• Title/Summary/Keyword: NPB

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Synthesis and Electroluminescent Properties of Cabazolyl Vinylene Derivatives

  • Seo, H.J.;Park, H.C.;Lee, S.E.;Park, J.W.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.952-954
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    • 2003
  • We report the photo-(PL) and electroluminescence (EL) properties of new conjugated compounds based on carbazolyl vinylene moiety, 3,3'-(1,4-phenylene di-2,1-ethenediyl) bis[9-ethyl-(E,E)-9H-carbazole](PEEC) and 3,3'-([1,1'-biphenyl]-4,4'-diyldi-2,1-ethenediyl)bis[9-ethyl-9H-carbazole](BPEEC), as emitting materials. The ITO/m-MTDATA/NPB/BPEEC/Alq3/LiF/Al device shows bluish-green EL spectrum at 490nm and turn-on voltage at 8V. PEEC shows bluish-green EL around ${\lambda}$ max=496nm and turn-on voltage at 6V and 2.4 Cd/A efficiency in ITO/m-MTDATA/NPB/PEEC/Alq3/LiF/Al device.

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Synthesis and Electroluminescent Properties of Imidazole Derivatives (Imidazole 유도체들의 합성과 유기 발광 특성 연구)

  • 박종욱;서현진
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.12
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    • pp.1121-1124
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    • 2003
  • We report the photo (PL) and electro luminescence (EL) properties of new conjugated compounds based on imidazole moiety, 4,4' -di(4,5 diphenyl-N-imidazolyl)stilbene(DDPIS) and 4,4'-di(2,4,5-triphenyl-N-imidazolyl)stilbene(DTPIS), as emitting materials. ITO/m-MTDATA/NPB/DDPIS/Alq3/LiF/AI device shows blue EL spectrum at 456 ㎚ and 0.3 cd/ A and turn on voltage at 7 ∼ 8 V. DTPIS shows blue EL spectrum at around λmax=453㎚ and 0.5 cd/A efficiency in ITO/m-MTDATA/NPB/DTPIS/Alq3/LiF/Al device.

Voltage-Current-luminance Characteristics of Organic : Light-Emitting Diodes depending on Hole-Injection Buffer Layer (유기 발광 소자에서 정공 주입 버퍼층에 의한 전압-전류-휘도 특성)

  • Jeong Joon;Kim Tag-Yong;Ko Keel-Young;Lee Deok-Jin;Hong Jin-Woong
    • 한국컴퓨터산업교육학회:학술대회논문집
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    • 2003.11a
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    • pp.49-54
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    • 2003
  • In this work, we have seen the effect of hole-transporting layer in organic light-emitting diodes using N,N'-biphenyl-N,N'-bis-(3-methylphenyl)-[1,1'-biphenyl]-4,4'-diamine(TPD) and N,N'-biphenyl-N,N'-bis-(1-naphenyl)-[1,1'-biphenyl]-4,4'-diamine(NPB). NPB is regarded as a better hole trans porting material than TPD, since it has a higher glass transition temperature$(T_g)$. And current -voltage, luminance-voltage and external quantum efficiency of device were measured with the thickness variation of buffer layer using copper phathalocyanine(CuPc) and polytetrafluoroethylene (PTFE) at room temperature. We have obtained an improvement of External quantum efficiency when the CuPc 30[nm] and PTFE 1.0[nm] is used.

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Error Rate for the Limiting Poisson-power Function Distribution

  • Joo-Hwan Kim
    • Communications for Statistical Applications and Methods
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    • v.3 no.1
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    • pp.243-255
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    • 1996
  • The number of neutron signals from a neutral particle beam(NPB) at the detector, without any errors, obeys Poisson distribution, Under two assumptions that NPB scattering distribution and aiming errors have a circular Gaussian distribution respectively, an exact probability distribution of signals becomes a Poisson-power function distribution. In this paper, we show that the error rate in simple hypothesis testing for the limiting Poisson-power function distribution is not zero. That is, the limit of ${\alpha}+{\beta}$ is zero when Poisson parameter$\kappa\rightarro\infty$, but this limit is not zero (i.e., $\rho\ell$>0)for the Poisson-power function distribution. We also give optimal decision algorithms for a specified error rate.

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Perovskite Solar Cells through Application of Hole Transporting Layers based on Vacuum Thermal Evaporation (진공 열 증착 기반의 정공수송층 적용을 통한 페로브스카이트 태양전지)

  • Kim, Hye Seung;Song, Myoung Hoon
    • Current Photovoltaic Research
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    • v.10 no.1
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    • pp.23-27
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    • 2022
  • In this study, we investigate organic-inorganic halide perovskite solar cells with a vacuum thermal evaporated hole transporting layer (NPB/MoO3-x). By replacing solution process based Spiro-MeOTAD with vacuum thermal evaporation based NPB/MoO3-x, a thin hole transporting layer was implemented. In addition, parasitic absorption that may occur during the doping process was eliminated by excluding solution process doping. In a solar cell with a thin vacuum thermal evaporated hole transporting layer, the short-circuit current density (Jsc) increased to 23.93 mA/cm2, resulting in the highest power converstion efficiency (PCE) at 18.76%. Considering these results, it is essential to control the thickness of hole transporting layer located at the top in solar cell configuration.

Dependency of the emission efficiency on doping profile of the red phosphorescent organic light-emitting diodes

  • Park, Won-Hyeok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.224-224
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    • 2016
  • Many researchers have been tried to improve the performance of the phosphorescent organic light-emitting diode(PHOLED) by controlling of the dopant profile in the emission layer. In this work, as shown in Fig. 1 insert, a typical red PHOLED device which has the structure of ITO/NPB(50nm)/CBP(30nm)/TPBi(10nm)/Alq3(20nm)/LiF(0.8nm)/Al(100nm) is fabricated with a 5nm thick doping section in the emission layer. The doping section is formed by co-deposition of CBP and Ir(btp)2acac with a doping concentration of 8%, and it's location(x) is changed from HTL/EML interface to EML/HBL in 5nm steps. The current efficiency versus current density of the devices are shown in Fig. 1. By changing the location of doping section, as shown in Fig. 1 and 2, at x=5nm, the efficiency shows the maximum of 3.1 cd/A at 0.5 mA/cm2 and it is slightly decreased when the section is closed to HTL and slightly increased when the section is closed to HBL. If the doping section is closed to HTL(NPB) the excitons can be quenched easily to NPB's triplet state energy level(2.5eV) which is relatively lower than that of CBP(2.6eV). Because there is a hole accumulation at EML/HBL interface the efficiency can be increased slightly when the section is closed to HBL. Even the thickness of the doping section is only 5nm,. the maximum efficiency of 3.1 cd/A with x=5 is closed to that of the homogeneously doped device, 3.3 cd/A, because the diffusion length of the excitons is relatively long. As a result, we confirm that the current efficiency of the PHOLED can be improved by the doping profile optimization such as partially, not homogeneously, doped EML structure.

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Performance Analysis of Cluster Network Interfaces for Parallel Computing of Computational Fluid Dynamics (전산유체역학 병렬해석을 위한 클러스터 네트웍 장치 성능분석)

  • Lee, Bo Seong;Hong, Jeong U;Lee, Dong Ho;Lee, Sang San
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.31 no.5
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    • pp.37-43
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    • 2003
  • Parallel computing method is widely used in the computational fluid dynamics for efficient numerical analysis. Nowadays, low cost Linux cluster computers substitute for traditional supercomputers with parallel computing shcemes. The performance of nemerical solvers on an Linux cluster computer is highly dependent not on the performance of processors but on the performance of network devices in the cluster system. In this paper, we investigated the effects of the network devices such as Myrinet2000, gigabit ethernet, and fast ethernet on the performance of the cluster system by using some benchmark programs such as Netpipe, LINPACK, NAS NPB, and MPINS2D Navier-Stokes solvers. Finally, upon this investigation, we will suggest the method for building high performance low cost Linux cluster system in the computational fluid dynamics analysis.

Design of an Electron Ohmic-Contact to Improve the Balanced Charge Injection in OLEDs

  • Park, Jin-U;Im, Jong-Tae;Yeom, Geun-Yeong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.283-283
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    • 2011
  • The n-doping effect by doping metal carbonate into an electron-injecting organic layer can improve the device performance by the balanced carrier injection because an electron ohmic contact between cathode and an electron-transporting layer, for example, a high current density, a high efficiency, a high luminance, and a low power consumption. In the study, first, we investigated an electron-ohmic property of electron-only device, which has a ITO/$Rb_2CO_3$-doped $C_{60}$/Al structure. Second, we examined the I-V-L characteristics of all-ohmic OLEDs, which are glass/ITO/$MoO_x$-doped NPB (25%, 5 nm)/NPB (63 nm)/$Alq_3$ (32 nm)/$Rb_2CO_3$-doped $C_{60}$(y%, 10 nm)/Al. The $MoO_x$doped NPB and $Rb_2CO_3$-doped fullerene layer were used as the hole-ohmic contact and electron-ohmic contact layer in all-ohmic OLEDs, respectively, Third, the electronic structure of the $Rb_2CO_3$-doped $C_{60}$-doped interfaces were investigated by analyzing photoemission properties, such as x-ray photoemission spectroscopy (XPS), Ultraviolet Photoemission spectroscopy (UPS), and Near-edge x-ray absorption fine structure (NEXAFS) spectroscopy, as a doping concentration at the interfaces of $Rb_2CO_3$-doped fullerene are changed. Finally, the correlation between the device performance in all ohmic devices and the interfacial property of the $Rb_2CO_3$-doped $C_{60}$ thin film was discussed with an energy band diagram.

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다층 그래핀과 유기물로 구성된 계면의 전자분광학 분석을 이용한 에너지 준위 정렬 분석

  • Seo, Jae-Won;Kim, Ji-Hun;Gwon, Dae-Gyeon;Maeng, Min-Jae;Mun, Je-Hyeon;Lee, Jeong-Ik;Choe, Seong-Ryul;Kim, Taek-Yeong;Park, Yong-Seop
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.163-163
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    • 2013
  • 최근 들어서 유연 OLED (Organic Light-Emitting Diodes) 소자에 대한 연구가 증가하면서 전통적인 ITO 전극을 대체할 수 있는 전극물질 후보로 그래핀이 많은 주목을 받고 있다. 그 중에 CVD 방법으로 합성된 다층 그래핀(Few layer graphene, FLG)은 실제 상용화되는 소자에 응용이 될 가능성이 높아 많은 연구가 이 방향으로 진행되고 있다. 이 연구에서는 다층 그래핀과 유기물질 사이의 계면을 전자분광학 분석을 이용해 각 분자층 사이의 에너지 준위 변화에 대해 분석했다. 에너지 준위 정렬을 이용하면 각 분자층간의 정공주입 에너지장벽을 알 수 있는데 이 에너지 장벽은 소자의 효율에 직접적으로 연관되는 값이다. 정공 주입층 물질로는 TAPC 1,1- Bis[4-[N,N'-di(p-tolyl)amino]phenyl]cyclohexane (TAPC)를 사용했고, 다층 그래핀과 TAPC층 사이의 에너지 준위 정렬을 분석한 결과 다층 그래핀과 TAPC층 사이에는 ~1.4 eV의 에너지 장벽이 존재함을 확인했다. 하지만 OLED 소자로 활용하기 위해서는 이보다 더 낮은 에너지 장벽을 필요로 하기 때문에 두 물질 사이에 4,4'-bis(N-phenyl-1-naphthylamino)biphenyl (NPB), 1,4,5,8,9,11-hexaazatriphenylene-hexacarbonitrile (HAT-CN)을 삽입하여 에너지 장벽을 낮추기 위한 시도를 해 보았다. 그래핀과 TAPC 사이에 중간층으로 NPB를 사용했을 때의 에너지 장벽은 0.55 eV, HAT-CN을 사용했을 때는 0.4 eV로 TAPC만 사용했을 때보다 ~1 eV정도 에너지 장벽을 낮추는 효과를 보여줬다. 이 연구를 통해 다층 그래핀을 OLED 소자의 전극으로 활용할 수 있는 가능성을 볼 수 있었다.

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Fabrication and Characterization of High Performance Green OLEDs using $Alq_3$-C545T Systems ($Alq_3$-C545T시스템을 이용한 고성능 녹색 유기발광다이오드의 제작과 특성 평가)

  • Jang Ji-Geun;Kim Hee-Won;Shin Se-Jin;Kang Eui-Jung;Ahn Jong-Myong;Lim Yong-Gyu
    • Journal of the Microelectronics and Packaging Society
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    • v.13 no.1 s.38
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    • pp.51-55
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    • 2006
  • The green emitting high performance OLEDs using the $Alq_3$-C545T fluorescent system have been fabricated and characterized. In the device fabrication, 2-TNATA [4,4',4'-tris(2-naphthylphenyl-phenylamino)-triphenylamine] as a hole injection material and NPB [N,N'-bis(1-naphthyl)-N,N'-diphenyl-1,1'-biphenyl-4,4'-diamine] as a hole transport material were deposited on the ITO(indium thin oxide)/glass substrate by vacuum evaporation. And then, green color emission layer was deposited using $Alq_3$ as a host material and C-545T[10-(2-benzothiazolyl)-1,1,7,7- tetramethyl-2,3,6,7-tetrahydro-1H,5H,11H-[1]/benzopyrano[6,7,8-ij]-quinolizin-11-one] as a dopant. Finally, small molecule OLEDs with structure of ITO/2-TNATA/NPB/$Alq_3$:C545T/$Alq_3$/LiF/Al were obtained by in-situ deposition of $Alq_3$, LiF and Al as the electron transport material, electron injection material and cathode, respectively. Green OLEDs fabricated in our experiments showed the color coordinate of CIE(0.29, 0.65) and the maximum power efficiency of 7.3 lm/W at 12 V with the peak emission wavelength of 521 nm.

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