• Proceedings of the KSME Conference
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• 2003.11a
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• pp.448-453
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• 2003

In this study, the effects of oxygen component in fuel and exhaust gas recirculation(EGR) method on the exhaust emissions has been investigated for a D.I. diesel engine. It was tested to estimate change of exhaust emission characteristics for the commercial diesel fuel and oxygenate blended fuel which has five kinds of blending ratio. Dimethoxy methane(DMM) contains oxygen component 42.5% in itself. and it is a kind of effective oxygenated fuel for reduction of smoke emission. It was affirmed that smoke emission was decreased with increasing of DMM blending ratio. But, NOx emission was increased compared with commercial diesel fuel. It was needed a NOx reduction countermeasure that EGR method was used as a countermeasure for NOx reduction. It was found that simultaneous reduction of smoke and NOx emission was achieved with DMM blended fuel and cooled EGR method($10{\sim}15%$).

• Proceedings of the Korean Society of Marine Engineers Conference
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• 2002.05a
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• pp.187-191
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• 2002

The exhaust gas from electric power stations, incinerators and industrial boilers contains considerable amount of harmful nitric oxide which causes air pollution. Selective catalytic reduction system with ammonia as a reductant(NH$_{3}$ SCR) have been applied to remove NOx since 1970. it is widely accepted that the NH$_{3}$ SCR process is the best method for the removal of NOx. In this paper the design of SCR reactor based on the NOx displacement is considered and the design program of SCR reactor is developed. The newly developed design program for de-NOx system maybe used in practice.

• Journal of Environmental Science International
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• v.12 no.1
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• pp.47-54
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• 2003

This paper have examined the optimum combination of SNCR and SCR by varying SNCR injection temperature and NSR ratio along with SCR space velocity. NOx reduction experiments using a SNCR/SCR combined process have been conducted in simple NO/NH$_3$/O$_2$ gas mixtures. Total gas flow rate was kept constant 4 liter/min throughout the SNCR and SCR reactors, where initial NOx concentration was 500 ppm in the presence of 5% O$_2$. Commercial catalyst, sulfated V$_2$O$\_$5/-WO$_3$/TiO$_2$, was used for SCR NOx reduction. The residence time and space velocity were around 1.67 sec, 2,400 h$\^$-1/ and 6,000 h$\^$-1/ in the SNCR and SCR reactors, respectively. SNCR NOx reduction effectively occurred in a temperature window of 900-950$^{\circ}C$. About 88% NOx reduction was achieved with an optimum temperature of 950$^{\circ}C$ and NSR=1.5. SCR NOx reduction using commercial V$_2$O$\_$5/-WO$_3$-SO$_4$/TiO$_2$ catalyst occurred in a temperature window of 200-450$^{\circ}C$ 80-98% NOxreduction was possible with SV=2400 h$\^$-1/ and a molar ratio of 1.0-2.0. A SNCR/SCR(SV=6000 h$\^$-1/) combined process has shown same NOx reduction compared with a stand-alone SCR(SV=2400 h$\^$-1/) unit process of 98% NOx reduction. The NH$_3$-based chemical could routinely achieve SNCR/SCR combined process total NOx reductions of 98% with less than 5 ppm NH$_3$ slip at NSR ranging from about 1.5 to 2.0, SNCR temperature of 900$^{\circ}C$-950$^{\circ}C$, and SCR space velocity of 6000 h$\^$-1/. Particularly, more than 98% NOx reduction was possible using the combined process under the conditions of T$\_$SNCR/=950$^{\circ}C$, T$\_$SCR/=350$^{\circ}C$, 5% O$_2$, SV=6000 h$\^$-1/ and NH$_3$/NOx=1.5. A catalyst volume was about three times reduced by SNCR/SCR combined process compared with SCR process under the same controlled conditions.

• Transactions of the Korean Society of Automotive Engineers
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• v.19 no.1
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• pp.117-124
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• 2011

Automotive engines require strategies to fulfill the emission regulations in terms of NOx and PM. A dramatic reduction in NOx and PM emissions could be achieved with high pressure injection, innovative combustion strategies and EGR. Recently, Lean NOx Trap (LNT) and Urea-SCR are considered as more practical strategy to suppress the engine-out emissions substantially for copying with severe regulation. These systems need to reduce the reducing agent injection system which has a huge impact on NOx purification efficiency. In this paper, different three injectors have been used to investigate spray characteristics and engine emission test was conducted to clarify the effect of these injectors on the NOx reduction.

• Transactions of the Korean Society of Automotive Engineers
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• v.10 no.3
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• pp.77-84
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• 2002

Measurements of NO and NOx emission of laminar partially premixed LPG/air flames with and without acoustic excitation are reported. The NOx emission at the tailpipe of a combustion chamber is determined by chemiluminescent analyser. The NOx measurements are taken in flames with several different center tube equivalance ratio( ø$\sub$o/), and overall equivalace ratio(ø$\sub$o/) for a fixed fuel flowrate. The NOx emission decrease to reach a minimum value at an optimum ø$\sub$c/ 2. Theø$\sub$c/ 2 flame gives a compromise of thermal NO and prompt NO mechanism. In the case of excitation. the visual shape of the flame is changed from laminar flame to turbulent-like flame. With increasing levels of excitation amplitude, an optimum value of the NO and NOx emission exists. A shorter flame caused by the enhanced upstream mixing due to acoustic excitation results in the reduction of NO and NOx emission in the present flames. The reduction of flame length affects the shorter residence time of center tube mixture, and significantly influences the NOx reduction.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.25 no.12
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• pp.1793-1801
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• 2001

A study of low NOx atomizer was carried out to reduce nitrogen oxides(NOx) in a liquid fuel burner flame. The basic concept of NOx reduction in this atomizer is the fuel 2-staging combustion which is generated by a single atomizer forming two different stoichiometric flames. Two orifices swirl atomizer was selected and modified to realize this concept, and it was tested to obtain the design process of low NOx atomizer. These experiments were achieved to find out the relationship between the injection pressures and the flow rate, spray angle and drop size of swirl atomizer as well as to confirm the NOx reduction concept in real plant(power boiler). In comparison between experimental and theoretical results, the correct discharge coefficient and spray angle were obtained. In real burning test, NOx reduction rate was reached to above 27% of the case using conventional swirl atomizer.

• Transactions of the Korean Society of Automotive Engineers
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• v.12 no.4
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• pp.31-35
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• 2004

A new combustion strategy called LIFC(Late Injection ＆ Fast Combustion) was developed for simultaneous reduction of particulate matter(PM) and nitrogen oxides(NOx) in exhaust emission of diesel engines, In this study, effects of injection timing and injection pressure under relatively high EGR rate were investigated. The experiments were conducted in a conventional engine over a range of commercial engine speed. The test engine could be operated in LIFC up to 2000rpm / bmep 5 bar condition with significant reduction of NOx and PM. The experimental results showed potential for the mechanism of the simultaneous reduction of NOx and PM from HSDI diesel engines.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.40 no.10
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• pp.637-644
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• 2016

The purpose of this study is to understand the characteristics of unburned carbon (UBC) and NOx emissions for pulverized coal when air staging combustion is applied. A two-staged drop tube furnace capable of applying air staging combustion was designed and installed. The combustion of sub-bituminous (Tanito) has been investigated. UBC and the NOx concentration were measured under various temperatures and stoichiometric ratios in unstaged and staged combustion. As a result, UBC decreased and the NOx concentration increased with an increase in stoichiometric ratio and temperature. In particular, the NOx reduction mechanism was activated when the temperature in the fuel rich zone increased. Both UBC and the NOx concentration decreased as the temperature increased in the fuel rich zone. A high NOx reduction effect was obtained, compared to the UBC increase, when the air staging technique was applied.

• Journal of Environmental Science International
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• v.13 no.6
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• pp.537-542
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• 2004

$V_{2}O_{5}/TiO_{2}$ catalysts promoted with Mn were prepared and tested for selective catalytic reduction of NOx in $NH_3.$ The effects of promoter content, degree of catalyst loading were investigated for NOx activity while changing temperatures, mole ratio, space velocity and $O_2$ concentration. Among the various $V-{2}O_{5}$ catalysts having different metal loadings, $V-{2}O_{5}$(1 wt.%) catalyst showed the highest activity(98%) under wide temperature range of $200-250^{\circ}C.$ When the $V-{2}O_{5}$ catalyst was further modified with 5 wt.% Mn as a promoter, the highest activity(90-47%) was obtained over the low temperature windows of $100-200^{\circ}C.$ From Mn-$V_{2}O_{5}/TiO_{2}$, it was found that by addition of 5 wt.% Mn on $V_{2}O_{5}/TiO_{2}$ catalyst, reduction activity of catalyst was improved, which resulted in the increase of catalytic activity and NOx reduction. According to the results, NOx removal decreased for 10%, but the reaction temperature down to $100^{\circ}C.$

• Transactions of the Korean Society of Automotive Engineers
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• v.15 no.3
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• pp.147-152
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• 2007

This study investigates the aging characteristics of NOx storage and reduction(NSR) catalyst on the emission conditions of lean burn natural gas vehicles. We designed various NSR catalysts using by the double-layer washcoat technology to increase of a surface area and a thermal durability performance of the catalysts. The experiments were conducted with 3 kinds of the NSR catalysts, which were manufactured using by a honeycomb cordierite substrate. It was found that Ba is weak in the thermal aging because it has lower melting temperature than that of precious metals (PMs). The suitable loading amount of Ba in this study should be about 42 g/L from the results of the NOx adsorption and the NOx reduction efficiency. The major reason in deactivation of the NSR catalyst is the decrease of the adsorption site owing to the agglomeration and sintering of Ba rather than PM aging by hydrothermal aging. It was confirmed by results of BET, SEM and TEM.