• Bulletin of the Korean Chemical Society
• /
• 제18권4호
• /
• pp.402-405
• /
• 1997

Olefinic and cyclopropyl group substituted arenes (C6H5Y) react with [Cp*Ir(CH3COCH3)3]A2 (A=ClO4-, OTf-) to give η6-arene complexes, [Cp*Ir(η6-C6H5Y)]2+ (1a: Y=-CH=CH2 (a),-CH=CHCH3 (b),-C(CH3)=CH2 (c),-CH-CH2-CH2 (d)). Complex 1b-1d are readily converted into η3-allyl complexes, [Cp*(CH3CN)Ir(η3-CH(C6H5)CHCH2)]+ (2a) and [Cp*(CH3CN)Ir(η3-CH2(C6H5)CH2)]+ (2b), in the presence of Na2CO3 in CH3CN. The η6-styrene complex, 1a reacts with NaBH4 to give η5-cyclohexadienyl complex, [Cp*Ir(η5-C6H6-CH=CH2)]+ (3), while with H2 it gives η6-ethylbenzene complex [Cp*Ir(η6-C6H5CH2CH3)]2+ (4). Complex 1a and 1c react with HCl to give [Cp*Ir(η6-C6H5CH2CH2Cl)]2+ (5a) and [Cp*Ir(η6-C6H5CH(CH3)CH2Cl]2+ (5b), respectively.

• 한국환경과학회지
• /
• 제21권6호
• /
• pp.655-659
• /
• 2012

This study elucidates the COD removal of dye (Rhodamine B) through electrochemical reaction. Effects of current density (7.2 to 43.3 $mA/cm^2$), electrolyte type (NaCl, KCl, $Na_2SO_4$, HCl), electrolyte concentration (0.5 to 2.0 g/L), air flow rate (0 to 4 L/min) and pH (3 to 11) on the COD removal of Rhodamine B were investigated. The observed results showed that the increase of pH decrease the COD removal efficiency. Whereas, the increase of current density;NaCl concentration and air flow rate caused the increase of the COD removal of Rhodamine B.

• 한국미생물·생명공학회지
• /
• 제27권6호
• /
• pp.458-465
• /
• 1999

Streptomyces luteogriseus KT-10 isolated from Korean farm soil produced a strong cathepsin B inhibitor. Optimal conditions for the cathepsin B inhibitor production by s. luteogriseus KT-10 were evaluated. The cathepsin B inhibitor was produced with maximal yield in the cultural condition of pH 7.0 and $25^{\circ}C$ for 4 days. Optimal medium for the cathepsin B inhibitor production was determined to be a medium containing 20g, peptone 3g, yeast extract 1g, K2HPO4 0.5g, MgSO4.7H2O 0.5g, NaNO3 0.5g, NaCl 0.5g per l. The cathepsin B inhibitor produced by S. luteogriseus KT-10 could also inhibit the other proteinases such as trypsin, papain, and cathepsin D.

• 한국세라믹학회지
• /
• 제40권10호
• /
• pp.998-1004
• /
• 2003

두 종류의 출발물질인 $Al_2$(S $O_4$)$_3$+x$Na_2$B$_4$ $O_{7}$$.$10$H_2O$(몰비;x=0.1, 0.7)와 ${\gamma}$-Al$_2$ $O_3$+x$Na_2$B$_4$ $O_{7}$$.$10$H_2O$(몰비; x=0.1, 0.7) 혼합시료로부터 재래식 및 마이크로파 열처리를 행하여 휘스커형 $Al_{18}$B$_4$ $O_{33}$ 입자들을 합성하였다. 휘스커형 $Al_{18}$B$_4$ $O_{33}$ 입자들의 성장에 마이크로파, flux양 및 온도의 영향을 X-선 회절장치 및 주사형 전자현미경을 사용하여 조사하였다. 재래식 및 마이크로파 열처리된 두 종류의 혼합시료는 각각 온도 및 flux양이 증가할수록 휘스커형 $Al_{18}$B$_4$ $O_{33}$ 입자의 크기가 증가하는 경향을 나타내었다. 한편, 재래식 열처리된 시료에 비하여 마이크로파 열처리된 시료에서 휘스커형 $Al_{18}$B$_4$ $O_{33}$ 입자들이 잘 발달되었다.자들이 잘 발달되었다.

• 한국축산식품학회지
• /
• 제27권1호
• /
• pp.35-41
• /
• 2007

pH 조절과 소금 첨가에 따른 돼지 뒷다리 부위를 이용한 수리미의 품질특성을 파악하기 위하여 C(명태수리미, 수세 2회, 소금 무첨가), 나머지 처리구들은 돼지 뒷다리 부위를 활용하여 제조한 수리미로 T1(pH 3.0, 소금 무첨가), T2(pH 3.0, 소금 첨가), T3(pH 11.0, 소금 무첨가) 및 T4(pH 11.0, 소금 첨가) 처리구로 하여 시험한 결과를 요약하면 다음과 같다. 육색은 pH가 높을수록 $L^*$값과 W값은 높았지만 $a^*$값과 $b^*$값은 현저하게 낮게 나타났다(p<0.05). 소금 첨가로 W값은 높았지만 $a^*$값과 $b^*$값은 현저하게 낮게 나타났다(p<0.05). 조직감의 응집성은 pH가 높을수록 높게 나타났으며(p<0.05), 탄력성을 제외한 모든 조직특성은 소금 첨가로 인해 현저하게 높게 나타났다(p<0.05). 파괴강도와 젤강도는 pH가 높을수록 높게 나타났고(p<0.05), 파괴강도, 젤강도 및 젤리강도는 소금 첨가로 인해 높게 나타났으나, 전단가는 오히려 낮게 나타났다(p<0.05). 관능검사 결과 연도는 pH가 높을수록 높게 나타났고(p<0.05), 소금 첨가로 인해 모든 관능평가 항목은 현저하게 높게 나타났다(p<0.05). pH 조절과 소금 첨가 유무 상호작용에는 육색, 조직감, 파괴강도, 변형값, 젤강도, 전단가 및 관능검사 결과는 현저한 차이가 없었다(p>0.05). 처리간에는 T2와 T4가 C와 가장 유사한 육색, 조직감, 물리적 특성 및 관능검사 결과를 나타내었고, 그 중에서도 pH 11.0 조절과 2% 소금 첨가구인 T4가 전반적으로 더 좋은 품질이었다.

• 한국환경과학회지
• /
• 제19권9호
• /
• pp.1143-1152
• /
• 2010

The purpose of this study is to degradation of Rhodamine B (RhB, dye) and N, N-Dimethyl-4-nitrosoaniline (RNO, indicator of the electro-generation of OH radical) in solution using boron doped diamond (BDD) electrode. The effects of applied current (0.2~1.0 A), electrolyte type (NaCl, KCl, and $Na_2SO_4$) and electrolyte concentration (0.5~3.0 g/L), solution pH (3~11) and air flow rate (0~4 L/min) were evaluated. Experimental results showed that RhB and RNO removal tendencies appeared with the almost similar thing, except of current. Optimum current for RhB degradation was 0.6 A, however, RNO degradations was increased with increase of applied current. The RhB and RNO degradation of Cl type electrolyte were higher than that of the sulfate type. The RhB and RNO degradation were increased with increase of NaCl concentration and optimum NaCl dosage was 2.5 g/L. The RhB and RNO concentrations were not influenced by pH under pH 7. Optimum air flow rate for the oxidants generation and RhB and RNO degradation were 2 L/min. Initial removal rate of electrolysis process was expressed Langmuir - Hinshelwood equation, which is used to express the initial removal rate of UV/$TiO_$2 process.

• 한국물환경학회지
• /
• 제26권6호
• /
• pp.963-968
• /
• 2010

This study has carried out to evaluate the performance of direct and indirect oxidation electrode for the purpose of decolorization of Rhodamine B (RhB) in water. Four kinds of electrodes were used for comparison: Pt and JP202 (indirect oxidation electrode), Pb and boron doping diamond (BDD, direct oxidation electrode). The effect of applied current (0.5 ~ 2.5 A), electrolyte type (NaCl, KCl, HCl, $Na_2SO_4$ and $H_2SO_4$) and electrolyte concentration (0.5 ~ 2.5 g/L), solution pH (3 ~ 11) and initial RhB concentration (25 ~ 125 mg/L) were evaluated. Experimental results showed that RhB removal efficiency were increased with increase of current, NaCl dosage and decrease of the pH. However, the effect of operating parameter on the RhB removal were different with the electrode type. JP202 electrode was the best electrode from the point of view of performance and energy consumption. The order of removed RhB concentration per energy lie in: JP202>Pt>Pb>BDD.

• 한국약용작물학회지
• /
• 제10권4호
• /
• pp.243-248
• /
• 2002

The effects of basal media, carbon, nitrogen, phosphate and some major macro elements on growth and shikonin production in Lithospermum erythrorhizon hairy root culture were studied. Among examined media, growth of hairy root cultured in B5 liquid medium was rapid, whereas shikonin production was high in MS liquid medium. Under B5 basal medium, sucrose concentration for optimal growth and shikonin production was 9% and 4% respectively. The growth and shikonin production on pH changes in B5 medium resulted little effect in pH 5.8 to pH 8.8 ranges, whereas growth was decreased dramatically in both above 8.8 and under 5.8. Nitrogen source and concentration effected on the growth and shikonin production. The highest growth rate was in B5 medium (50 mM $KNO_3$ and 1 mM $NaH_2PO_4)$, whereas the highest shikonin production was in the condition supplemented with 5 mM $KNO_3$ and 10 mM $NaH_2PO_4$.

• 한국잡초학회지
• /
• 제15권3호
• /
• pp.214-223
• /
• 1995

본 실험은 경엽처리 제초제로 널리 사용되고 있는 Bentazon에 의한 옥수수의 생장저해량을 측정하여 옥수수 품종간의 내성 차이를 구명하고, 선발된 내성 및 감수성 옥수수 품종을 공시하여 효소활성 유기화합물 1,8-naphthalic anhydride, Ethanol, Phenobarbital로 처리한 후 Microsome을 얻은 다음, $^{14}C$-bentazon을 공시하여 TLC(Chloroform : Methanol : Amonium hydroxide = 13 : 7 : 1)와 LSC를 이용하여 Bentazon 불활성 분해효소 Bentazon 6-hydroxylase(B6H)를 측정하여 옥수수 품종간 내성기작를 밝히고자 수행되었다. 1. 생장반응에 의한 품종간 Bentazon의 내성정도는 GA 209, IK 2, DB 544, 수원 19호에서 강하게 나타났으며, KSS 3, KSS 4, KS 5, 만옥 2호에서는 감수성을 나타냈는데, 특히 3엽보다 4엽에서 더욱 뚜렷하였다. 2. 내성 품종인 수원 19호와 GA 209는 Bentazon 6-hydroxylase 활성이 감수성 품종인 단옥 2호와 KS 5에 비해 비교적 높은 경향을 보였다. 3. 내성 품종인 수원 19호와 GA 209 에서는 1,8-NA 0.5% 이상, Ethanol 2.5% 이상에서 B6H 활성이 높은 경향을 보인 반면, 감수성 품종인 단옥 2호와 KS 5에서는 1,8-NA 0.25% 이상, Ethanol 1.0, 2.5% 이상에서 B6H 활성이 낮은 경향을 보였다. 그리고, Phenobarbital은 2mM 에서 B6H 활성이 가장 높았으며, 내성 품종은 전반적으로 감수성 품종보다 약 2배정도 높은 활성을 나타냈다. 4. 내성 품종인 수원 19호와 GA 209에서는 1,8-NA, Ethanol, Phenobarbital 처리에서 모두 B6H효소 활성이 감수성 품종인 단옥 2호와 KS 5보다 높은 경향이므로 B6H효소에 의한 Bentazon의 히드록시 반응 불활성 대사가 빨리 일어나기 때문에 Bentazon에 내성을 나타낸 것으로 사료된다.

• 한국표면공학회지
• /
• 제43권4호
• /
• pp.205-210
• /
• 2010

The A106 Gr B low carbon steel, which was used in the electric power plants and heavy chemical plants, was welded by multi-pass arc welding. The heat affected zone (HAZ) formed by welding was corroded in acid chloride solution, or in saturated $H_2S$ containing acid chloride solution, or in saturated $H_2S$ containing acid chloride solution under applied current. In this order of corrosion solution, the rate of corrosion increased, because $H_2S$ accelerated the iron dissolution, hydrogen evolution, and the formation of nonprotective FeS, whereas the applied current accelerated the electrochemical reaction. The scales formed in acid chloride solution consisted primarily of $Fe_3O_4$, while those formed in $H_2S$ containing acid chloride solution consisted primarily of $Fe_3O_4$ and FeS.