• Title/Summary/Keyword: NOx(Nitrogen oxides)

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NOx Reduction by Acoustic Excitation on Coaxial Air Stream in Lifted Turbulent Hydrogen Non-Premixed Flame (부상된 수소난류확산화염에서 동축공기의 음향가진에 의한 NOx 저감)

  • Heo, Pil-Won;Oh, Jeong-Seog;Yoon, Young-Bin
    • Journal of the Korean Society of Combustion
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    • v.14 no.1
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    • pp.31-38
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    • 2009
  • The effects of acoustic excitation of coaxial air on mixing enhancement and reduction of nitrogen oxides (NOx) emission were investigated. A compression driver was attached to the coaxial air supply tube to impose excitation. Measurements of NOx emission with frequency sweeping were performed to observe the trend of NOx emission according to the fuel and air flow conditions and to inquire about the effective excitation frequency for reducing NOx. Then, Schlieren photographs were taken to visualize the flow field and to study the effect of excitation. In addition, phase-locked particle image velocimetry (PIV) was performed to acquire velocity field for each case and to investigate the effect of vortices more clearly. Direct photographs and OH chemiluminescence photographs were taken to study the variation of flame length and reaction zone. It was found that acoustic forcing frequencies close to the resonance frequencies of coaxial air supply tube could reduce NOx emission. This NOx reduction was influenced by mixing enhancement due to large-scale vortices formed by fluctuation of coaxial air jet velocity.

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Analysis of NO Formation in Nonpremixed Hydrogen-Air Flames Considering Turbulence-Chemistry Interaction (난류연소 모델링을 이용한 수소-공기 비예혼합 화염의 NOx 생성 분석)

  • Park, Y.H.;Moon, H.J.;Kim, S.Y.;Yoon, Y.;Jeong, I.S.
    • 한국연소학회:학술대회논문집
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    • 1999.10a
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    • pp.71-79
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    • 1999
  • Numerical analysis on the characteristics of nitrogen oxides (NOx) formation in turbulent nonpremixed hydrogen-air flames was carried out. Lagrange IEM model and Assumed PDF model were applied to consider turbulence-chemistry interaction known to affect the production of NOx. Partial equilibrium assumption was used to predict nonequilibrium effect to which one-half power dependence between EINOx normalized by flame residence time and global strain rate is attributed. As a result. such one-half power dependence could be reproduced only by reaction model including $HO_{2}$and $H_{2}O_{2}$, which means its dependence on Damkohler number; nonequilibrium effect. This dependence was shown better in the region of higher global strain. Besides, the improvement of turbulence model is required to predict mean flow properties quantitatively in the radial direction.

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Fabrication and Performances of Amperometric Gas Sensors (전류검출형 가스센서의 구성 및 성능평가에 관한 연구)

  • 김귀열;박용필;이준웅;서장수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.1073-1075
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    • 2001
  • The nitrogen oxides, NO and NO2, abbreviated usually as NOx, emitted from combustion facilities such as power plants and automobiles are the typical air-pollutants causing acid rain and photochemical smog. In order to solve the NOx-related pollution problems effectively, we need efficient techniques to monitor NOx in the combustion exhausts and in environments. Development of solid-state electrochemical devices for detecting NOx is demonstrated based on various combination of solid electrolytes and auxiliary sensing materials. The object of this research is to develop various sensor performance for solid state amperometric sensor, and to test gas sensor performance manufactured. So we try to present a guidance for developing amperometric gas sensor. We concentrated on development of manufacturing process and performance test.

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Technology of Amperometric Gas Sensors (전류검출형 가스센서의 기술)

  • 김귀열
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07a
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    • pp.222-225
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    • 2002
  • The nitrogen oxides, NO and NO2, abbreviated usually as NOx, emitted from combustion facilities such as power plants and automobiles are the typical air-pollutants causing acid rain and photochemical smog. In order to solve the NOx-related pollution problems effectively, we need efficient techniques to monitor NOx in the combustion exhausts and in environments. Development of solid-state electrochemical devices for detecting NOx is demonstrated based on various combination of solid electrolytes and auxiliary sensing materials. The object of this research is to develop various sensor performance for solid state amperometric sensor, and to test gas sensor performance manufactured. So we try to present a guidance for developing amperometric gas sensor.

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Numerical Investigation for Combustion Characteristics of Vacuum Residue in a Test Furnace

  • Sreedhara, S.;Huh, Kang-Y.;Park, Ho-Young
    • 한국연소학회:학술대회논문집
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    • 2006.04a
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    • pp.121-127
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    • 2006
  • It has become inevitable to search for alternative fuels due to severe energy crisis these days. Use of alternative fuels, which are typically of lower quality, tends to increase environmental pollution, including formation of nitrogen oxides (NOx). In this paper performance of vacuum residue has been investigated experimentally as well as numerically in typical operating conditions of a furnace. Heat release reaction is modeled as sequential steps of devolatilization, simplified gas phase reaction and char oxidation as that for pulverized coal. Thermal and fuel NOx are predicted by conditional estimation of elementary reaction rates and are compared against measured experimental data. On the overall reasonable agreement is achieved for spatial distributions of major species, temperature and NOx for all test cases.

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Amperometric Gas Sensors Research of Solid Electrode (고채전해질을 사용한 전류검출형 가스센서 연구)

  • 서장수;김귀열;백승철;김용주
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.924-926
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    • 2000
  • The nitrogen oxides, NO and NO2, abbreviated usually as NOx, emitted from combustion facilities such as power plants and automobiles are the topical air-pollutants causing acid rain and photochemical smog. In order to solve the NOx-related pollution problems effectively, we need efficient techniques to monitor NOx in the combustion exhausts and in environments. Development of solid-state electrochemical devices for detecting NOx is demonstrated based on various combination of solid electrolytes and auxiliary sensing materials. The object of this research is to develop various sensor performance for solid state amperometric sensor, and to test gas sensor performance manufactured. So we try to present a guidance for developing amperometric gas sensor. We concentrated on development of manufacturing process and performance test.

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Effects of Combustor Stages on M501J Gas Turbine Combustion (M501J 가스터빈 연소기 단별 연료비율이 연소상태에 미치는 영향 고찰)

  • Yu, Won-Ju;Chung, Jin-Do
    • Journal of the Korea Safety Management & Science
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    • v.21 no.2
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    • pp.1-8
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    • 2019
  • Most of gas turbine combined cycle power plants are located in urban areas to provide peak load and district heating. However, NOx(nitrogen oxides) of exhaust gas emission from the power plants cause additional fine dust and thus it has negative impact on the urban environment. Although DLN(dry low NOx) and multi-stage combustors have been widely applied to solve this problem, they have another critical problem of damages to combustors and turbine components due to combustion dynamic pressure. In this study, the effect of different fuel ratio on NOx emission and pressure fluctuation was investigated regarding two variable conditions; combustor stages and power output on M501J gas turbine.

Combustion Performance Test of Syngas Gas in a Model Gas Turbine Combustor - Part 2 : NOx/CO emission Characteristics, Temperature Characteristics and Flame Structures (모델 가스터빈 연소기에서 합성가스 연소성능시험 - Part 2 : NOx/CO 배출특성, 온도특성, 화염구조)

  • Lee, Min Chul;Yoon, Jisu;Joo, Seong Pil;Yoon, Youngbin
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.41 no.8
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    • pp.639-648
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    • 2013
  • This paper describes on the NOx/CO emission characteristics, temperature characteristics and flame structures when firing coal derived synthetic gas especially for gases of Buggenum and Taean IGCC. These combustion characteristics were observed by conducting ambient-pressure elevated-temperature combustion tests in GE7EA model combustor when varying heat input and nitrogen dilution ratio. Nitrogen addition caused decrement in adiabatic flame temperature, thus resulting in the NOx reduction. At low heat input condition, nitrogen dilution raised the CO emission dramatically due to incomplete combustion. These NOx reduction and CO arising phenomena were observed at certain flame temperature of $1500^{\circ}C$ and $1250^{\circ}C$, respectively. As increasing nitrogen dilution, adiabatic flame temperature and combustor liner temperature were decreased and singular points were detected due to change in flame structure such as flame lifting. From the results, the effect of nitrogen dilution on the NOx/CO and flame structure was examined, and the test data will be utilized as a reference to achieve optimal operating condition of the Taean IGCC demonstration plant.

A Study on the Estimation of Air Pollutants Emission Factors in Electric Power Plants (화력발전소의 대기오염물질 배출계수 산정 연구)

  • 김대곤;엄윤성;홍지형;이석조;석광설;이대균;이은정;방선애
    • Journal of Korean Society for Atmospheric Environment
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    • v.20 no.3
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    • pp.281-290
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    • 2004
  • The main purpose of this study was to characterize the air pollutants emission factors in electric power plant (EPP) using fossil fuels. The electric power plant is a major air pollution source, thus knowing the emission characteristics of electric power plant is very important to develop a control strategy. The major air pollutants of concern from EPP slacks are particulate matter (PM), sulfur oxides (SOx), nitrogen oxides (NOx), carbon monoxide (CO) and heavy metals. Throughout the study, the following results are estimated - PM : 8.671E-05 ∼ 8.724E+01 PM emission (kg) per fuel burned (ton) - SOx : 4.149E-04∼7.877E+01 SOx emission (kg) per fuel burned (ton) - NOx 1.578E-02∼9.857E+00 NOx emission (kg) per fuel burned (ton) - CO : 3.800E-04∼1.291E+00 CO emission (kg) per fuel burned (ton) - Hg : 1.220E+01∼3.108E+02 Hg emission (mg) per fuel burned(ton) From the statistical analysis by Wilcoxon signed ranks test between the emission factors of ours and U.S. EPA's, we can yielded that : p 〉0.05.

Emission Characteristics and Coefficients of Air Pollutants in Iron and Steel Manufacturing Facilities (제철제강시설의 대기오염물질 배출특성 및 배출계수 산정)

  • Kim, Byoung-Ug;Hong, Young-Kyun;Lee, Yeong-Seob;Yang, Seung-Pyo;Hyun, Geun-Woo;Yi, Geon-Ho
    • Journal of Environmental Health Sciences
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    • v.47 no.3
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    • pp.259-266
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    • 2021
  • Objectives: This study was conducted to identify the emissions characteristics of total particulate matter (TPM), fine dust (PM10, PM2.5), and gaseous pollutants (SOx, NOx) in iron and steel manufacturing facilities in order to investigate emissions factors suitable for domestic conditions. Methods: Total particulate matter (TPM), fine dust (PM10, PM2.5), and gas phase materials were investigated at the outlet of electric arc furnace facilities using a cyclone sampling machine and a gas analyzer. Results: The concentrations of TPM ranged from 1.64 to 3.14 mg/Sm3 and the average was 2.47 mg/Sm3. Particulate matter 10 (PM10) averaged 1.49 mg/Sm3 with a range of 0.92 to 1.99 mg/Sm3, and the resulting ratio of PM10 to TPM was around 60 percent. PM2.5/PM10 ranged from 33.7 to 47.9% and averaged 41.6%. Sulfur oxides (SOx) were not detected, and nitrogen oxides (NOx) averaged 6.8 ppm in the range of 5.50 to 8.67 ppm. TPM emission coefficients per product output were in the range of 0.60 to 1.26 g/kg, 0.13 to 0.79 g/kg for PM10 and 0.12 to 0.36 g/kg for PM2.5, and showed many differences from the emissions coefficients previously announced. An emissions coefficient for NOx is not currently included in the domestic notices, but the results were calculated to be 0.42 g/kg per product output. Conclusions: Investigation and research on emissions coefficients that can reflect the characteristics of various facilities in Korea should be conducted continuously, and the determination and application of unique emissions coefficients that are more suitable for domestic conditions are needed.