• 제목/요약/키워드: NO conversion

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Ag/γ-Al2O3 촉매상에서 탄화수소-SCR(Selective Catalytic Reduction) 연구 (A study of hydrocarbon SCR(selective catalytic reduction) on Ag/γ-Al2O3 catalyst)

  • 김문찬;이철규
    • 분석과학
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    • 제18권2호
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    • pp.139-146
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    • 2005
  • 본 연구에서는 자동차의 배출가스중에 포함된 NO를 비선택적 촉매환원법으로 환원시켜 제거하기 위하여 Ag의 함량을 여러 가지로 달리하여 ${\gamma}-Al_2O_3$에 담지한 촉매를 제조하였고, 제조한 촉매에 대하여 온도, 산소농도, 아황산가스농도의 변화에 따른 $NO_x$의 전환율에 대하여 연구하였다. 또한 제조한 촉매의 물성분석을 통하여 촉매의 상태와 $NO_x$의 전환율과의 관계를 알아보았다. 제조한 각각의 촉매에 대하여 반응조건을 여러 가지로 달리하여 반응실험을 한 결과 $Ag/{\gamma}-Al_2O_3$ 촉매는 Ag의 함량이 2 wt%일 때, 그리고 반응온도가 약 $450^{\circ}C$일 때 가장 높은 $NO_x$ 전환율을 나타냈다. 반응실험 전 후의 촉매에 대하여 X-ray Diffraction (XRD), X-ray Photoelectron Spectroscopy (XPS), Temperature Programmed Reduction (TPR), Ultraviolet-Visible Diffuse Reflectance Spectroscopy (UV-Vis DRS)등의 분석 결과와 반응실험 결과를 비교하여 볼 때 Ag의 산화상태가 잘 유지되지 못하여 고온에서는 $NO_x$ 전환율이 낮아지는 것으로 나타났다.

Ku-Band Sub-Harmonically Pumped Single Balanced Resistive Mixers with a Low Pass Filter Using Photonic Band Gap

  • Kim, Jae-Hyuk;Park, Hyun-Joo;Lee, Jong-Chul;Kim, Nam-Young
    • 한국전자파학회논문지
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    • 제11권4호
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    • pp.599-609
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    • 2000
  • In this paper, sub-harmonically pumped single balanced resistive mixers are presented . Frequency bandwidth is selected for a Ku-band, which is 11.75-12.25GHz for RF, 5.375∼5.625 GHz for LO, and 1 GHz for IF signals. A rat-race hybrid is designed for the accomplishment of single balanced type. A low pass filter (LPF) with photonic band gap(PBG) structure is used for good conversion loss and unwanted harmonics suppression. Two types of mixers are suggested, which are one with no gate bias for no DC power consumption and the other with the IF amplifier for conversion gain. When a LO signal with the power of 6 dBm at 5.5 GHz is injected, a conversion loss of 12.17dB and a conversion gain of 7.83 dB are obtained for each mixer. For the both mixers , LO to RF isolation of 20 dB and LO to IF isolation of 60dB are obtained. With the RF power of -30dBm to -3dBm, the mixer shows linear characteristics region of IF. this mixer can be applied for Ku-band and other microwave communication systems.

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초기에 전환장애로 잘못 진단되었던 위증환자 보고 1례 (A case study of Wei symptom initially misdiagnosed as conversion disorder)

  • 김윤용;변순임;김지영;황의완;조성훈
    • 동의신경정신과학회지
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    • 제18권3호
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    • pp.147-156
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    • 2007
  • Conversion disorder is a diagnosis based on a psychological construct that currently has no known neurobiologic substrate. But It is not easy to differentiate a real conversion disorder from a neurological disease or other medical disease. A patient in this case report had been diagnosed as conversion disorder but later it was found that the conversion disorder was misdiagnosis. During the 7 days of treatment, this patient was treated by herb medication, acupuncture and TENS and bad a little improvement. Both way, this patient was evaluated and evantually was diagnosed as Guillain-Barre Syndrome Miller-Fisber Variant, suggesting that the former diagnosis bad been a mistake. In this case report, we will present this patient's case and review the misdiagnosis of conversion disorder.

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High-Power-Density Power Conversion Systems for HVDC-Connected Offshore Wind Farms

  • Parastar, Amir;Seok, Jul-Ki
    • Journal of Power Electronics
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    • 제13권5호
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    • pp.737-745
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    • 2013
  • Offshore wind farms are rapidly growing owing to their comparatively more stable wind conditions than onshore and land-based wind farms. The power capacity of offshore wind turbines has been increased to 5MW in order to capture a larger amount of wind energy, which results in an increase of each component's size. Furthermore, the weight of the marine turbine components installed in the nacelle directly influences the total mechanical design, as well as the operation and maintenance (O&M) costs. A reduction in the weight of the nacelle allows for cost-effective tower and foundation structures. On the other hand, longer transmission distances from an offshore wind turbine to the load leads to higher energy losses. In this regard, DC transmission is more useful than AC transmission in terms of efficiency because no reactive power is generated/consumed by DC transmission cables. This paper describes some of the challenges and difficulties faced in designing high-power-density power conversion systems (HPDPCSs) for offshore wind turbines. A new approach for high gain/high voltage systems is introduced using transformerless power conversion technologies. Finally, the proposed converter is evaluated in terms of step-up conversion ratio, device number, modulation, and costs.

DeSOx/DeNOx 효율 개선을 위한 펄스 코로나 방전하에서 기체미립자 전환반응의 적용 (Application of Gas to Particle Conversion Reaction to increase the DeSOx/DeNOx Efficiency under Pulsed Corona Discharge)

  • 최유리;김동주;김교선
    • 산업기술연구
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    • 제18권
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    • pp.249-258
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    • 1998
  • In this paper, we investigated the post-combustion removal of nitrogen oxide($NO_x$) and sulfur oxide($SO_x$) which is based on the gas to particle conversion process by the pulsed corona discharge. Under normal pressure, the pulsed corona discharge produces the energetic free electrons which dissociate gas molecules to form the active radicals. These radicals cause the chemical reactions that convert $SO_x$ and $NO_x$ into acid mists and these mists react with $NH_3$ to form solid particles. Those particles can be removed from the gas stream by conventional devices such as electrostatic precipitator or bag filter. The reactor geometry was coaxial with an inner wire discharge electrode and an outer ground electrode wrapped on a glass tube. The simulated flue gas with $SO_x$ and $NO_x$ was used in the experiment. The corona discharge reactor was more efficient in removing $SO_x$ and $NO_x$ by adding $NH_3$ and $H_2O$ in the gas stream. We also measured the removal efficiency of $SO_x$ and $NO_x$ in a cylinder type corona discharge reactor and obtained more than 90 % of removal efficiency in these experimental conditions. The effects of process variables such as the inlet concentrations of $SO_x$, $NH_3$ and $H_2O$, residence time, pulse frequencies and applied voltages were investigated.

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Performance Prediction of Centrifugal Compressor Based on Performance Test, Similarity Conversion and CFD Simulation

  • Zhu, Changyun;Qin, Guoliang
    • International Journal of Fluid Machinery and Systems
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    • 제5권1호
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    • pp.38-48
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    • 2012
  • One centrifugal compressor is applied for refrigeration and its working substance is R134a. The operating points obtained by using similar conversion at different rotation speeds are compared with the numerical results. They keep consistent with each other while the rotation speeds are lower, but the error between them will become large with the increasing of the rotation speed. Then the operating points are obtained when the working substance is air by using two similar conversion methods separately. Based on the comparison, it can be obtained that the result of keeping the specific volume ratio of inlet and outlet is more accurate than the result of maintaining Ma number. Then the test result is compared with the similarity result and the numerical result when the working substance is air. It is obtained that the similarity result is more consistent with the test result better than the numerical result and the trend of efficiency and pressure ratio change with the flow rate is consistent with the test result. In the process of similar conversion, the efficiency ${\eta}$ is no useful for similitude design and it has less influence on the conversion result.

변환효율 향상을 위한 횡방향 가변 셀밀도법을 사용한 자동차용 촉매변환기의 수치적 설계 (Numerical Design of Auto-Catalyst Substrate for Improved Conversion Performance Using Radially Variable Cell Density)

  • 정수진;김우승
    • 대한기계학회논문집B
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    • 제24권12호
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    • pp.1596-1607
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    • 2000
  • The optimal design of auto-catalyst needs a good compromise between the pressure drop and flow uniformity in the substrate. One of the effective methods to achieve this goal is to use the concept of radially variable cell density. But this method has not been examined its usefulness in terms of chemical behavior and conversion performance. In this work, two-dimensional performance prediction of catalyst coupled with turbulent reacting flow simulation has been used to evaluated the benefits of this method n the flow uniformity and conversion efficiency. The results showed that two cell combination of 93cpsc and 62 cpsc was the most effective for improved pressure drop and conversion efficiency due to balanced space velocity and efficient usage of geometric surface area of channels. It was also found that large temperature difference between the bricks in case that the edge of the frontal face of brick has too much lower cell density(less than 67% of cell density of the center of the brick). This study has also demonstrated that the present computational results show the better prediction accuracy in terms of CO, HC and NO conversion efficiencies compared to those of conventional 1-D adiabatic model by comparison with experimental results.

디메틸에테르(DME) 자열개질 운전조건 최적화에 관한 연구 (Experiments of dimethyl ether autothermal reforming optimization)

  • 최승현;배중면;김태훈;장덕진;김도연
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2011년도 추계학술대회 초록집
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    • pp.97.1-97.1
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    • 2011
  • Dimethyl ether (DME) is an attractive fuel as a hydrogen carrier for mobile PEMFC applications. However, its reforming technologies are rarely studied especially by using autothermal reforming (ATR) method. This work explored the impact of operating conditions to the performance of DME ATR. Temperature, Steam to carbon ratio(SCR), Oxygen to carbon ratio(OCR) and Gas hourly space velocity(GHSV) were considered as the operating conditions. As results, conversion efficiency was increased as the temperature increased, but saturated around $700^{\circ}C$. There was no significant effect of SCR on conversion efficiency, but high SCR led reactions in endothermic manner. High OCR substantially suppressed conversion efficiency, but it helped to sustain the temperature by stimulating exothermic reactions. Conversion efficiency was decreased as GHSV increased. The optimized operating conditions was suggested: $700^{\circ}C$, SCR of 1.5, OCR of 0.45 and GHSV below 15000/h and conversion efficiency was ~85% at the conditions.

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The effect of thickness and translucency of polymer-infiltrated ceramic-network material on degree of conversion of resin cements

  • Barutcigil, Kubilay;Buyukkaplan, Ulviye Sebnem
    • The Journal of Advanced Prosthodontics
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    • 제12권2호
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    • pp.61-66
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    • 2020
  • PURPOSE. The aim of the present study was to determine the degree of conversion of light- and dual-cured resin cements used in the cementation of all-ceramic restorations under different thicknesses of translucent (T) and high-translucent (HT) polymer-infiltrated ceramic-network (PICN) material. MATERIALS AND METHODS. T and HT PICN blocks were prepared at 0.5, 1.0, 1.5, and 2.0 mm thicknesses (n=80). Resin cement samples were prepared with a diameter of 6 mm and a thickness of 100 ㎛. Light-cured resin cement was polymerized for 30 seconds, and dual-cure resin cement was polymerized for 20 seconds (n=180). Fourier transform infrared spectroscopy (FTIR) was used for degree of conversion measurements. The obtained data were analyzed with ANOVA and Tukey HSD, and independent t-test. RESULTS. As a result of FTIR analysis, the degree of conversion of the light-cured resin cement prepared under 1.5- and 2.0-mm-thick T and HT ceramics was found to be lower than that of the control group. Regarding the degree of conversion of the dual-cured resin cement group, there was no significant difference from the control group. CONCLUSION. Within the limitation of present study, it can be concluded that using of dual cure resin cement can be suggested for cementation of PICN material, especially for thicknesses of 1.5 mm and above.

조사광이 통과하는 치질의 두께와 광조사시간에 따른 광중합형 복합레진의 중합률에 관한 연구 (A STUDY ON THE DEGREE OF CONVERSION OF LIGHT CURING COMPOSITE RESIN ACCORDING TO THE THICKNESS OF TOOTH STRUCTURE PENETRATED BY LIGHT AND APPLIED LIGHT CURING TIME)

  • 황기환;장인호;이세준;이광원
    • Restorative Dentistry and Endodontics
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    • 제27권1호
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    • pp.16-23
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    • 2002
  • Physical properties of composite resins such as strength, resistance to wear, discoloration, etc depend on the degree of conversion of the resin components. The purpose of this study was to evaluate the degree of conversion of the composite resins according to the thickness of tooth structure penetrated by light and applied light curing time. The coronal portions of extracted human teeth (one anterior tooth, three posterior tooth) was embedded by pink denture material. the mounted teeth were cut into three illumination sections (1mm thickness enamel section, 1mm thickness dentin section, 2mm thicknes dentin section) and one backing section with cutting wheel. Thin resin films were made by using 6kg pressure between slide glass during 5 minutes Thin resin film was light cured on coupled illumination section during 40sec, 80sec and 120sec. each illumination section was coupled as follows; no tooth structure(X), ename section(E), enamel section + 1mm dentin section(ED1), enamel section + 2mm dentin section(ED2), enamel section + 1mm dentin section + 2mm dentin section(EDD). To simulate the clinical situation more closely, thin resin films was cured against a backing section of tooth structure. The degree of conversion of carbon double bonds to single bonds in the resin films were examined by means of Fourier Transform Infrared Spectrometer. The results were obtained as follows ; 1 As curing time was increased, conversion rate was increased and as tooth thickness which was penetrated by curing light was increased, conversion rate was decreased. 2. At all tooth thickness groups, conversion rate between 80sec and 120sec was not significantly increased(P>0.05). 3. At 40sec group and 80sec, conversion rate between no tooth structure(X) group and 1mm enamel section(E) group was not significantly decreased(P>0.05). 4. At 80sec group and 120sec, conversion rate between 1mm enamel section(E) group and 1mm enamel section + 1mm dentin section(ED1) group was not significantly decreased(P>0.05).