• Title/Summary/Keyword: NOx Removal

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Removal of Nitrogen in Seafood Processing Wastewater Using High-rate Anaerobic Process and Nitritation-denitritation (고율 혐기성 공정과 아질산-아탈질을 연계한 수산물가공폐수의 질소제거)

  • Choi, Yong-Bum;Kang, Dong-Gu;Park, Sang-Sung;Eum, Ki-Hyun;Rim, Jay-Myung;Kwon, Jae-Hyouk
    • Journal of Environmental Health Sciences
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    • v.37 no.4
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    • pp.315-322
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    • 2011
  • Objectives: Organic matter and nitrogen were removed using the EGSB process, a high-rate anaerobic process, in combination with a nitritation-denitritation process, in order to ensure the stable treatment of seafood processing wastewater. Methods: The upflow velocity of an EGGS reactor was operated at 10 m/hr for maximal organics removal efficiency. For removal of nitrogen from seafood processing wastewater a nitritation-denitriation process was applied Results: The efficiency of the EGSB process showed that it has an 80% or more organic matter (CODcr) removal efficiency with an HRT of six hours or more at influent loadings of 17.34 kgCOD/$m^3$/day or less. The methane product for TCODcr removal was 0.23-0.38 $m^3CH_4$/kgCODrem., which was similar to the theoretical generation of STP-state methane, 0.35 $m^3CH_4$/kgTCODrem. In the nitritation-denitritation process, the nitritation conversion rate to $NH_4^+$-N concentration was 82% to 87%, 72% to 81% and 64% to 69% when HRT was 24 hr, 21 hr and 18 hr, respectively. In the denitritation process, the ratio of SCOD consumption to NOx-N removal ranged from 2.347 to 2.587. It was 2.472 on average. Conclusions: The optimal HRT for stable processing of seafood processing wastewater is six hours or more. The ratio of nitrite to total NOx-N was 82% to 96%, which indicates that nitrite accounts for the largest portion of the product.

A Study on Characteristic of NO Reduction by High Level O2Gas in Selective Non-Catalystic Reaction (High Level O2배가스중 NO 저감에 대한 선택적비촉매환원 반응특성에 관한 연구)

  • 이강우;정종현;오광중
    • Journal of Environmental Science International
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    • v.11 no.6
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    • pp.577-582
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    • 2002
  • Selective catalytic reduction and selective non-catalytic reduction processes are mainly used to treat nitrogen oxidants generated from fossil-fuel combustion. Especially, the selective non-catalytic reduction process can be operated more economical and designed more simply than the selective catalytic reduction. For this reason, many researchers carried out to increase the removal efficiency of nitrogen oxidants in the condition of low oxygen concentration by using the selective non-catalytic reduction process. However, this study was flue gas contained high oxygen concentration of 20(v/v%) with ammonia as a reducing agent. Moreover, it carried out experiment with many factors that are reaction temperature, retention time, initial NO concentration, NSR(normalized stoichiometric ratio). It was determined optimal operating conditions to improve NO removal efficiency with SNCR process. The De-NOx efficiency was increased with NSR, initial NO concentration and retention time increasement. This study has NO removal efficiency over 80% in the high oxygen concentration as well as low oxygen concentration. The injection of reducing agent may be considered for SNCR process and facility operation in 850$\^{C}$ of optimal condition.

The Removal Properties of NO Using KOH-Treated ${\gamma}$ -Alumina (KOH로 처리된 ${\gamma}$} -Alumina를 이용한 NO의 제거특성)

  • 모세영;김만수;장홍기;안대현;손종렬
    • Journal of environmental and Sanitary engineering
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    • v.16 no.3
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    • pp.104-110
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    • 2001
  • NOx coming from combustion make photochemical smog and acid rain, cause chronic respiratory disease resulting in critical hazard to environment and human health. Most composition of NOx coming from combustion is NO and the remaining small amount of $NO_x$ is $NO_2$. Currently, many technologies are developed and used to control NO release. One of these technologies is control technology through use of the adsorbent. In this study, two methods were used to make the adsorbent and compared. KOH and ${\gamma}{\;}-alumina$ were mixed by using two methods. Then, the experimental conditions were as follows: the concentrations of KOH used were 1 mole, 0.5 mole, and 0.1 mole, respectively and the amount of ${\gamma}{\;}-alumina$$250^{\circ}C$. As a result, precipitation method, which is one of the production methods of the adsorbent, showed the most removal efficiency as KOH concentration as 1 mole and reaction temperature as $100^{\circ}C$ were used. This study shows 40 to 60% of micropores of ${\gamma}{\;}-alumina$ was lost by the reaction with KOH through the analysis of SEM and BET Finally, KOH is the most predominant factor to control the removal of NO rather than micropore of the adsorbent.

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The Experimental Study on the Removal of Diesel Engine Pollutant Emissions Using DC Non-Thermal-Plasma(NTP) (DC 저온플라즈마를 이용한 디젤엔진 유해 배기가스 저감에 관한 실험적 연구)

  • Chae, Jae-Ou;Hwang, Jae-Won;Jung, Jee-Yong;Han, Jung-Hee;Hwang, Hwa-Ja;Kim, Seok
    • Transactions of the Korean Society of Automotive Engineers
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    • v.9 no.2
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    • pp.35-42
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    • 2001
  • The diesel engine exhaust gas is know as one of the causes to produce photochemical smog, which causes damage on environmental. However, due to the high thermal efficiency and low carbon dioxide emission, the usage of a diesel engine is prevailed. In this study, the DC non-thermal plasma technology used to the particulate matter (PM) aftertreatment. The exhaust gas characteristics and energy density were investigated on the dynamometer test bed and chassis dynamometer with CVS-75 mode in a passenger diesel car. It was reported that the smoke removal efficiency has around the 70% in the dynamometer test with 80W energy consumption and the PM removal efficiency has the 68% in the real car test. The NOx also reduced the 20% according to electrode type respectively. Considering these results, plasma technology is one of the ways to simultaneously removing method the particulate matter (PM) and NOx.

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The influence of $O_2$ concentration on the generation of $NO_2$ by using the wire-plate reactor (선대 평판형 반응기에서 $NO_2$ 생성에 미치는 $O_2$의 영향)

  • Park, Jae-Youn;Kim, Sung-Jin;Kim, Jong-Dal;Lee, Sun-Jae;Ha, Sang-Tae;Han, Sang-Bo;Lee, Dong-Hoon
    • Proceedings of the KIEE Conference
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    • 2000.07c
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    • pp.2050-2052
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    • 2000
  • In this paper, the effect of $O_2$ concentration on NO removal and $NO_2$ generation by corona discharge from simulated flue gas was measured and estimated for the wire-plate reactor. $NO_2$ removal rate was 0$\sim$30[%] under about 3.4[%] of oxygen concentration, however, it was difficult to remove NOx over 3.4[%] of oxygen concentration. It may be due to generate $NO_2$ from $N_2$ and $O_2$ molecules and converse NO to $NO_2$ by 0 and $O_3$. Magnetic field applied to electric field in plasma was very effective for NOx removal under 2[%] of $O_2$ concentration.

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Wet Chemical Process for Improving Air Quality in Semiconductor Manufacturing Process (반도체 생산공정의 대기질 개선을 위한 복합 대기오염물의 습식화학 제거공정)

  • Jun, Chang-Sung;Kim, Hak-Ju;Park, Young-Moo;Lee, Dae-Won;Ham, Dong-Suk;Jeon, Sang-Moon;Lee, Kwan-Young
    • Clean Technology
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    • v.13 no.2
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    • pp.109-114
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    • 2007
  • In this study, we performed basic researches to develop wet purification system for improving air qualities of ventilation in semiconductor manufacturing process. Using 0.5 M aqueous solution of $KMnO_4$, 50 ppm of $NH_3$, SOx and NOx were reduced to 99% successfully. However, the removal of $O_3$ was limited to $22{\sim}30%$ for all the tested chemical solutionsincluding $KMnO_4$. Therefore, adoption of a dry ozone filter is necessary to reduce $O_3$ below a satisfactory level. For all the chemical solutions tested, NOx removal efficiency increased as NOx was mixed with $O_3$. As chemical solution was sprayed using water spraying system equipped with air atomizing type nozzle, the removal efficiencies of gaseous pollutants increased due to the increase of gas-liquid interfacial area.

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A Study on Low Emission Pulverized Coal Combustion in the 2 Staged Coaxial Cyclone Combustor (2단 동축형 Cyclone 연소기를 이용한 저공해 미분탄 연소특성 연구)

  • Choi, Sang-Il;Park, Chu-Sik;Kim, Sung-One;Kim, Ho-Young
    • Journal of the Korean Society of Combustion
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    • v.4 no.1
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    • pp.67-83
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    • 1999
  • The objective of this study is development of low emission pulverized coal combustor for reducing pollutant emission generated from coal combustion. Low emission combustion technology for reducing NOx and fly ash was investigated by using 2 stage coaxial cyclone combustor. Staged combustion was employed for NOx reduction and high temperature slagging combustion was also studied for fly ash removal in the combustor. The result of this study shows that the low emission combustion system can reduce the amount of atmospheric pollutions with improved boiler efficiency and performance.

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Development of the Inorganic Paint Using Clay-Titania Carrier and the Removal Property of Air Pollutant (점토와 광촉매를 이용한 무기도료의 개발과 대기정화성능에 관한 특성 연구)

  • Kim, Wha-Jung;Lee, Jun-Cheol;Chai, Han-Sik
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.11a
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    • pp.655-658
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    • 2005
  • In the domestic atmosphere environment, the VOCs and the NOx have a large proportion of the pollutant, and the HCHO is the main environmental pollutant factor within the house. In this study, the inorganic paint which can absorb and remove VOCs, NOx and HCHO is developed by using clay-titania carrier. The basic data to develope eco-friendly inorganic paint is collected with the performance test to remove the VOCs, NOx and HCHO in the condition of the addition of several inorganic materials to the paint, and also the plan to practical use of eco-friendly inorganic paint is studied.

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Commercialization of SCR System for Removal of NOx from Marine Diesel Exhaust Gas (선박 디젤엔진용 NOx 배출저감을 위한 SCR 시스템 상용화)

  • Yang, Hee-Sung;Seong, Hee-Je;Ko, Joon-Ho;Lee, Sung-Young;Park, Kee-Yong;Park, Jong-Kuk;Song, Seok-Yong
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2006.06a
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    • pp.23-24
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    • 2006
  • The International Maritime Organization announced that the regulation of nitrogen oxide put into force for vessels constructed after 2000 from May, 2005 as agenda is satisfied on May, 2004. A honeycomb-typed Pillared Inter-Layered Clay(PILC) catalyst was developed for do-NOx SCR system in 2004. This catalyst has been applied to 9H25/33 engine that is one of the main diesel engines in Engine Machinery Division of the Hyundai Heavy Industries CO., LTD. In addition, we have tried to develop better catalysts in the aspects of easy synthetic method and performance.

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Characteristics of Nutrient Removal with Variation of the Anoxic-Oxic Phase Repetition in Sequencing Batch Reactor Process (SBR공정의 무산소-호기 구간반복에 따른 영양염류 제거 특성)

  • Lee, Jaekune;Yim, Soobin
    • Journal of the Korean GEO-environmental Society
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    • v.10 no.1
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    • pp.43-48
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    • 2009
  • This study was performed to investigate the characteristics of nutrient removal by Sequencing Batch Reactor (SBR) system, which could achieve high removal efficiencies of nitrogen and phosphorus and make it possible convenient management and operation. In this study, dissolved oxygen (DO), chemical oxygen demand (COD), nitrogen, and phosphorus in SBR system were examined by variation of anoxic-oxic phase repetition in order to optimize an operational method. The 1~4 times of anoxic-oxic phases (Run 1~4) were repeated during 1 cycle operation period. As the repetition frequency increased, it was more difficult to maintain DO condition enough for denitrification. The SBR system showed high COD removal efficiency more than 91% regardless of operational condition. About 68% of nitrogen removal rate was obtained in conditions of 2 or 3 times repetition of anoxic phases, in which NOx-N among discharged total nitrogen account for more than 99%. Approximately 40% of phosphorus was eliminated in the conditions of 1~3 times of anoxic phase repetition.

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