• Title/Summary/Keyword: Na-pyrophosphate

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Studies on the humus soil reclaimed by farming for cultivation (화전토양(火田土壤)의 부식(腐植)에 관(關)한 연구(硏究))

  • Kwag, Pan-Ju
    • Applied Biological Chemistry
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    • v.9
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    • pp.153-159
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    • 1968
  • In this paper the auther investigated the chemical properties, process of humification and type of humic acid in soils which were reclaimed by farming for cultivation in Kangwondo. The results obtained in this studies were summarized as follows: 1. General chemical components of these soil were similar to the ordinary soil but C.E.C. and humus contents were found much more 2. Humic acid and fulvic acid which were extracted with NaOH from soil were greater than those of Na-pyrophosphate(Na-p.) and NaF. Hmus contents and PQ% were increased much more in the upper layer than in the lower layer. 3. Degree of humification of humic acid extracted with NaOH. was very similar to those extracted with Na-pyrophosphate. Humification degree of humic acid extracted with NaF was lower than humic acid which were extracted with NaOH and Na-pyrophosphate. But humification degree of humic acid extracted with NaOH was similar to that with Na-pyrophosphate. Humic acid in B soil and the upper layer was higher than A, C soil and the lower layer of soil, in humification degree. 4. Humic acids extracted with NaOH and Na-pyrophosphate from soil were fractionated by Mg into two parts ${\alpha}$ type and ${\beta}$ type humic acid. Humic acids of ${\alpha}$ and ${\beta}$ type extracted with NaOH were higher than these of Na-pyrophosphate in humification degree. In this soil the humification degree of humic acid was not changed during the period of cultivation. 5. ${\alpha}$, ${\beta}$ type humic acid extracted with NaOH were very similar to the humic acid extracted with Na-pyrophosphate in shapes of absorption curves.

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Pyro-synthesis of Na2FeP2O7 Nano-plates as Cathode for Sodium-ion Batteries with Long Cycle Stability

  • Song, Jinju;Yang, Juhyun;Alfaruqi, Muhammad Hilmy;Park, Wangeun;Park, Sohyun;Kim, Sungjin;Jo, Jeonggeun;Kim, Jaekook
    • Journal of the Korean Ceramic Society
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    • v.53 no.4
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    • pp.406-410
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    • 2016
  • Carbon-coated sodium iron pyrophosphate ($Na_2FeP_2O_7$) was prepared by a simple and low-cost pyro-synthesis route for further use as the cathode for Na-ion batteries. The X-ray diffraction (XRD) pattern of the sample annealed at $650^{\circ}C$ confirmed the pure triclinic phase of $Na_2FeP_2O_7$. Electron microscopy studies revealed a cross linked plate shape morphology of the $Na_2FeP_2O_7$ sample. When tested for application in Na-ion battery, the $Na_2FeP_2O_7$ cathode showed two redox pairs in the potential window of 2.0-4.0 V. The cathode registered initial discharge and charge capacities of 80.85 and 90 mAh/g, respectively, with good cycling performance.

An experimental study of heat transfer with $Na_4P_2O_7{\cdot}10H_2O$ as P.C.M. ($Na_4P_2O_7{\cdot}10H_2O$의 축열방열시 열전달 특성에 관한 실험적 연구)

  • Lee, C.M.;Yim, C.S.
    • Solar Energy
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    • v.9 no.1
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    • pp.70-77
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    • 1989
  • Sodium pyrophosphate that melting point is $79-80^{\circ}C$ have been Studied on heat storage and heat discharge. In heat storage process, sodium pyrophosphate was kept up initial temperature $50^{\circ}C,\;60^{\circ}C,\;70^{\circ}C$ which melt by heated water at temperature $85^{\circ}C,\;90^{\circ}C,\;95^{\circ}C$. In heat discharge process, initial temperature of sodium pyrophosphate was maintained at temperature $85^{\circ}C,\;90^{\circ}C,\;95^{\circ}C$ which varied cooling temperature $50^{\circ}C,\;60^{\circ}C,\;70^{\circ}C$. The experiment has been reached conclusions as follows. 1) Heat transfer properties of phase change material is controlled by conduction during heating and cooling process. 2) The temperature increased rapidly at initial stage and transient region increase slowly because of characteristic of latent heat. 3) The lower cooling water temperature is the less the time that get to thermal equivalent state take during discharge process. 4) The higher cooling water temperature is the less temperature difference between top and bottom in P.C.M during discharge process.

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Studies on the Formation of Pyrophosphate-$^{99m}T_c$ complex

  • Kim, Jae-Rok;Awh, Ok-Doo
    • Nuclear Engineering and Technology
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    • v.12 no.1
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    • pp.19-28
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    • 1980
  • An instant labelling technique for lyophilized pyrophosphate with $^{99m}$Tc is described labelling yield of about 90% is obtained at the pH range 3.5-5.5 on reconstitution with sodium pertechnetate-$^{99m}$ Tc solution. The final product is controlled by a modified two dimensional paper chromatography using 85% methanol and 0.85% saline, and biodynamic investigations are performed on white mice. Generally, the less amount of stannous chloride is used. the higher labelling yield is obtained. The molar ratio of pyrophosphate to stannous chloride of 10 : 1 ~ 50 : 1 is sufficient. The more amount of reduced unbound $^{99m}$Tc is injected, the more radioactivity is incorporated in the liver. Thus. the cause of the false bone-imaging is attributable to the presence of reduced unbound $^{99m}$Tc which is known to be well adsorbed to oxidized tin colloidals. The maximum uptake ratio of bone: liver in mice, in weight basis, 35 : 1 is achieved in lime of 60 min. or so. Tile preparation is suitable for clinical investigations on patients with bone diseases.iseases.

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Effect of Starch Noodle (Dangmyeon) and Pork Intestines on the Rehydration Stability of Korean Blood Sausage (Sundae)

  • Kim, Youngmin;Jang, Hyejin;Lim, Sangdong;Hong, Sangpil
    • Food Science of Animal Resources
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    • v.41 no.1
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    • pp.153-163
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    • 2021
  • This study was conducted to examine the effects of starch noodles (dangmyeon; SNs) with different starch sources and porcine intestines (PIs) with different pH on the rehydration stability of Korean blood sausage (sundae). Mungbean SN3 and PI3 (pH 9.18) showed significantly higher values of 80.69%-91.67% and 79.66%-80.98%, respectively, regardless of the drying methods (hot air, vacuum and freeze drying) (p<0.05). A number of larger pores were observed only in the cross-section of the freeze dried SN and PI through SEM. SN2 (potato starch) and PI3 (pH 9.18) showed lower expansion (⁎ΔL 6.90 mm) and higher expansion ratio (⁎ΔL 26.29 mm), respectively, after rehydration of freeze dried sample (p<0.05). From the application of SN2 (potato starch) and PI (0.5%-2.0% Na-pyrophosphate) to freeze dried sundae manufacturing, higher rehydration stability of more than 91.5% was obtained. These results suggested that potato SN and treatment of PI with Na-pyrophosphate is useful for desirable rehydration stability of freeze dried sundae.

Effects of Condensed Sodium Phosphates as a Degumming Aid Reagent for Raw Silk Fabric (견의 정연조제로서 축합인산염의 효과에 관한 연구)

  • 이용우;송기언;정인모
    • Journal of Sericultural and Entomological Science
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    • v.25 no.2
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    • pp.44-50
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    • 1984
  • The effects of sodium pyrophosphate, sodium tripolyphosposphate and ethylene diamine tetraacetic acid as a degumming aid reagent were investigated under the conditions of underground water and dimineralized water for the scouring water sources. The changes of water qualities by adding the condensed sodium phosphates and the physical properties of scoured silk fabric were examined, respectively. 1. The water hardness of underground water was decreased by adding the condensed sodium phosphates and it was further reduced according to the increasing temperature. The water hardness reducing power of sodium pyrophosphate was a little stronger than that of sodium tripolyphosphate. 2. The sodium silicate as an alkaline reagant for scouring decreased the water hardness, but the sodium carbonate increased it in the underground water. 3. The pH value of 0.4% soap and 0.25% sodium silicate mixed solution after boiling was. 9.80, but it was leveled upto 9.90 by adding 0.05% sodium pyrophosphate and upto 9.95 by 0.02% ehtylene diamine tetraacetic acid, respectively. 4. The masking action of Fe$\^$3+/ ions dissolved in the scouring water was more remarkable by ethylene diamine tetraacetic acid than by the condensed sodium phosphates. Of the condensations, sodium tripolyphosphate was more effective than sodium pyrophosphate in the action. 5. Genrally, the dimineralized water scouring increased the boil-off ratio with reducing the flexural rigidity of fabric which was negatively related with the favorablility of hand-touch more than the underground one did. 6. Under the underground water scouring, the addition of ethylene diamine tetraacetic acid increased the boil-of ratio and compressive elasticity of fabric with reducing the flexural rigidity more than that of the condensed sodium phosphates did. 7 The additions of sodium tripolyphosphate and ethylene diamine tetraacetic acid reduced the flexural rigidity of fabric with raising the boil-off ratio even in the dimineralized water scouring, but there was no sifnificant difference between both of them.

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A Study on Comparison of Heat Transfer Characteristic and Heat Storage Capability of $C_{28}H_{58}$ and $Na_4P_2O_7{\cdot}10H_2O$ ($C_{28}H_{58}$$Na_4P_2O_7{\cdot}10H_2O$의 전열특성 및 축열성능 비교에 관한 연구)

  • Yim, Chang-Soon;Kim, Jun-Keun;Cho, Nam-Cheol;Kim, Young-Ki
    • Solar Energy
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    • v.11 no.2
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    • pp.41-50
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    • 1991
  • Heat transfer phenomena and temperature characteristics in heat storage and release process in the heat storage system using PCM(Phase Change material) were studied experimentally. The melting points of Octacosane paraffin($C_{28}H_{58}$) and sodium pyrophosphate decahydrate ($Na_4P_2O_7{\cdot}10H_2O$) used for phase change materials are $62^{\circ}C$ and $79^{\circ}C$ respectively. Experiments were performed in order to investigate temperature distributions, the heat storage quantity and the release quantity on octacosane paraffin and sodium pyrophosphate decahydrate for heat storage and release in the heat storage system. Furthermore the comparison of these characteristics between paraffin and $Na_4P_2O_7{\cdot}10H_2O$ were evaluated. In case of the paraffin, temperature slowly increased at early heat storage process by natural convection, while temperature of $Na_4P_2O_7{\cdot}10H_2O$ rapidly increased the dominant role played by conduction at early heat storage processing Also, during the heat storage and release process in case of the paraffin, it was observed that the variation of temperature of the neighborhood of wall and center in the top and bottom of the tube exhibited a great difference, however in $Na_4P_2O_7{\cdot}10H_2O$, it was observed that the variation of temperature exhibited a little difference. And heat storage quantity of each PCM of identity mass in heat storage process was shown that $Na_4P_2O_7{\cdot}10H_2O$ exhibited more by 16 percents than paraffin.

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Rheological Behavior of Coal-Fly-Ash and Clay Slip (석탄회-점토계 슬립의 유동학적 거동)

  • 이기강;박천주;김유택;김석범;김정환
    • Journal of the Korean Ceramic Society
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    • v.35 no.2
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    • pp.180-184
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    • 1998
  • It was examined that the rheological behaviors of fly ash 70wt%-clay 30wt% slip in which nonplastic fly ash was a major component. We have systematically investigated the effects of deflocculant(Tetrasodium pyrophosphate ; Na4P2O7 nH2O Sodium silicate; Na2SiO3) and coagulant(CaSO4) on the rheological behavior of ash-clay slip. Ash-clay slip have been characterized on the basis of the time dependent rheology which was done out by the gel-curve test. Dispersion mechanism of ash-clay slip is the steric stabilization by the Na2SiO3 coating of cenospheres surface. Coagulated slip seems to have the new network structure and shows the gellation behaviors which makes it possible to direct coagulated casting(DCC).

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Preparation and Analysis of Alkaline Powder Cleaning Agents for Steel (철강용 알칼리 분말세정제의 제조 및 세정해석)

  • Lee, Ae-Ri;Chung, Dong-Jin;Park, Hong-Soo;Im, Wan-Bin
    • Journal of the Korean Applied Science and Technology
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    • v.20 no.4
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    • pp.283-288
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    • 2003
  • Alkaline powder cleaning agents (APCAs) were prepared by blending of $Na_2CO_3$ tetrasodium pyrophosphate (TSPP). sodium orthosilicate (Na-OSi), Na-dioctyl sulfosuccinate (303C), Demol C, and MJU-100A (100A). The physical properties of APCAs tested with steel specimen showed the following results. The cleaning powers of APCA-6 ($Na_2CO_3$ 250g/TSPP 70g/Na-OSi 40g/303C 60g/Demol C 50g/100A 30g mixture) for press-rust preventing oil was 97% and 98% degreasing at 2wt%, $70^{\circ}C$ and $90^{\circ}C$, respectively; for Quenching oil, the cleaning power of APCA-6 was 95% degreasing at 2wt% and $70^{\circ}C$. From the results, it was ascertained that APCA-6 exhibited a good cleaning power. Also low foaming power tests proved that the APCA-6 maintained good defoaming effect.