust particles at the end of dilution tunnel along the NEDC(ECE15+EUDC) and CVS-75 vehicle test mode. As the research result, the characteristic of vehicle test mode on the diesel nano-particle number and size distribution was investigated in this study.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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• pp.50-51
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• 2009

Nitride Phosphors have recently been considered as a novel class of luminescent materials for white LEDs due to their promising luminescent properties. It is of great importance to tailor the emission color in order to meet the requirements for practical applications. The paper presents the results of tuning the emission colors of sialon phosphors through compositional tailoring.

• 산업기술연구
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• 제22권A호
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• pp.255-260
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• 2002

We prepared the nano-sized $TiO_2$ particles by the diffusion flame reactor and investigated the effects of several process variables on the generation and transport properties of $TiO_2$ particle. As the length from the tip of diffusion flame reactor increases, the size of $TiO_2$ particle increases by the coagulation between particles. The structure of $TiO_2$ particles prepared is almost found to be anatase. It was found that the $TiO_2$ particle size depends more largely on the change of reactor temperature than on the change of inlet $TiCl_4$ concentration.

• 한국분말재료학회지
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• 제10권1호
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• pp.51-56
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• 2003

To investigate the effect of the parameters of the plasma arc discharge process on the particle formation and particle characteristics of the iron nano powder, the chamber pressure, input current and the hydrogen volume fraction in the powder synthesis atmosphere were changed. The particle size and phase structure of the synthesized iron powder were studied using the FE-SEM, FE-TEM and XRD. The synthesized iron powder particle had a core-shell structure composed of the crystalline $\alpha$-Fe in the core and the crystalline $Fe_3O_4$ in the shell. The powder generation rate and particle size mainly depended on the hydrogen volume fraction in the powder synthesis atmosphere. The particle size increased simultaneously with increasing the hydrogen volume fraction from 10% to 50%, and it ranged from about 45nm to 130 nm.

• 한국분무공학회지
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• 제12권1호
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• pp.65-70
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• 2007

This paper is to investigate the characteristics of exhaust emissions and nano-particle emission from diesel passenger vehicle according to using biodiesel fuel as an alternative fuel. In this work, the particulate matters (PM) of exhaust emissions in diesel engine were investigated by number of particles and mass measurement. The mass of the total PM was measured using the standard gravimetric measurement method, the total number concentrations were measured on a ECE15+EUDC driving cycle using Condensation Particle Counter (CPC). Total PM emission was reduced $2{\sim}38%$ and number concentration was reduced $1{\sim}27%$ according to increasing blended ratio of biodiesel with diesel fuel. Total PM emission was reduced more than particle number emission because volatile particles were measured in total PM but were not measured in particle number emissions.

• 한국전기전자재료학회논문지
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• 제26권6호
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• pp.478-481
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• 2013

Diameter controlled carbon nanotubes (CNTs) were grown using surface modified iron nano-particle catalysts with aminpropyltriethoxysilane (APS). Iron nano-particles were synthesized by thermal decomposition of iron pentacarbonyl-oleic acid complex. Subsequently, APS modification was done using the iron nano-particles synthesized. Agglomeration of the iron nano-particles during the CNT growth process was effectively prevented by the surface modification of nano-particles with the APS. APS plays as a linker material between Fe nano-particles and $SiO_2$ substrate resulting in blocking the migration of nano-particles. APS also formed siliceous material covering the iron nano-particles that prevented the agglomeration of iron nano-particles at the early stages of the CNT growth. Therefore we could obtain the diameter controlled CNTs by blocking agglomeration of the iron nano-particles.