• Title/Summary/Keyword: NaCl$CO_2$

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The Preparation and Mossbauer Study of M-type Barrium Ferrite using Salt-Catalysis Method (소금-촉매에 의한 M형 Barrium Ferrite의 제조 및 Mossbauer 분광학적 연구)

  • 이충섭;권동욱;권해웅
    • Journal of the Korean Magnetics Society
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    • v.9 no.1
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    • pp.17-22
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    • 1999
  • Hexagonal M-type barium ferrite $BaFe_{12}O_{19}$ was prepared by a direct solid state reaction between $BaCO_3$ and ${\Alpha}-Fe_2O_3$ powders at temperatures ranging from 800 to 1000 $^{\circ}C$ in a nitrogen or air environment. The effects of NaCl on phase transformation of mixture of $BaCO_3$ and ${\Alpha}-Fe_2O_3$ to $BaFe_{12}O_{19}$ were studied using X-ray diffraction and M$\"{o}$ssbauer spectroscopy. Regardless of the environment for heat treatment or the added NaCl, two phases, BaFe and ${\Alpha}-Fe_2O_3$, coexist for samples heat treated at 800 $^{\circ}C$, but a single phase was observed from samples heat treated at 100$0^{\circ}C$ in both air and nitrogen environments. It was found that the addition of NaCl reduced the amount of $a-Fe_2O_3$ phase.hase.

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Cultural Condition of the Production of Alkaline Pretense by f parahaemolyticus(1) (V. parahaemolyticus에 의한 Alkaline Pretense 생산조건(1))

  • 양지영;한종흔;강현록;황미경;차재호
    • Journal of Food Hygiene and Safety
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    • v.15 no.2
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    • pp.176-178
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    • 2000
  • V parahaemolyticus possessed an extracellular alkaline pretense activity during the stationary growth phase. Various factors such as nitrogen sources, the concentration of NaCl and metal ions were investigated for optimizing the production of alkaline pretense from V. parahaemolyticus ATCC 17802. Among the nitrogen sources tested skim milk showed the distinct increase of the activity and the activity was the highest at 2% in final concentration after 60 hours incubation. The addition of NaCl and metal ions did not increase the alkaline pretense activity. CoC$_2$, CuC1$_2$, and HgCl rather highly inhibited alkaline protease production.

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Effect of High Concentrations of Sodium or Chloride Salts in Soil on the Growth of and Mineral Uptake by Tomatoes (토양에의 고농도 Na 및 Cl 염류가 토마토의 생육 및 무기성분 흡수에 미치는 영향)

  • 강경희;권기범;최영하;김회태;이한철
    • Journal of Bio-Environment Control
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    • v.11 no.3
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    • pp.121-126
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    • 2002
  • This study was conducted to investigate the effect of high concentration of sodium salts and chlorides in soil on the growth of tomato and the uptake of minerals. The growth inhibition rates of plant height and dry weight were different depending on salts, but they were not related to the electric conductivities (EC) and acidities (pH) in the soil solution. The orders of growth inhibition were Cl, SO$_4$, CO$_3$, PO$_4$>NO$_3$ in the sodium salts series, and Na, K, Mg, NH$_4$>Ca in the chlorides. The growth inhibition rates of the sodium salts series tended to be larger than those of the chloride series. Yield was lower 30%~10% in the sodium salt and chloride series than in the control. Chlorophyll content, photosynthetic rate and stomatal conductance were lower in the sodium salts and chloride series than in the control. Mineral concentration was lower in sodium salts and chlorides than in control. The nitrate absorption was inhibited in all salts except for NaNO$_3$ and NH$_4$Cl, and specially in NaCl and Na$_2$SO$_4$ treatments of the sodium salts and in KCl treatment of chloride series. K concentration was reduced NaCl and Na$_2$SO$_4$ treatments compared with the other salts. In the sodium salt series, calcium and magnesium concentration were decreased antagonistically when sodium concentration was increased.

Effects of Starter Candidates and NaCl on the Production of Volatile Compounds during Soybean Fermentation

  • Jeong, Do-Won;Lee, Hyundong;Jeong, Keuncheol;Kim, Cheong-Tae;Shim, Sun-Taek;Lee, Jong-Hoon
    • Journal of Microbiology and Biotechnology
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    • v.29 no.2
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    • pp.191-199
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    • 2019
  • We inoculated different combinations of three starter candidates, Bacillus licheniformis, Staphylococcus succinus, and Tetragenococcus halophilus, into sterilized soybeans to predict their contributions to volatile compound production through soybean fermentation. Simultaneously, we added NaCl to soybean cultures to evaluate its effect on the volatile compounds profile. Cells in soybean cultures (1.5% NaCl) nearly reached their maximum growth in a day of incubation, while cell growth was delayed by increasing NaCl concentrations in soybean cultures. The dominance of B. licheniformis and S. succinus in the mixed cultures of three starter candidates switched to T. halophilus as the NaCl concentration increased from 1.5% to 14% (w/w). Seventeen volatile compounds were detected from the control and starter candidate-inoculated soybean cultures with and without the addition of NaCl. Principal component analysis of these volatile compounds concluded that B. licheniformis and S. succinus made major contributions to producing a specific volatile compound profile from soybean cultures where both species exhibited good growth. 3-Hydroxybutan-2-one, butane-2,3-diol, and 2,3,5,6-tetramethylpyrazine are specific odor notes for B. licheniformis, and 3-methylbutyl acetate and 2-phenylethanol are specific for S. succinus. Octan-3-one and 3-methylbutan-1-ol were shown to be decisive volatile compounds for determining the involvement of S. succinus in the soybean culture containing 7% NaCl. 3-Methylbutyl acetate and 3-methylbutan-1-ol were also produced by T. halophilus during soybean fermentation at an appropriate level of NaCl. Although S. succinus and T. halophilus exhibited growth on the soybean cultures containing 14% NaCl, species-specific volatile compounds determining the directionality of the volatile compounds profile were not produced.

Effect of electrolyte on Bow-tie Water tree (Electrolyte 가 Bow-tie 형 수트리에 미치는 영향)

  • Kang, T.O.;Yang, W.Y.;Kim, K.S.;Chun, C.O.
    • Proceedings of the KIEE Conference
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    • 1994.07b
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    • pp.1550-1552
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    • 1994
  • In order to investigate the effect of electrolyte solutions on the activities of bow-tie water trees in XLPE insulated power cable, we have tried to observe the characteristics on water treeing ( bow-tie type ) using several electrolyte solutions such as $CH_3COOH$, $MgCl_2$,HCl and NaCl solution and tap water. Bow-tie tree density in $CH_3COOH$ and $MgCl_2$ solution was higher than in any other solution, and the growth of tree was stimulated in NaCl and $CH_3COOH$ solution, and diffusion of bow-tie trees into insulation in $MgCl_2$, HCl and NaCl solutions was faster than in $CH_3COOH$ solution and water. Also, although the increase of applied voltage caused bow-tie tree density to be high, it didn't affect the growth of tree maximum length noticeably.

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Development of Combined Method for Extraction of Sea Tangle (다시마의 효과적 추출을 위한 종합적인 추출방법의 개발)

  • Kim, Woo-Jung;Lee, Jung-Kun;Chang, Young-Sang
    • Korean Journal of Food Science and Technology
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    • v.26 no.1
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    • pp.51-56
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    • 1994
  • Development for extraction method of sea tangle was investigated with addition of sucrose, NaCl, EDTA-2Na, SHMP, and hydrolysis with commercial polysaccharide hydrolyzing enzymes. The total solids and protein yields were significantly increased by enzymatic hydrolysis or addition of NaCl and EDTA-2Na during boiling. The extract prepared by enzymatic hydrolysis followed by 2 hrs of boiling in 1.5% NaCl solution was significantly improved in solids and protein yield from 24.1% and 13.9% of 2 hrs of water boiling to 44.6% and 32.2%, respectively. The combined method increased the amino-nitrogen content but reduced the turbidity and viscosity. Extracts with a high intensity of total and seaweed-like taste as revealed by sensory evalution were obtained by combined method.

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CaCO3 Biomineralization in Microfluidic Crystallizer (미세유체 결정화기를 이용한 탄산칼슘 Biomineralization)

  • Seo, Seung Woo;Ko, Kwan Young;Lee, Chang Soo;Kim, In Ho
    • Korean Chemical Engineering Research
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    • v.51 no.1
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    • pp.151-156
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    • 2013
  • Crystallization of $CaCO_3$ is practiced on a polymethylsiloxane (PDMS) - based microfluidic system. Liquid- liquid reaction was investigated by mixing calcium chloride ($CaCl_2$) and sodium carbonate ($Na_2CO_3$) solution to crystallize $CaCO_3$. Aspartic acid (Asp) was added to investigate the morphology change such as vaterite and calcite. Suitable ratio of $Na_2CO_3$ and $CaCl_2$ was searched for initial seed formation. Christmas tree model was used as microfluidic device to form concentration gradient of $Na_2CO_3$ and $CaCl_2$. After observing microfluidic channel by using optical microscope, we found that seeds of $CaCO_3$ were formed under the condition that the ratio of $Na_2CO_3$ and $CaCl_2$ was 2:1. Morphology of crystals were also observed as $CaCO_3$ crystals grow. When Asp was added, vaterite crystal was more frequently found in two morphologies (vaterite and calcite) and seed formation and crystal growth were inhibited.

A Study on the Coolingability of Sodium Aqueous Solutions by Quenching (퀜칭시 나트륨계 수용액의 냉각성능에 관한 연구)

  • Kim, Ok Sam;Choi, Eun Soon;Min, Soo Hong
    • Journal of the Korean Society for Heat Treatment
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    • v.5 no.4
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    • pp.224-232
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    • 1992
  • Coolingability of coolants is important factor in cooling processor heat treatment of steel. Using standard apparatus and method defined in the Korean Industrial Standard three different shapes of probe were designed, ie, cylinderical, spherical and square on shape with same volume of standard probe. Distilled water and sodium aquious solutions with different concentration of NaOH, NaCl and $Na_2CO_3$ were examined. Estimation of coolingability of each quenchants for the probes of cylinderical, spherical or square shape, the cooling rate is greater square, cylinder and sphere in order. Coolingability of sodium aquious solution of NaCl, $Na_2CO_3$ and NaOH is found generally greater then that of distilled water. Effectiveness of ingredients is in the order of $Na_2CO_3$, NaOH and NaCl. In both solutions coolingability increases in 20%, 5%, and 10%in order. Analytical results obtained from Finite Element Method were compared with experimental ones and found as practically satisfactional.

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Syntheses and Spectroscopic Studies of [$Cp_2ZrR]_2Fe(CO)_4$

  • Ko, Jae-Jung
    • Bulletin of the Korean Chemical Society
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    • v.7 no.6
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    • pp.413-421
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    • 1986
  • Hydrocarbon solution of $Cp_2Zr(CH_3)Cl$ react rapidly with $Na_2Fe(CO)_4$ (1/2 equiv.) to yield $[Cp_2Zr(CH_3)]_2Fe(CO)_4$ and NaCl. The more soluble metal-metal bonded complex $[Cp_2ZrC_8H_{17}]_2Fe(CO)_2$ has also been prepared through the reaction of $Cp_2Zr(C_8H_{17})BF_4$ and $Na_2Fe(CO)_4 (1/2 equiv.). The complexes were characterized by IR, $^1H$ NMR, ^{13}C$ NMR, and elemental analysis. The infrared spectrum of $[Cp_2ZrR]_2Fe(CO)_4$ shows four bands, which is indicative of a cis-structure. The $^{13}C$ NMR spectrum provides evidence for the cis-structure.

Stable Isotope and Fluid Inclusion Studies of the Daebong Gold-silver Deposit, Republic of Korea (대봉 금-은광상에 대한 유체포유물 및 안정동위원소 연구)

  • 유봉철;이현구;김상중
    • Economic and Environmental Geology
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    • v.36 no.6
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    • pp.391-405
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    • 2003
  • The Daebong gold-silver deposit consists of mesothermal massive quartz veins thar are filling the fractures along fault shear (NE, NW) Bones within banded or granitic gneiss of Precambrian Gyeonggi massif. Based on vein mineralogy, ore textures and paragenesis, ore mineralization of this deposits is composed of massive white quartz vein(stage I) which was formed in the same stage by multiple episodes of fracturing and healing, and transparent quartz vein(stage II) which is separated by a major faulting event. Stage I is divided into the 3 substages. Ore minerals of each substages are as follows: 1) early stage I=magnetite, pyrrhotite, arsenopyrite, pyrite, sphalerite, chalcopyrite, 2) middle stage I=pyrrhotite, arsenopyrite, pyrite, marcasite, sphalerite, chalcopyrite, galena, electrum and 3) late stage I=pyrite, sphalerite, chalcopyrite, galena, electrum, argentite, respectively. Ore minerals of the stage II are composed of pyrite, sphalerite, chalcopyrite, galena and electrum. Systematic studies (petrography and microthermometry) of fluid inclusions in stage I and II quartz veins show fluids from contrasting physical-chemical conditions: 1) $H_2O-CO_2-CH_4-NaCl{\pm}N-2$ fluid(early stage I=homogenization temperature: 203∼3$88^{\circ}C$, pressure: 1082∼2092 bar, salinity: 0.6∼13.4 wt.%, middle stage I=homogenization temperature: 215∼28$0^{\circ}C$, salinity: 0.2∼2.8 wt.%) related to the stage I sulfide deposition, 2) $H_2O-NaCl{\pm}CO_2$ fluid (late stage I=homogenization temperature: 205∼2$88^{\circ}C$, pressure: 670 bar, salinity: 4.5∼6.7 wt.%, stage II=homogenization temperature: 201-3$58^{\circ}C$, salinity: 0.4-4.2 wt.%) related to the late stage I and II sulfide deposition. $H_2O-CO_2-CH_4-NaCl{\pm}N_2$ fluid of early stage I is evolved to $H_2O-NaCl{\pm}CO_2$ fluid represented by the $CO_2$ unmixing due to decrease in fluid pressure and is diluted and cooled by the mixing of deep circulated meteoric waters ($H_2O$-NaCl fluid) possibly related to uplift and unloading of the mineralizing suites. $H_2O-NaCl{\pm}CO_2$ fluid of stage II was hotter than that of late stage I and occurred partly unmixing, mainly dilution and cooling for sulfide deposition. Calculated sulfur isotope compositions ({\gamma}^{34}S_{H2S}$) of hydrothermal fluids (3.5∼7.9%o) indicate that ore sulfur was derived from mainly an igneous source and partly sulfur of host rock. Measured and calculated oxygen and hydrogen isotope compositions ({\gamma}^{18}O_{H_2O}$, {\gamma}$D) of ore fluids (stage I: 1.1∼9.0$\textperthousand$, -92∼-86{\textperthansand}$, stage II: 0.3{\textperthansand}$, -93{\textperthansand}$) and ribbon-banded structure (graphitic lamination) indicate that mesothermal auriferous fluids of Daebong deposit were two different origin and their evolution. 1) Fluids of this deposit were likely mixtures of $H_2O$-rich, isotopically less evolved meteoric water and magmatic fluids and 2) were likely mixtures of $H_2O$-rich. isotopically heavier $\delta$D meteoric water and magmaticmetamorphic fluids.