• Journal of the Korean Society of Combustion
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• v.19 no.3
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• pp.26-33
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• 2014

We examined the characteristics of $NO_x$ emission for CH4/air non-premixed flames using the exhaust gas recirculation(EGR) methods, which are the air-induced EGR(AI-EGR) and fuel-induced EGR(FI-EGR) methods. Our experimental results show that the $NO_x$ emission index($EI_{NOx}$) decreased with increasing EGR ratio. In the range needed to form a stable flame, the reduction rate of $EI_{NOx}$ for the FI-EGR method was approximately 29% when the EGR ratio was 20%, and the reduction rate for the AI-EGR method was approximately 28% with 25% of the EGR ratio. According to the flame structure based on numerical results, high temperature regions for the FI-EGR method were narrower and lower than those for the AI-EGR method at the same EGR ratio. Furthermore, based on the experimental results for swirl flames, the reduction rate of $EI_{NOx}$ for the FI-EGR method was approximately 49% with 15% of the EGR ratio, while the maximum reduction rate for AI-EGR method was approximately 45% with 25% of the EGR ratio. Consequently, we verified that the FI-EGR method was more effective than the AI-EGR method in reducing $NO_x$ emission for non-premixed flames with EGR. We expect that the results of this study will provide fundamental information relating to hybrid combustion systems, which can be used in the design of combustion systems in the future.

• Transactions of the Korean Society of Automotive Engineers
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• v.4 no.2
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• pp.11-22
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• 1996

It has been generally accepted that NOx formation increases as the maximum temperature or correspondingly the maximum pressure of a combustion system increases. Recently some exceptional experimental results have been reportes that under certain circumstance NOx formation could be reduced while the maximum pressure was increasing by varying the methods of combustion for the same kind of premixed gases. Until now that kind of results have been acquired only for the case of a dual opposed prechamber. But the mechanism has not been clearly understood yet. 3D computer simulation has been tried to clarify the mechanism. Flor this purpose KIVA-Ⅱ has been modified and applied to the model combustion chamber with which the same kind of experimental works have been done by the authors. A good agreement with the experimental results was achieved with the spatial and temporal resolution which is hard th be obtained by the experimental methods. And it was observed that for the dual opposed prechamber case the time for the NOx formation, which is non-equilibrium reaction, is shorter than any other case by an appropriate mixing process in the main combustion chamber. The shorter time reduceed heat loss through the combustion chamber walls and thereby obtaines the higher maximum pressure.

• Journal of Applied Reliability
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• v.18 no.1
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• pp.66-71
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• 2018

Purpose: Performance recovered from SCR through cleaning was studied, measuring differential pressure, NOx reduction efficiency, fuel consumption and engine power before and after cleaning. Ideal cleaning intervals are proposed based on SCR mileage and differential pressure. SCR endurance and reliability improvements through cleaning were studied through physicochemical testing of SCR durability at 43,000km 50,000km, and 110,000km respectively. Methods: Engine power, fuel consumption and exhaust gas were measured using engine full load tests and ND-13 MODE by installing the SCR before cleaned at total engine mileages of 400,000 km, 300,000km and 200,000km. The same tests were performed after cleaning the SCR catalytic converter. Endurance and reliability of the SCR cleaning was studied through the same test by SCR catalyst after each 43,000km 50,000km, 110,000km, durability test on SCR cleaning. Conclusion: We confirmed the low-performance of the SCR due to clogging is restored by SCR cleaning technology. The NOx reduction efficiency was restored to 82%, 86% and 88% from 69%, 72% and 79%. As well as the NOx reduction efficiency, it was confirmed that the engine power, fuel consumption and back pressure was restored to fresh SCR levels. As a result of the durability and reliability achieved through SCR cleaning, we confined the appearance and reduction efficiency through visual inspection and ND-13 MODE are similar to new SCR catalysts. Finally, it was judged that there was no change in performance even when driving the SCR without cleaning throughout the 100,000 km mileage warranty.

• Journal of Advanced Marine Engineering and Technology
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• v.30 no.1
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• pp.81-87
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• 2006

In marine air pollution control, SCR (Selective Catalytic Reduction) is reconized as the most effect method to control NOx, but on the other hand. seawater scrubber applying the basic characteristic that is naturally alkaline (pH typically around 8.1) is viewed as an economical SOx removal system at present. Especially, seawater scrubber would not be necessary to follow any of the various land based flue gas desulfurization methods. i.e. wet, dry or alkali scrubbing. However, these methods are not readily adaptable to marine conditions due to the quantifies of consumables required i.e. lime or limestone, the means of operation and the commercial availability. This research is undertaken to develop a new method as the main target of eliminating all exhaust emissions, particularly vessel, because of easy access to seawater and apt to apply a wet scrubber system. First, using the acidic seawater by seawater electrolysis, nitric monoxide(NO) is adequately oxidized to nitric dioxide $(NO_2)$by ClOx-in the acidic seawater, the electrolyzed alkaline seawater by electrolysis which contains mainly NaOH together with alkali metal ions $(i.e\;Na^{+}\;K^{+},\;Mg_{2}\;^{+},\;Ca_{2}\;^{+})$, is used as the absorption medium of NOx, the SOx are absorbed by relatively high solubility compared to other components of exhaust pollutants. The results found that the NOx and SOx removals could be achieved nearly Perfect.

• Journal of ILASS-Korea
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• v.21 no.2
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• pp.71-77
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• 2016

Air pollutants nitrogen oxides are inevitably generated in the combustion reaction. Its amount trend is steadily increasing because the rapid modern industrialization and population growth. For this reason, NOx is controlled to reducing the harmful components in the exhaust gas. So Marine Environment Protection Committee (MEPC) take effect 'Tier I', 'Tier II' of air pollution regulation in 2005 and 2011 respectively. According to NOx emissions are strictly regulated management of the vessel through them. In addition, since 2016 the regulation enter into force in the next step 'Tier III' was confirmed by MEPC 66th committee. It's 80% enhanced emissions limits than the 'Tier I' Alternatively these emission regulation, research is actively being carried out about exhaust gas after-treatment methods through the vessel application of Selective Catalytic Reduction(SCR). Therefore depending on the basic specification of cell density according to the Area velocity, Space velocity, Linear velocity is studied the effects of NOx removal efficiency

• Journal of Advanced Marine Engineering and Technology
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• v.31 no.1
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• pp.44-50
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• 2007

Diesel engines have high thermal efficiency, and they have less CO & HC emissions than another engines. while NOx & Soot emissions are very much. compared with exhaust emission standards. However, the limit level is more and more strengthened yearly due to the importance of environmental protection. So, the optimal countermeasures for the reduction of NOx & Soot emissions below limit level are required. Therefore. the author has investigated the effects of emulsified fuel on the characteristics of exhaust emissions. using an four-cycle, four-cylinder and direct injection diesel engine because the using of emulsified fuel among various methods for reducing NOx & Soot emissions is simple in installation low in cost and high in efficiency. The results of investigation according to various operating conditions are as follows : 1) Specific fuel consumption increase maximum 19.8% at low load. but is not affected at full load. 2) In case of emulsion ratio 25%, NOx emission decrease 32% at 75% load. 30% at full load. 3) In case of emulsion ratio 25%, Soot emission decrease 84% at 75% load, 59% at full load.

• Journal of Korea Society of Waste Management
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• v.35 no.7
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• pp.647-652
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• 2018

The emission of nitrogen oxides has a great environmental impact. It leads to Los Angeles type smog, and it recently has attracted attention as a source of ultrafine dust. The main sources of nitrogen oxides are internal combustion engines and industrial boilers. These emission sources are processes that are essential for human industrial activities, so the regulation of original use is impossible. Therefore, special control methods should be applied to reduce NOx emissions into the atmosphere. In this study, we investigated how the supply of ER and urea influences the removal of nitrogen oxides from SRF combustion boilers. Experimental results show that the removal efficiency of nitrogen oxides can be up to 80% under the conditions of ER 2.0 and a urea feed of 0.5 LPM.

• Journal of Environmental Science International
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• v.20 no.11
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• pp.1465-1481
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• 2011

The accuracy of ozone sensitivity coefficients estimated with HDDM (High-order Decoupled Direct Method) can vary depending on the $NO_x$ (Nitrogen Oxides) and VOC (Volatile Organic Compound) conditions. In order to evaluate the applicability of HDDM over the Seoul Metropolitan Area (SMA) during a high ozone episode in 2007 June, we compare BFM (Brute Force Method) and HDDM in terms of the $1^{st}$-order ozone sensitivity coefficient to explain ozone change in response to changes in NOx and VOC emissions, and the $2^{nd}$-order ozone sensitivity coefficient to represent nonlinear response of ozone to the emission changes. BFM and HDDM estimate comparable ozone sensitivity coefficients, exhibiting similar spatial and temporal variations over the SMAduring the episode. NME (Normalized Mean Error) between BFM and HDDM for the episode average $1^{st}$- and $2^{nd}$-order ozone sensitivity coefficients to NOx and VOC emissions are less than 3% and 9%, respectively. For the daily comparison, NME for the $1^{st}$- and $2^{nd}$-order ozone sensitivity coefficients are less than 4% ($R^2$ > 0.96) and 15% ($R^2$ > 0.90), respectively. Under the emission conditions used in this study, two methods show negative episode average $1^{st}$-order ozone sensitivity coefficient to $NO_x$ emissions over the core SMA. The $2^{nd}$-order ozone sensitivity coefficient to $NO_x$ emissions leads ozone to respond muchnonlinear to the reduction in $NO_x$ emissions over Seoul. Nonlinear ozone response to reduction in VOC emissions is mitigated due to the $2^{nd}$-order ozone sensitivity coefficient which is much smaller than the $1^{st}$-order ozone sensitivity coefficient to the emissions in the magnitude.

• Particle and aerosol research
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• v.15 no.1
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• pp.1-13
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• 2019

Current desulfurization and denitrification technologies have reached a considerable level in terms of reduction efficiency. However, when compared with the simultaneous reduction technology, the individual reduction technologies have issues such as economic disadvantages due to the difficulty to scale-up apparatus, secondary pollution from wastewater/waste during the treatment process, requirement of large facilities for post-treatment, and increased installation costs. Therefore, it is necessary to enable practical application of simultaneous SOx and NOx treatment technologies to remove two or more contaminants in one process. The present study analyzes a technology capable of maintaining simultaneous treatment of SOx and NOx even at low temperatures due to the electrochemically generated strong oxidation of the wet-pulse complex system. This system also reduces unreacted residual gas and secondary products through the wet scrubbing process. It addresses common problems of the existing fuel gas treatment methods such as SDR, SCR, and activated carbon adsorption (i.e., low treatment efficiency, expensive maintenance cost, large installation area, and energy loss). Experiments were performed with varying variables such as pulse voltage, reaction temperature, chemicals and additives ratios, liquid/gas ratio, structure of the aeration cleaning nozzle, and gas inlet concentration. The performance of individual and complex processes using the wet-pulse discharge reaction were analyzed and compared.

• Transactions of the Korean Society of Automotive Engineers
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• v.22 no.4
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• pp.121-130
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• 2014

This paper is the second investigation on the effects of intake flow control methods on the part load performance in a spark ignition engine. In the previous work, two control methods, port throttling and masking, were compared with respect to lean misfire limit, fuel consumption and emissions. In this work, the effects of these two methods on EGR characteristics were studied and simultaneously the differences between EGR and lean combustion as a dilution method were investigated. The results show that EGR limit is expanded up to 23% and 3 ~ 5% improvement in the fuel consumption are achieved around 8 ~ 13% rates by the flow controls comparing with 10% limit and 1.5% reduction around 3% rate of non-control case. The masking method is more effective on the limit expansion than throttling as like as lean misfire limit; however there is no substantial difference in fuel consumptions improvement regardless the control methods except high load condition. Also it is observed that there exist critical EGR rates around which the combustion performance and NOx formation change remarkably and these rates generally coincide with optimum rates for the fuel consumption. In addition, dilution with fresh air is much more advantageous than that of the exhaust gas from the view point of dilution limit and fuel consumption, while utilization of the exhaust gas is more effective on NOx reduction in spite of considerably small dilution compared with the use of fresh air. Finally, the improvement of fuel consumption by massive EGR is highly dependent on the EGR limit at which the engine runs stably, therefore the stratified combustion technique might be a best solution for this purpose.