• 제목/요약/키워드: NOx concentration

검색결과 450건 처리시간 0.021초

광양만권 질소산화물(NOx)의 수치모의 (Numerical Simulation of NOx Concentration in Gwangyang Bay, Korea)

  • 이상득;유지영
    • 한국환경과학회지
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    • 제11권9호
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    • pp.897-905
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    • 2002
  • A three-dimensional photochemical air pollution model considered advection, dispersion, photochemical reactions, and precipitation processes was developed. The calculated results of meteorological observation clearly exhibited geographical effects of Gwangyang Bay, in which land and sea breezes, mount-valley winds and local circular winds occurred. The observed results of daytime NOx concentrations were slightly higher than the calculated NOx concentrations in Yosu industrial complex, Gwangyang iron mill, and container yard. Eventually, the calculated NOx results generally agreed well with the observed ones.

OZIPR을 이용한 부산지역 고농도 오존 사례 모사 (A Numerical Simulation of High Ozone Episode Using OZIPR in Busan)

  • 도우곤;이화운;정우식
    • 한국환경과학회지
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    • 제16권8호
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    • pp.985-994
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    • 2007
  • To investigate the effect of NOx and VOCs(volatile organic compounds) on the generation of high ozone episode, examined the hourly variations of ozone, NOx and VOCs concentrations, and calculated the ozone isopleth about maximum ozone concentrations using OZIPR which was presented by U. S. EPA at three sites in Busan. There was some difference by the sites, but decreasing VOCs concentration was effective for reduction of ozone at 22 July, the episode day of 2005. In the year 2006, the episode day was 8 August and the variations of NOx and VOCs concentration was little than variation of ozone. So it was estimated that the photochemical production of ozone was low than transportation of ozone. And the result of the OZIPR modeling was that decreasing VOCs concentration was effective for reduction of ozone.

Plasma반응에 의한 NOx와 Ozone의 특성에 관한 연구 (A Study on Characteristics of NOx and Ozone by Plasma Reaction)

  • 최재욱;산외서수;최재진
    • 한국가스학회지
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    • 제4권2호
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    • pp.1-6
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    • 2000
  • 가스중에 포함되어 있는 NOx를 안전하게 처리하기 위하여 침상전극을 취부한 플라즈마 반응기를 제작하여 장치의 특성을 실험적으로 조사하여 유효성을 검정하였다. 반응가스는 $NO/N_2$ 혼합가스와 $N_2/O_2$ 혼합가스를 이용하여 초기 NO농도를 설정하고, 유속을 2${\iota}$/min으로 공급하였다. NOx의 반응특성은 방전주입전력이 높을때는 NO의 농도가 감소하였으며, 산소의 농도 증가시에 NO의 분해가 용이하고 NO의 분해에너지 효율이 높았다. 또한 NO의 농도가 증가할 수록 NO의 분해에너지 효율은 높으나 분해율은 낮았다. 오존의 특성은 방전주입전력이 높을수록 오존의 생성이 증가하고, $NO/N_2$의 농도가 증가할 수록 오존의 생성량이 감소하였다.

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메탄/산소 난류 확산화염의 연소 특성에 관한 연구 (A Study on Combustion Characteristics of Turbulent Methane/Oxygen Diffusion Flames)

  • 이상민;김호근;김한석;안국영
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2004년도 제28회 KOSCO SYMPOSIUM 논문집
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    • pp.118-123
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    • 2004
  • The combustion characteristics of 0.03MW turbulent methane/oxygen diffusion flames have been investigated to give basic informations for designing industrial oxyfuel combustors. NOx reduction has become one of the most determining factors in the combustor design since 3-5% nitrogen is intrinsically included from the current oxygen producing processes. Flame lengths and NOx concentrations were measured by varying flow velocities with and without installing quarls. Flame stabilities are significantly enhanced by oxyfuel combustion in contrast to air-fuel combustion. Flame length decreases with increasing fuel or oxygen velocity because of the enhancement of turbulent mixing. NOx concentration was reduced with increasing flo velocities. This can be attributed to the entrainment of inert product gases into flame decreasing flame temperature. The installation of quarl on the burners rather increased NOx concentration since the quarl blocked the entrainment above the nozzles.

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Urea-SCR 시스템의 유동혼합 개선을 위한 혼합기 형상에 관한 수치적 연구 (NUMERICAL STUDY ON THE MIXER TYPE OF UREA-SCR SYSTEM FOR FLOW MIXING IMPROVEMENT)

  • 이종욱;최훈기;유근종;김원석
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 2010년 춘계학술대회논문집
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    • pp.368-375
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    • 2010
  • To alleviate NOx emission, a variety of approaches has been applied. In marine diesels, the application of SCR systems has been considered an effective exhaust aftertreatment method for NOx emission control. Most current SCR systems use a various catalyst for the reaction of ammonia with NOx to form nitrogen and water. In theory, it is possible to achieve 100% NOx if the NH3-to-NOx ratio is 1:1. However, the reaction has a limited non-uniformity of the exhaust gas flow and ammonia concentration distribution. Therefore it is necessary to investigate the optimum flow conditions. In order to achieve uniform flow at monolith front face, we are equipped with a various mixed device. In this paper, it is presented that the mixed devices play an important role improvement of flow patterns and particle distributions of NH3 by numerical simulation.

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Urea-SCR 시스템에서 유동혼합 개선을 위한 혼합기 형상에 관한 수치적 연구 (NUMERICAL STUDY ON THE MIXER TYPES OF UREA-SCR SYSTEM FOR FLOW MIXING IMPROVEMENT)

  • 이종욱;최훈기;유근종
    • 한국전산유체공학회지
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    • 제15권4호
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    • pp.9-16
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    • 2010
  • To alleviate NOx emission, a variety of approaches has been applied. In marine diesels, the application of SCR systems has been considered an effective exhaust aftertreatment method for NOx emission control. Most current SCR systems use a various catalyst for the reaction of ammonia with NOx to form nitrogen and water. In theory, it is possible to achieve 100% NOx if the $NH_3$-to-NOx ratio is 1:1. However, the reaction has a limited non-uniformity of the exhaust gas flow and ammonia concentration distribution. Therefore, it is necessary to investigate the optimum flow conditions. In order to achieve uniform flow at monolith front face, we are equipped with a various mixed devices. In this paper, it is presented that the mixed devices play an important role improvement of flow patterns and particle distributions of $NH_3$ by numerical simulation.

승용디젤엔진의 연료분사 제어를 통한 LNT 촉매의 NOx 저감 특성에 관한 연구 (A Study on NOx Reduction Characteristics of LNT Catalyst with Fuel Injection Control in Light-duty Diesel Engine)

  • 황승권;고아현;윤주웅;명차리;박심수;김은석
    • 한국자동차공학회논문집
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    • 제20권4호
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    • pp.150-155
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    • 2012
  • Lean NOx Trap (LNT) catalysts are capable of reducing exhaust NOx emissions from diesel engines. LNT stores NOx in lean condition and exhausts N2 by reducing NOx in rich condition. NOx reduction characteristic of LNT catalysts using throttle position sensor and fuel injection timing control for light-duty diesel engine was investigated. In contrast to SCR system, LNT catalyst uses diesel fuel in resuctant. Also if the concentration of reductant is exceeded, excessive amount of reductant will slip throughout LNT and cause another emission problem. Thus LNT regeneration with precise engine control established that can make higher NOx conversion efficiency and lower fuel penalty, prevent another emission problem. NOx and reductant concentration were measured by the NOx sensor and Mexa7100D equipped inlet and outlet of catalyst. As a result of engine test, regeneration strategy has reached high of 77.8% NOx conversion efficiency according to engine operation condition. Moreover, we have proved that it is possible to use regeneration strategy of LNT within 5% fuel penalty.

생석회 탄산화를 위한 회전로 배가스 재순환이 연소 및 NOx 발생양에 미치는 영향 (Effect of Recirculation of Rotary Kiln Exhaust Gas for the Carbonation of Lime on the Combustion Conditions and the Amounts of NOx)

  • 이만승;이시형
    • 자원리싸이클링
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    • 제12권1호
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    • pp.41-47
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    • 2003
  • 대기에 방치된 생석회의 상온에서 내수화성을 향상시키기 위해 생석회의 탄산화반응과 수화반응실험을 수행하였다. 제강공정에서 사용시까지 수화반응을 억제시키기 위해서는 생석회 표면을 약 6%정도 탄산화시킬 필요가 있었다. 생석회의 탄산화를 위한 회전로 배가스 재순환이 평형연소온도 및 NOx농도에 미치는 영향을 열역학적으로 계산한 결과, 배가스 부피 백분율이 증가함에 따라 연소온도와 NOx농도는 감소하였다.

탄화수소 가스 첨가가 PPCP 장치에 의한 NOx 및 SOx 저감에 미치는 영향 (Effect of Adding Hydrocarbon Gases for Reduction of NOx and SOx Using PPCP)

  • 김홍석;강형수;정태용
    • 한국자동차공학회논문집
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    • 제7권5호
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    • pp.73-80
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    • 1999
  • To decrease NOx and SOx using PPCP(Pulse-induced Plasma Chemical Process). This study is tried to obtain the relation and the basic data under the various conditions such the initial concentrations of NOx and SOx. The additional amount of hydrocarbon gases. The concentration of oxygen and input power etc. Especially, this study is focused on the effects of the additional hydrocarbon gases on the decrease of NOx and SOx.

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환경 대기중에서 Nitrate의 생성에 관한 연구(II) (A Study on the Formation of Nitrate in Atmosphere(II))

  • 천만영;이영재;김희강
    • 한국대기환경학회지
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    • 제9권3호
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    • pp.216-221
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    • 1993
  • This study was carried out to determine the concentration of gaseous nitrate$(HNO_3)$ particulate nitrate$(NO_3^-)$ and conversion rate of NOx to nitrate in atmosphere in Seoul from Oct 1991 to July 1992. The average concentration of gaseous nitrate in daytime(09:00 - 17:00) was 9.93, 3.37, 7.40 and 10.40$\mug/m^3$ and, in highttime was 6.21, 7.31, 4.79 and 3.86$\mug/m^3$ respectively. The concentratin of $HNO_3$ was greater in summer and daytime than winter and nighttime. But the concentration of $NO_3^-$ was greater in winter and nighttime than in summer and daytime. The average conversion rate of NOx to $HNO_3$(Fn) indaytime was 13.18, 3.78, 9.13 and 23.13% and, in nighttime was 3.06, 1.37, 1.70 and 8.72% during fall, winter, spring and summer respectively. But the average conversion rate of NOx to $NO_3^-$(Fn') in daytime was 5.79, 5.77, 2.63 and 3.90% and in nighttime was 5.95, 6.51, 3.25 and 4.84% respectively. The average conversion rate of NOx to total nitrate $(HNO_3 + NO_3^-)$(Fn') was 12.72, 7.81, 7.82 and 18.40% respectively. The average conversion rate of NOx to $HNO_3$(Fn) was greater than $NO_3^-$(Fn') about 1.6 times.

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