• Title/Summary/Keyword: NR System

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Effect of Electrochemical Redox Reaction on Biochemical Ammonium Oxidation and Chemical Nitrite Oxidation

  • Jeon, Bo-Young;Seo, Ha-Na;Kang, Seung-Won;Park, Doo-Hyun
    • Journal of Microbiology and Biotechnology
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    • v.20 no.3
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    • pp.485-493
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    • 2010
  • A modified graphite felt electrode with neutral red (NR-electrode) was shown to catalyze the chemical oxidation of nitrite to nitrate under aerobic conditions. The electrochemically oxidized NR-electrode (EO-NR-electrode) and reduced NR-electrode (ER-NR-electrode) catalyzed the oxidation of $1,094{\pm}39$ mg/l and $382{\pm}45$ mg/l of nitrite, respectively, for 24 h. The electrically uncharged NR-electrode (EU-NR-electrode) catalyzed the oxidation of $345{\pm}47$ mg/l of nitrite for 24 h. The aerobic bacterial community immobilized in the EO-NR-electrode did not oxidize ammonium to nitrite; however, the aerobic bacterial community immobilized in the ER-NR-electrode bioelectrochemically oxidized $1,412{\pm}39$ mg/l of ammonium for 48 h. Meanwhile, the aerobic bacterial community immobilized on the EU-NR-electrode biochemically oxidized $449{\pm}22$ mg/l of ammonium for 48 h. In the continuous culture system, the aerobic bacterial community immobilized on the ER-NR-electrode bioelectrochemically oxidized a minimal $1,337{\pm}38$ mg/l to a maximal $1,480{\pm}38$ mg/l of ammonium to nitrate, and the community immobilized on the EU-NR-electrode biochemically oxidized a minimal $327{\pm}23$ mg/l to a maximal $412{\pm}26$ mg/l of ammonium to nitrate every two days. The bacterial communities cultivated in the ER-NR-electrode and EU-NR-electrode in the continuous culture system were analyzed by TGGE on the $20^{th}$ and $50^{th}$ days of incubation. Some ammonium-oxidizing bacteria were enriched on the ER-NR-electrode, but not on the EU-NR-electrode.

Thermal Aging Properties of NR Vulcanizates with Different Cure Systems (가교 시스템이 다른 NR 가황물의 열노화 특성)

  • Choi, Sung-Seen;Park, Byung-Ho
    • Elastomers and Composites
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    • v.40 no.3
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    • pp.181-187
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    • 2005
  • Changes of physical properties or NR vulcanizates with different cure systems by thermal aging were investigated. Two sulfur cure systems and one resole cure system were employed, and total contents of the curatives were varied. For the NR vulcanizates with sulfur cure systems, hardness and modulus after the thermal aging at $90^{\circ}C$ for 3 days were increased, but elongation at break and tensile strength were decreased. For the NR vulcanizates with resloe cure system, the physical properties after the thermal aging were decreased. The change of physical properties by the thermal aging was explained with the crosslink density change. The crosslink densities or the NR vulcanizates with sulfur cure systems were increased after the thermal aging, but those with resole cure system were decreased. Influence of the migration of antidegradant on the changes of physical properties was also investigated. However, the changes of physical properties by the thermal aging were not explained sufficiently with the migration of antigradant.

Effect of NR/BR Blends ratio and Oil Content on the Mechanical Properties of Rubber Isolator at Low Temperature (저온환경에서 NR/BR 블렌드 조성비 및 오일함량이 방진고무재료의 기계적 특성에 미치는 영향)

  • Kim, Wan-Doo;Kim, Wan-Soo;Woo, Chang-Soo;Choi, Sung-Seen
    • Elastomers and Composites
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    • v.39 no.2
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    • pp.95-104
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    • 2004
  • New compounds were made using various NR/BR blend ratio and oil content to improve mechanical properties of rubber isolator at low temperature. Mechanical properties were investigated as a function of NR/BR blend ratio and oil content. Hardness and tensile modulus generally increased, but tensile strength and elongation at break decreased with increasing BR content. Hardness, tensile modulus and tensile strength decreased, but elongation at break were nearly the same with increasing oil content. The glass transition temperature of NR and BR were found to be $-50^{\circ}C$ and $-90^{\circ}C$ respectively based on the abrupt drops in storage elastic modulus and peak of loss factor. Two distinct transition temperature were observed in NR/BR blend compounds and each transition point was not affected by blend level indicating incompatible nature of NR/BR blend.

The Study on the Properties of EPDM/NR Blends (EPDM/NR 블랜드의 물성에 관한 연구)

  • Go, Jin-Hwan;Park, Sung-Soo
    • Elastomers and Composites
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    • v.29 no.2
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    • pp.121-130
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    • 1994
  • The physical properties of rubber blend between natural rubber(NR) and ethylene propylene diene terpolymer(EPDM) were investigated as a study of EPDM composite materials. For EPDM/NR blends, the effects of ethylene and diene contents in EPDM, blend ratio, dicumyl peroxide(DCP) curing system on the physical properties, interfacial adhesion force and dynamic crack growth etc. were studied. EPDM/NR blends loaded with carbon black were prepared by mechanical mixing and cured by plate heating cure press. Crosslinking density was measured by swelling method with toluene. The physical properties of all blends were measured with Instron, fatigue to failure(FTF), Demattia flex cracking tester(DMFC), scanning electron microscopy (SEM), etc. As the ethylene and diene contents in EPDM increased, the physical properties, such as dynamic crack growth, adhesion to other component were increased too. Interfacial adhesion force of EPDM/NR blends to dissimilar layer was improved by the use of optimum peroxide curing system.

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Verticillium dahliae toxins-induced nitric oxide production in Arabidopsis is major dependent on nitrate reductase

  • Shi, Fu-Mei;Li, Ying-Zhang
    • BMB Reports
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    • v.41 no.1
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    • pp.79-85
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    • 2008
  • The source of nitric oxide (NO) in plants is unclear and it has been reported NO can be produced by nitric oxide synthase (NOS) like enzymes and by nitrate reductase (NR). Here we used wild-type, Atnos1 mutant and nia1, nia2 NR-deficient mutant plants of Arabidopsis thaliana to investigate the potential source of NO production in response to Verticillium dahliae toxins (VD-toxins). The results revealed that NO production is much higher in wild-type and Atnos1 mutant than in nia1, nia2 NR-deficient mutants. The NR inhibitor had a significant effect on VD-toxins-induced NO production; whereas NOS inhibitor had a slight effect. NR activity was significantly implicated in NO production. The results indicated that as NO was induced in response to VD-toxins in Arabidopsis, the major source was the NR pathway. The production of NOS-system appeared to be secondary.

An active noise control window system to reduce noise rating in low frequency band (저주파 대역의 소음 평가 지수 개선을 위한 창문형 능동 소음 제어기)

  • Oh, Wongeun
    • The Journal of the Acoustical Society of Korea
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    • v.37 no.5
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    • pp.331-337
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    • 2018
  • In this paper, we apply the NR (Noise Rating) to the evaluation of the residual noise of the window type ANC (Active Noise Control) and study the active noise controller for minimizing the NR value in rooms. We proposed a shape of a noise shaping filter of the Filtered-E LMS (Least Mean Square) algorithm that reduces the NR value within the effective operating frequency band of the ANC. The usefulness of the proposed scheme is verified by simulation and showed that the NR value of the residual noise is lower than the filters used in the conventional psychoacoustic ANC.

Preparation of NR/MG Latex Blend Films and its Mechanical Properties (NR/MG Latex 블랜드필름의 제조 및 그의 기계적특성)

  • Kim, K.S.;Park, J.H.;Eum, J.S.;Kim, S.J.
    • Elastomers and Composites
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    • v.29 no.1
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    • pp.9-17
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    • 1994
  • Methylmetharylate grafted latex(MGL) was prepared by emulsion graft copolymerization of methyl methacrylate onto natural rubber latex(NRL) by using t-butyl hydroperoxide and tetraethylene pentamine in an aqueous medium. Blending of MGL and NRL with different mixing ratio carried out and viscosity and particle size distribution of blend latex were determined. It was found that the optimum condition of mature time, vulcanizing temperature and time for preparation of blend latex films were investigated. latex films prepared by dipping process were meaured. As the reuslt, blend latex(NR-d-MG) films obtained from two-dipping system were more excellent than NR and MG film obtained from one-dipping system.

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Unlicensed Band Traffic and Fairness Maximization Approach Based on Rate-Splitting Multiple Access (전송률 분할 다중 접속 기술을 활용한 비면허 대역의 트래픽과 공정성 최대화 기법)

  • Jeon Zang Woo;Kim Sung Wook
    • KIPS Transactions on Computer and Communication Systems
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    • v.12 no.10
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    • pp.299-308
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    • 2023
  • As the spectrum shortage problem has accelerated by the emergence of various services, New Radio-Unlicensed (NR-U) has appeared, allowing users who communicated in licensed bands to communicate in unlicensed bands. However, NR-U network users reduce the performance of Wi-Fi network users who communicate in the same unlicensed band. In this paper, we aim to simultaneously maximize the fairness and throughput of the unlicensed band, where the NR-U network users and the WiFi network users coexist. First, we propose an optimal power allocation scheme based on Monte Carlo Policy Gradient of reinforcement learning to maximize the sum of rates of NR-U networks utilizing rate-splitting multiple access in unlicensed bands. Then, we propose a channel occupancy time division algorithm based on sequential Raiffa bargaining solution of game theory that can simultaneously maximize system throughput and fairness for the coexistence of NR-U and WiFi networks in the same unlicensed band. Simulation results show that the rate splitting multiple access shows better performance than the conventional multiple access technology by comparing the sum-rate when the result value is finally converged under the same transmission power. In addition, we compare the data transfer amount and fairness of NR-U network users, WiFi network users, and total system, and prove that the channel occupancy time division algorithm based on sequential Raiffa bargaining solution of this paper satisfies throughput and fairness at the same time than other algorithms.

Influence of Thermal Aging in Change of Crosslink Density and Deformation of Natural Rubber Vulcanizates

  • Choe, Seong Sin
    • Bulletin of the Korean Chemical Society
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    • v.21 no.6
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    • pp.628-634
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    • 2000
  • Crosslink is the most important chemistry in a rubber vulcanizate. Degree and type of crosslinks of the vulcanizate determine its physical properties. Change of crosslink density and deformation of a rubber vulcanizate by thermal aging were studied using natural rubber (NR) vulcanizates with various cure systems (conventional, semi-EV, and EV) and different cure times (under-, optimum-, and overture). All the NR vulcanizates were deformed by the thermal aging at 60-100 $^{\circ}C.$ The higher the aging temperature is, the more degree of the deformation is. The undercured NR vulcanizates after the thermal aging were deformed more than the optimumand overcured ones. The NR vulcanizates with the EV cure system were less deformed than those with the conventional and semi-EV cure systems. The deformation of the NR vulcanizates was found to be due to change of the crosslink density of the vulcanizates. The crosslink densities of all the vulcanizates after the extraction of organic materials were also changed by the thermal ging. The sources to change the crosslink densities of the vulcanizates by the thermal aging were found to be dissociation of the existing sulfur crosslink and the formation of new crosslinks by free sulfur, reaction products of curing agents, and pendent sulfide groups.

Synthesis of Natural Rubber-g-polyacrylamide Polymer (Natural Rubber-polyacrylamide Graft 공중합체의 합성)

  • Son, Cha Hoo;Kim, Kyung Hwan;Park, Tchun Wook
    • Textile Coloration and Finishing
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    • v.7 no.4
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    • pp.45-53
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    • 1995
  • Natural rubber(NR)-polyacrylamide(PAAm) graft copolymers(GP)(toluene soluble GP : TSGP, water dispersible GP : WDGP) have been synthesized as coupling agents by pre-emulsification methods based on "inverse emulsion graft polymerization" technique. The polymerization was carried out at $65^{\circ}C$ using Azobisisobytyro nitrile(AIBN) as an initiator in the inverse emulsion system formed by inxing NR toluene solution with inverse emulsion of awueous AAm solution emulsified with $Tween^{\#}$ 80 in toluene. The mechanism of inverse emulsion graft copolymerization was studied on AAm conversion, % grafting, grafting efficiency, NR conversion, production ratio of TSGP and amount of GP(sum of TSGP and WDGP). The reaction has been confirmed through use of optical microscope to proceed via adsorption of emulsifier colloid particles onto the stretched NR molecule. From the analysis of the effects of various polymerization conditions on the grafting, it has also been found that the present rection system can easily yield high(over 90%) grafting efficiency and AAm conversion and relatively high(over 80%) NR conversion.onversion.

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