• 제목/요약/키워드: Na-Y

검색결과 27,685건 처리시간 0.05초

NaOH처리시 Poly(ethylene terephthalate)필름의 표면특성에 영향을 주는 Diamine의 첨가효과 (Effect of Diamine Addition in NaOH Treatment Solution on Surface Characteristics of Poly (Ethylene Terephthalate) Film)

  • 강인숙;배현숙
    • 한국의류산업학회지
    • /
    • 제15권2호
    • /
    • pp.302-308
    • /
    • 2013
  • This study is a preliminary investigation of the influence of surface characteristics of substrates on detergency of particulate soil. The surface of PET film was modified with NaOH and NaOH+ethylene diamine on different times. The surface morphology of the film was scanned by AFM and surface energies were calculated from measured contact angles between several solutions and film based on the geometric mean and a Lewis acid base method. The surface morphology of PET film treated with NaOH and NaOH+ethylene diamine became more etched, and the surface area, surface roughness and the coefficient of friction of film increased with treatment of NaOH and NaOH+ethylene diamine. The contact angle of film treated with NaOH and NaOH+ethylene diamine decreased in water and surfactant solution; in addition, the surface energy increased was largely attributed to the increased portion on the polar surface energy of film. However, the effect of the diamine addition to the NaOH treatment solution on surface characteristics of PET film was insignificant.

내염성 담배 캘러스에 대한 NaCl의 효과 (Effect of NaCl on Salt-tolerant Callus in Tobacco)

  • 차현철
    • Journal of Plant Biology
    • /
    • 제36권1호
    • /
    • pp.113-120
    • /
    • 1993
  • Effects of various NaCl concentrations on salt-tolerant callus of tobacco were investigated. Selection of NaCl-tolerant (S) callus was conducted by subculturing Nicotiana tabacum cv. BY 4 callus in 200 mM NaCl-containing MS medium for more than 18 months. In spite of the long subculture period, characteristics of salt tolerance were maintained very stably. Significant differences were found in ion contents of each callus which was subcultured with treatment of various NaCl concentrations: Na+ and Cl- became higher but Mg2+, Ca2+ and K+ became lower with the increasing external salt contents. Therefore, the ratios of Na+/Ca2+ and Na+/K+ also increased resulting close to those of halophytic property. The contents of chlorophylls and carotenoids in S callus were estimated to 3.1 and 2.9 times more, respectively. than those of non-selected (NS) callus (control). The higher content of external NaCl tended to increase the amount of water soluble proteins and to decrease the amounts of the total sugars, reducing sugars and free amino acids. The activity of peroxidase was increased with higher contents of external NaCl in S callus, but it was maintained at a higher level than S callus at lower NaCl, followed by a subsequent decrease above 80 mM NaCl in NS callus. These results suggest that S callus may have a biological system converting energy source to efficient growth leading to reduction of the growth inhibition under stress environment.

  • PDF

Effect of sodium on transmembrane calcium movement in the cat ileal longitudinal muscle

  • Rho, Young-Jae;Yun, Il;Kang, Jung-Sook
    • Archives of Pharmacal Research
    • /
    • 제10권2호
    • /
    • pp.80-87
    • /
    • 1987
  • To get a better insight into the exxistence and the role of a Na-Ca exchange mechanism in smooth muscle, the effect of Na substitution with sucrose on tension development, cellular Ca uptake and $^{45}Ca$ efflux was investigated using isolated cat ileal longitudinal muscle strips. Experimental results were summarized as follows;1) Exposure of the cat ileal longitudinal muscle to Na-free solution induced a contraction, and the magnitude of the contraction increased after incubation of the muscle strips with ouabain ($2{\times10^{-}5}$M) for 1hr. 2) Cellular Ca uptake in Na-free solution increased with an increase in Na content of the Na-loading media, and a linear relationship existed between tissue Na content and cellular Ca uptake for 10 min 3) After tissues were equilibrated in PSS containing $^{45}Ca$ for 2hr, cellular Ca uptake decreased with rising the external Na concentration. 4)Removal of medium Na or inhibition of the Na-K pump decreased the rate of $^{45}Ca$ efflux. These results strongly suggested that Na substitution increases cellular Ca uptake and decreases the rate of $^{45}Ca$ efflux via a Na-Ca exchange mechanism.

  • PDF

Na$_2$CO$_3$-NaOH 혼합용융염과 물의 접촉에 의한 증기폭발에 관한 연구 (A Study on Vapour Explosion Caused by the Contact Between Molten Salt of Na$_2$CO$_3$-NaOH Mixture and water)

  • Mok, Yun-Soo;Chiaki Ogiso;Yoichi Uehara
    • 한국안전학회지
    • /
    • 제4권1호
    • /
    • pp.41-46
    • /
    • 1989
  • Molten salt-water explosion caused by the contact between molten salt and water is one of vapour explosions. An experimental study of the vapour explosion, which occurs when the molten mixture of Na$_2$CO$_3$-NaOH and water come in contact was performed. The pressure wave generated in each composition Of molten mixtures was measured. The results obtained are as follows: 1) The vapour explosion didn't occur for a molten salt of 100%-Na$_2$CO$_3$- 2) For a molten salt of Na$_2$CO$_3$ 80%-NaOH 20% mixture, a small vapour explosion occured initially, and a large vapour explosion, which showed the largest pressure wave among the present experiments, occurred after an induced period. 3) For molten salt of Na$_2$CO$_3$60% - NaOH 40% mixture and Na$_2$CO$_3$ 40% - NaOH 60% mixture, the vapour explosion occurred near the water surface shortly after they come in contact with water. This explosion would be caused by fragmentation of the molten salts due to impulse generated when thee molten salts and water come in contact.

  • PDF

Na이 첨가된 Mo 전극을 이용한 CIGS 박막 태양전지 연구 (A Study on the CIGS cells with Na-doped Mo back contact)

  • 윤재호;김기환;김민식;안병태;안세진;이정철;윤경훈
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 한국신재생에너지학회 2006년도 춘계학술대회
    • /
    • pp.218-221
    • /
    • 2006
  • The photovoltaic properties of CIES cells on alumina substrate were improved by using the Na-doped Mo as theabotom layer of hilo back contact. Na was supplied to the CIGS bulk region from alumina/Na-doped Mo/Mo/alumina? structure, as same assimilar to the Na diffusion from soda-lime glass. The content diffusion of Na from Na-doped bfo was smaller more controlled than that from SLG. These Our results indicate that Na-doped bfo act as Na source material and contents of Na amount can be controlled without the use of an alkali barrier layer. The best CIGS solar cell with conversion efficiency of 13.34%, $J_{sc}=34.62mA/cm^2,\;V_{oc}=0.58V$ and FF=66% for an active area of $0.45cm^2$ on the alumina substrate was obtained in the condition of for 100nm Na-doped Mo/1000nm Mo.

  • PDF

고농도 NaBH4 수용액에서 비담지 촉매의 가수분해 반응 특성 (Characteristics of Hydrolysis Reaction Using Unsupported Catalyst at High Concentration of NaBH4 Solutions)

  • 이혜리;나일채;박권필
    • Korean Chemical Engineering Research
    • /
    • 제54권5호
    • /
    • pp.587-592
    • /
    • 2016
  • 휴대용 고분자전해질 연료전지의 수소발생용으로써 $NaBH_4$는 많은 장점을 갖고 있다. 본 연구에서는 고농도 $NaBH_4$ 용액에서 비담지 Co-P-B, Co-B 촉매의 $NaBH_4$ 가수분해 특성에 대해 연구하였다. 고농도에서 수소 발생 수율을 높이기 위해 $NaBH_4$ 가수분해 반응의 수소 발생 수율에 미치는 촉매 형태, $NaBH_4$ 농도, 응축수 회수 등의 영향에 대해 실험하였다. Co-P-B 제조과정에서 붕소의 비가 높아질수록 수소 발생 수율이 증가하였다. Co-P:B = 1:5 촉매를 사용해 $NaBH_4$ 수용액 농도를 20 wt%에서 25 wt%로 증가시켰을 때 수소 발생 수율이 감소하였다. Co-P-B와 Co-B 촉매를 같이 사용한 반응기에서 촉매 팩의 두께를 감소시키고 응축수를 회수하여, $NaBH_4$ 25 wt% 수용액으로 최고 수소 발생수율 96.4%를 얻었다.

산과 염이 폴리에스터 직물의 알칼리 감량에 미치는 영향 (Effect of Acid and Salt on Weight toss of Polyester (PET) fabric by Sodium Hydroxide)

  • 도성국;조환
    • 한국염색가공학회지
    • /
    • 제4권3호
    • /
    • pp.65-73
    • /
    • 1992
  • To control the hydrolysis rate of PET fabric with NaOH, HCl and $CH_3$COOH(HAc), as regulating reagent, were added to the 0.5 M NaOH solution. The concentrations of acids in 0.5 M NaOH were varied. PET fabrics were treated with aqueous solutions of acids in 0.5 M NaOH under different conditions. The weight loss of PET fabric, the rate of hydrolysis, the apparent activation energy (E$_{\alpha}$), the handle value, the etched surface of treated PET fabric, and the effect of salts such as NaCl, $CH_3$COONa(NaAc), and NH$_4$Cl on the weight loss were discussed. Acids in the aqueous 0.5 M NaOH solution decreased the weight loss of PET fabric bacause of neutralization of OH- and the weight loss of PET fabrics treated with corresponding concentration of aqueous NaOH solution to the concentrations of the aqueous solutions of acids in 0.5 M NaOH was lower than that of PET fabrics treated with aqueous solutions of acids in 0.5 M NaOH. The addition of NaCl to aqueous NaOH solution accelerated the reaction of OH- with PET greatly, the addition of NaAc increased the weight loss slightly, but the addition of NH$_4$Cl decreased the weight loss. It was thought that the very remarkable result that NaCl in aqueous NaOH solution promoted the hydrolysis of PET with NaOH would contribute to the conservation of energy and NaOH in the weight loss finishing process of PET fabric. The etched surface and the handle value of treated PET fabric were independent of the difference in the kinds of acids and salts added.nd salts added.

  • PDF

정상생활을 하는 고혈압 여성에 있어서 일상적인 나트륨, 칼슘 섭취습관이 혈압조절 관련 호르몬에 미치는 영향 (The Effect of Habitual Calcium and Sodium Intakes on Blood Pressure Regulating Hormone in Free-Liveing Hypertensive Women)

  • 박정아;윤진숙
    • Journal of Nutrition and Health
    • /
    • 제34권4호
    • /
    • pp.409-416
    • /
    • 2001
  • In order to evaluate the effect of habitual Na and Ca intake on blood pressure regulation, we measured the habitual dietary intakes of Na and Ca, urinary excretion of Ca, Na and K, and plasma level of renin activity, aldosterone, and indices of Ca metabolism in 27 untreated hypertensive women and 30 age-matched normal women on a free diet. Hypertensive and total subjects were divided into four groups according to habitual dietary intakes of Na and Ca as low Na-low Ca(LNLC), low Na-high Ca(LNHC), high Na-low Ca(HNLC), and high Na-high Ca(HNHC). HNLC hypertensive group showed the lowest level of plasma renin activity, 25-(OH) Vit D$_3$, calcitonin and serum total Ca, and presented the highest level of PTH and urinary excretions of Na/K and Ca/Cr. There were no significant difference in plasma level of aldosterone and urinary excretion of Na and K among four hypertensive groups. When all subjects were divided into four groups according to the same method, HNLC group showed the highest level of blood pressure with no statistical significance and the lowest level of calcitonin and total serum Ca. The above results indicated that renin-aldosterone system and Ca regulating hormone has a mutual relationship in hypertension. Na and Ca may interact each other, rather than affecting independently blood pressure control. As a result, considering the fact that daily balance of Na and Ca intakes affects Na and Ca regulating hormones and urinary excretion of Na and Ca, it may be involved in blood pressure control. These results suggest that maintaining an adequate intake of Ca with less intake of Na may prevent from the risk of hypertension. (Korean J Nutrition 34(4) : 409~416, 2001)

  • PDF

Suppression of Pyrite Oxidation by Formation of Iron Hydroxide and Fe(III)-silicate Complex under Highly Oxidizing Condition

  • Lee, Jin-Soo;Chon, Chul-Min;Kim, Jae-Gon
    • 한국토양비료학회지
    • /
    • 제44권2호
    • /
    • pp.297-302
    • /
    • 2011
  • Acid drainage generated by pyrite oxidation has caused the acidification of soil and surface water, the heavy metal contamination and the corrosion of structures in abandoned mine and construction sites. The applicability of Na-acetate (Na-OAc) buffer and/or Na-silicate solution was tested for suppressing pyrite oxidation by reacting pyrite containing rock and treating solution and by analyzing solution chemistry after the reaction. A finely ground Mesozoic andesite containing 10.99% of pyrite and four types of reacting solutions were used in the applicability test: 1) $H_2O_2$, 2) $H_2O_2$ and Na-silicate, 3) $H_2O_2$ and 0.01M Na-OAc buffer at pH 6.0, and 4) $H_2O_2$, Na-silicate and 0.01M Na-OAc buffer at pH 6.0. The pH in the solution after the reaction with the andesite sample and the solutions was decreased with increasing the initial $H_2O_2$ concentration but the concentrations of Fe and $SO_4^{2-}$ were increased 10 - 20 times. However, the pH of the solution after the reaction increased and the concentrations of Fe and $SO_4^{2-}$ decreased in the presence of Na-acetate buffer and with increasing Na-silicate concentration at the same $H_2O_2$ concentration. The solution chemistry indicates that Na-OAc buffer and Na-silicate suppress the oxidation of pyrite due to the formation of Fe-hydroxide and Fe-silicate complex and their coating on the pyrite surface. The effect of Na-OAc buffer and Na-silicate on reduction of pyrite oxidation was also confirmed with the surface examination of pyrite using scanning electron microscopy (SEM). The result of this study implies that the treatment of pyrite containing material with the Na-OAc buffer and Na-silicate solution reduces the generation of acid drainage.

Fly ash의 NaOH 용융처리에 의한 고순도 Na-P1 Zeolite의 합성 (Synthesis of Highly Pure Na-P1 Zeolite by NaOH Fusion Treatment of Fly Ash)

  • 최충렬;이동훈;이인중;신동현;김장억;박만
    • 한국환경농학회지
    • /
    • 제24권3호
    • /
    • pp.232-237
    • /
    • 2005
  • This study was conducted to elucidate the effects of NaOH fusion treatment on Na-P1 zeolite synthesis from fly ash and to evaluate its optimal condition. NaOH fusion treatment of fly ash led to Na-P1 zeolite with shorter reaction time and higher quality compared that of simple hydrothermal method. Mixed zeolite phases of Na-P1 and hydroxy sodalite were formed by the fusion treatment below $450^{\circ}C$, whereas only Na-P1 zeolite was formed above $550^{\circ}C$. Ratio of NaOH/fly ash, reaction times, fusion temperature and solid/liquid ratio strongly affected the kind and crystallinity of the zeolite formed. The CEC of Na-P1 zeolite formed at the optimum reaction conditions of NaOH/fly ash ratio 0.9 and solid/liquid ratio $1/5.0{\sim}1/7.5$ after NaOH fusion treatment at $550^{\circ}C$ for 2 hours was about $398cmol^+kg^{-1}$ which was 40% higher than those of control products. Therefore, it is clear that NaOH fusion treatment of fly ash in open system could lead to Na-P1 zeolite with high purity.