• Journal of the Korean Crystal Growth and Crystal Technology
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• v.30 no.4
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• pp.123-130
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• 2020

Nano seed incorporated in micro-sized 4BS (Tetrabasic lead Sulfate) seed was applied to the positive electrode active material and compared with Nano 4BS seed (NS). The dispersion of NS decreased due to the aggregation phenomenon, while the nano seed incorporated in micro-sized 4BS seed (INS) could confirm excellent dispersion. As the content of INS increased, the particle size of the active material became small and constant, which was confirmed through SEM and particle size analysis. The specific surface area for the reaction was increased and the high-rate discharge and lifetime characteristics were improved. In order to confirm the variation in particle size distribution in the plate manufacturing process, internal resistance and voltage were measured for 200 AGM lead-acid batteries, and it was confirmed that batteries quality variation decreased.

• Journal of Korean Society of Environmental Engineers
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• v.31 no.12
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• pp.1069-1074
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• 2009

This study investigated soil microbial community and growth of Zea mays to compare the toxicity of nano and micro-sized Cu and Zn oxide particles in microcosm system. In the presence of nanoparticles, biomass of Zea mays reduced by 30% compared with micro-sized particles and inhibited growth. Dehydrogenase activity was inhibited by CuO nano although it was increased by ZnO nano particles. According to the Biolog test, the microbial diversity was decreased after exposed to CuO nanoparticles and ZnO microparticles. Therefore, though it is widely recognized that nanoparticles are more harmful than microparticles, we can conclude that the diversity of microbial community does not always influenced by the size of particles of nano and micro.

• Journal of ILASS-Korea
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• v.17 no.4
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• pp.185-191
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• 2012

Particulate matters (PM) that is generated by most diesel engine is regulated by the mass concentration measured by the conventional method it had been. Recently, Europe PMP (Particle Measurement Program) decided to start the regulation of vehicle's nano-sized particle number (PN) from the year of 2011 because of nano-particle's higher degree of harm to the human body. So firstly, the standard level of PN emission is introduced in the Euro 5/6 emissions regulation with a limit of $6{\times}10^{11}$ per km for light duty vehicle. Also KPMP(Korea Particle Measurement Program) was organized to copy quickly international technical trend. In this paper, it was investigated the nano-sized PN measurement characteristics for different particle generators between spray type and soot type. And the difference ratio between particle generators, the characteristic of PN concentration, counting efficiency and linearity was analyzed. Then, we make conclusions as followed. When particle diameter is increased, counting efficiency of two generators is decreased. Also Secondary calibration method is more higher 3% than Primary calibration method. Finally, SOF which is included in soot particles is not totally removed so it have great influence on test result of counting efficiency and linearity.

• Journal of the Korean Chemical Society
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• v.57 no.5
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• pp.618-624
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• 2013

We demonstrated unique inter- and intra-plasmonic coupling effects in bimetallic Au@Ag core-shell NP arrays which are regularly or randomly arranged on self-assembled block copolymer (BCP) inverse micelle monolayers. Polyvinylpyrrolidone (PVP)-stabilized Au@Ag core-shell NP arrays in regular or disordered configuration were incorporated and assembled on reconstructed PS-b-P4VP inverse micelle templates through two types of processes. The intensively enhanced LSPR coupling properties of individual and assembled Au@Ag NPs were evaluated by UV-visible spectroscopy in terms of the type of ligand stabilizer, coupling between Au and Ag, thickness of Ag shell, and type of array configuration. Finally, Au@Ag core-shell NP arrays were employed as active substrates for surface enhanced Raman spectroscopy (SERS) and a significantly enhanced signal enhancement was observed in accordance with the coupling intensity of Au@Ag NPs patterns.

• Journal of the Korean Applied Science and Technology
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• v.31 no.4
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• pp.679-687
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• 2014

In this study, a new paint which is able to resist the cavitation erosion is tried to be developed by using urethane added with nano particles such as multi-wall and single-wall carbon nano tube and spherical and fiber type graphite. The new paint synthesized was characterized with physical properties and resistivity to cavitation erosion($t_{50}$). Among nano particles, fiber type graphite($t_{50}$ 292min) showed high hardness and wear resistance compared with spherical type($t_{50}$ 182min). For carbon nano tube, single-wall type($t_{50}$ 286min) was higher than multi-wall type in wear resistance. Fiber-type graphite was the best nano-particle for paint with resistivity to cavitation erosion. In the application test of paint, the manually painted sample showed surface with smooth but the surface of sample prepared with spray was not smooth. During spray, dust was fixed on the surface.

• Journal of the Society of Cosmetic Scientists of Korea
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• v.30 no.3 s.47
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• pp.295-305
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• 2004

Colloid and surface chemistry have been focused on surface area and surface energy. Local surface properties such as surface density, interaction, molecular orientation and reactivity have been one of interesting subjects. Systems of such surface energy being important would be listed as association colloid, emulsion, particle dispersion, foam, and 2-D surface and film. Such nanoparticle systems would be applied to drug delivery systems and functional cosmetics with biocompatible and degradable materials, while nanoparticles having its size of several nm to micron, and wide surface area, have been accepted as a possible drug carrier because their preparation, characteristics and drug loading have been inves-tigated. The biocompatible carriers were also used for the solubilization of insoluble drugs, the enhancement of skin absorption, the block out of UV radiation, the chemical stabilization and controlled release. Nano/micro emulstion system is classified into nano/microsphere, nano/microcapsule, nano/microemulsion, polymeric micelle, liposome according to its prep-aration method and size. Specially, the preparation method and industrial applications have been introduced for polymeric micelles self-assembled in aqueous solution, nano/microapsules controlling the concentration and activity of high concen-tration and activity materials, and monolayer or multilayer liposomes carrying bioactive ingredients.

• Applied Chemistry for Engineering
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• v.21 no.6
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• pp.676-679
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• 2010

Nano composite particles were synthesized from a bulk ZrVFe alloy ingot by transferred DC thermal plasma. Effects of plasma gas flow rate on the characteristics of the produced nano composite particles were investigated. The characteristics of the synthesized powder were analyzed by field scanning electron microscopy (FE-SEM), light scattering particle size analyzer (PSA), energy dispersive X-ray spectroscopy (EDS), X-ray diffractometer (XRD), and Brunauer-Emmett-Teller (BET) surface area analyzer. As the flow rate of plasma gas increased from 20 L/min to 40 L/min, the average particle size decreased from 91 nm to 55 nm, the particle size distribution became narrower, the surface area increased from $200\;m^2/g$ to $255\;m^2/g$, the particle composition was nearly unaffected, and the particle crystallinity was improved.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2012.05a
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• pp.429-434
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• 2012

Ignition delay of micro/nano aluminum particles is caused by aluminum oxide shell. The method of minimizing this ignition delay is proposed in the study. Generating and heating of particles are processed at the same time. As soon as heated particles are produced, they immediately contact with oxygen. Chemical reaction is induced on the contact surface instead of crystallization of oxide shell. Finally particles are ignited. Aluminum particles are generated by laser ablation on an aluminum plate using Nd:YAG pulse laser. Injected particles are confirmed through visualization of particles using scattering method. $CO_2$ continuous laser supplies heat to aluminum plate and generated particles. Trace of burning particles is observed in the experiment.

• Journal of the Society of Cosmetic Scientists of Korea
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• v.35 no.2
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• pp.79-89
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• 2009

The objective of this study was to find out the stable formulation of nano-emulsion containing high concentration of quercetin and to investigate the effect of an ethanol on the nano-emulsion prepared by POE (30) hydrogenated castor oil (HCO-30)/oil/quercetin/ethanol/water system. Nano-emulsion was prepared using emulsion inversion point (EIP) method as low-energy method plus homogenizer as high-energy method. To evaluate effect of ethanol and other components on the nano-emulsion, physical properties such as droplet size, morphology, and size distribution were determined. The optimal quercetin concentration was 0.2 % on the nano-emulsion. The droplet diameter was below 300 nm at the HCO-30 concentration below 2.00 %. Nano-emmulsion containing 4.75 % HCO-30 was the most stable and its mean droplet size was 172.40 nm. Finally, the size of nano-emulsion containing 4.00 % ethanol was 128.15 nm and size distribution was also narrow. The results showed that the breakdown process of this nano-emulsion could be attributed to Ostwald ripening. This study about effect of ethanol on the nano-emulsion showed that loading capacity of drug could be increased by using a small amount of ethanol. As prepared stable nano-emulsion, this study showed that these results could be applied to pharmaceutics, cosmetic including skin-care products, perfume and etc.

• Particle and aerosol research
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• v.6 no.3
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• pp.123-129
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• 2010

As the indoor activity increases in recent years, the indoor air quality becomes more important. One of the major contaminants in office space is the copy machines and the laser based printers. These devices usually emit nano-particles and chemical species that may give some health effect. The amount of particles generated by the printers and copy machines depend on printer models, printing speed, toners, papers, humidity and so on. To evaluate the emission rate of nano-particles from Laser Printers, the mass concentration measurement method has been used (BAM, 2004). However, the mass concentration measurement method for nano-particles is tedious and time consuming. Therefore, for the development of a new nano-particle counting method, the nano-particle emission characteristics and size distributions are evaluated.