• 해양환경안전학회지
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• 제20권5호
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• pp.468-473
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• 2014

본 연구에서는 정제되지 않은 ZnO 및 $TiO_2$나노입자를 M4배지에 노출시켜 두 나노입자가 어느 정도 크기의 응집체로 변화되는지를 살펴보고 또한 두 나노입자가 수생태계 생물종인 Daphnia magna에 어떠한 영향을 초래하는지 유영저해 및 폐사율을 통해 살펴보았다. ZnO 및 $TiO_2$나노입자의 분말상태 크기는 각각 20 nm와 40 nm였지만, M4배지에서는 1333 nm와 1628 nm로 약 40~70배의 크기로 응집되었다. 유영저해의 경우 ZnO와 $TiO_2$나노입자 모두 시간 및 농도가 높아질수록 D.magna가 유영하는데 영향을 미친 것으로 나타났으며, 특히 ZnO나노입자가 $TiO_2$나노입자에 비해 더 큰 영향을 미치는 것으로 나타났다. 폐사율의 경우 ZnO나노입자에서는 시간 및 농도가 높아질수록 폐사되는 비율이 높았으며, $TiO_2$나노입자에서는 72시간이 경과된 시점의 10 ppm 이상의 농도에서 폐사하는 것으로 관찰되었다. 이는 나노입자가 해양에 유입됨으로 인해 원래의 크기에 비해 응집되어 증가되어진다는 것을 알 수 있으며, 또한 그 응집체로 인해 수생태계 생물에 영향을 주는 것으로 나타났다.

• 공업화학
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• 제23권2호
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• pp.222-227
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• 2012

본 연구에서는 마디풀 추출물의 에틸아세테이트 분획을 함유한 안정한 나노에멀젼을 제조하였고, 이 나노에멀젼의 피부 흡수 증진 효과를 평가하였다. 나노에멀젼은 균질기(homogenizer) 처리 후 고압유화기(microfluidizer)를 이용한 고에너지법으로 제조하였다. 마디풀 추출물의 에틸아세테이트 분획을 함유한 나노에멀젼의 입자 크기와 포집효율을 측정하였다. 평균 입자 크기는 238 nm이었으며 포집 효율은 98% 이상으로 나타났다. 나노에멀젼은 단분산의 입도 분포를 나타냈으며 고압 유화 과정을 거치지 않은 일반 에멀젼보다도 더 안정함을 보여주었다. Franz diffusion cell을 이용하여 마디풀 추출물의 에틸아세테이트 분획을 함유한 나노에멀젼의 피부 투과 실험을 수행하였다. 에틸아세테이트 분획 함유 나노에멀젼은 대조군인 1,3-butylene glycol 용액에서 보다 피부 흡수 및 투과량이 더 큰 것으로 나타났다. 이상의 연구 결과들은 항산화 및 항노화 활성이 큰 마디풀 추출물의 에틸아세테이트 분획을 함유한 나노에멀젼이 안정성 및 피부 투과력이 우수함을 시사한다.

• 한국입자에어로졸학회지
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• 제14권3호
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• pp.49-63
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• 2018

During the last decade, electrospray (ES) techniques have been used as potential methods for preparing of core-shell materials. Depending on the architecture of nozzle and design of devices, the ES techniques includes monoaxial, coaxial, multiple coaxial nozzle ES and microfluidic ES devices. ES operates based on a basic principle, in which a spray of monodisperse droplets is formed by dispensing an electrically conductive liquid through a capillary charged to a sufficiently high potential. In review of many recent research papers, we take a closer look at ES techniques and their applications for fabrication of core-shell materials. Several advantages of ES technique compared with other methods were emphasized and it may be regarded as a potential tool for fabrication of core-shell materials current and near future.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2000년도 추계학술대회논문집B
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• pp.180-185
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• 2000

Nano crystalline or non-crystalline particles have been widely used in various industrial area, such as ceramics, catalysis, electronics, metallurgy and optic device. In all applications, synthesizing the particles as small as possible and controlling the crystalline phase according to its purpose are necessary for the enhancement of processing performance. In some cases, non-agglomerated particles may be necessary for solving the packing problems. This motivates our attempt of controlling size, morphology, phase of nano titania and silica particles. If one can enhance sintering rate of small aggregates independently of collision rate, one may expect that original aggregates can be changed into volume equivalent spheres and thereby the decrease of collision frequency due to the change leads to much smaller rate of growth of the particles. This is the basic idea of our control strategy.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2003년도 춘계학술대회
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• pp.1684-1689
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• 2003

Dielectric Barrier Discharges (DBD) in oxygen and air are well established for the production of large quantities of ozone and are more recently being applied to a wider range of after treatment processes for HAPs(Hazardous Air Pollutants). The potential use as a charger for particle collection are not well known. In this work, we measured charge distribution of nanometer or submicron sized particles passing through the dielectric barrier discharge reactor. The bipolar charge characteristics of particles passing DBD reactor were investigated. Fluorometric method using uranine particles and a fluorometer was employed to examine the bipolar charging characteristics of the charged particles by DBD reactor. Finally, the charge distributions of particles were determined from the electrical mobility classification using DMA.

• 한국가시화정보학회지
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• 제2권1호
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• pp.12-17
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• 2004

The physical characteristics of soot near the soot inception point were investigated with various measurements. In-situ measurements of particle size and volume fraction were introduced based on time resolved laser-induced incandescence (TIRE-LII) and laser-induced ion mobility (LIIM). The one has more convenience and accuracy than conventional LII technique and the other works best for particle sizes of a few nanometers at high concentrations in a uniform concentration field. A complementary ex-situ measurement of particle size is nano differential mobility analyzer (Nano-DMA), which recently developed for measuring particle sizes between 2nm and 100nm and provides high-resolution size information for early soot. Particles will be also collected on transmission electron microscope (TEM) grids using rapid thermophoretic sampling and analyzed for morphology. These measurements will allow fresh and original insight into the characterizing soot inception process. The measured physical properties of incipient soot will clarify the controlling growth mechanism combined with chemical ones, and the dominant mechanism for soot modeling can be deduced from the information.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2004년도 춘계학술대회
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• pp.1510-1515
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• 2004

The effects of additive ions on the generation of metallic nanoparticles were evaluated using a corona induced supersonic nozzle. Applying the corona discharge to the nanoparticle generator, a tungsten needle and the supersonic nozzle are used as an anode electrode and a cathode electrode respectively. The corona ions act as nuclei for the silver vapor condensation. The ion density was controlled precisely as varying the applied voltage between electrode and nozzle. The mean diameter of the silver particle decreases as the ion density increases. However, the number concentration of the silver particle tended to increase with the ion density. The size distribution is more uniform as the ion density increases.

• 한국입자에어로졸학회지
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• 제11권3호
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• pp.77-85
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• 2015

A Belousov-Zhabotinsky reaction in a liquid-liquid system under microwave radiation was observed under non-stirring conditions. To control this non-equilibrium reaction, nano-particle, which is active under microwave irradiation, was added to the solution. Color changes of the solution during the oscillatory reaction were found to be influenced by the irradiation power although the droplet temperature was equal to the temperature of surrounding oil. During the irradiation, the period of oscillation became shorter because the reaction rate was faster. It could also be observed that there is possibility to eliminate oscillatory behaviors of the reaction using higher power of microwave. The possibility of controlling non-linear reaction using microwave was shown since microwave can easily travel through oil phase and reach water phase.

• 대한설비공학회:학술대회논문집
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• 대한설비공학회 2008년도 하계학술발표대회 논문집
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• pp.184-188
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• 2008

It has been recognized that friction coefficient decreased with decreasing viscosity of oil in lubrication. In general, the more viscosity decreases, the more wear rate increases due to decrease load carrying capacity. It has been proposed that nano particles in oil decrease friction coefficient and wear rate. The purpose of this study is to apply oil of lower viscosity that mix with nano particles at the compressor used in a refrigerator to decrease friction coefficient keeping Load carrying capacity. Mineral oil of 8 cSt were used and mixed with nano particle. Friction coefficient was evaluated by a disk-on-disk tester. As a result, friction coefficient of nano oil decreased by 90% in comparison with raw oil. These results lead us to the conclusion that nano oil is new plan to raise efficiency of the compressor.

• 한국재료학회지
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• 제16권12호
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• pp.739-742
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• 2006

The ${\gamma}-Fe_2O_3$ nano particles in the size range of $5{\sim}30$ nm were prepared by a chemical coprecipitation method. The nano particles were coated with 2nd surfactants for obtaining the water-based. The size effect of ${\gamma}-Fe_2O_3$ nano particles for the ultraviolet protection was investigated. The variation of the UV-Vis transmittance spectra as a function of wavelength for a ${\gamma}-Fe_2O_3$ nano particles were showed red-shifted increase with the particle size. The protective effects of UVA onset at near 469, 494, 591 nm for a particle size of 8.7, 9.1 and 12 nm. It is shown that the ${\gamma}-Fe_2O_3$ nano particles was good materials for protect of UV.