• Title/Summary/Keyword: NO conversion

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Strength and conversion characteristics of DeNOx catalysts with the addition of dispersion agent (분산제 첨가에 따른 탈질촉매의 강도세기 및 전환특성)

  • Lee, Hyun Hee;Park, Kwang Hee;Cha, Wang Seog
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.12
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    • pp.6575-6580
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    • 2013
  • Various modified SCR catalysts were prepared and tested to improve the strength of catalysts for use under severe conditions. The SCR catalysts were modified with a binder and dispersion agent, and tested at the fixed bed reactor. FT-IR and $H_2$-TPR were used to analyze the degree of hydrogen use and ammonia adsorption by the modified catalysts. In the case of the SCR catalysts coated with 2.3g of the binder, 4.7g of ethanol, and 0.1g of dispersion agent, the strength of catalyst was increased by approximately 12%. On the other hand, despite the enhancement of strength, the activities of the SCR catalysts were decreased by 2-10%. When the mixed solution composed of binder, dispersion agent and $SiO_2$ solution was precipitated on the catalyst, the $NO_x$ conversion of the catalyst was decreased slightly. The Bronsted acid site and Lewis acid site worked as the activators for the SCR reaction, and were decreased by $SiO_2$.

The Effect of $MnO_2$ Addition on the $V_2O_5/TiO_2$ Catalytic Filters for NO Reduction (NO 환원반응을 위한 $V_2O_5/TiO_2$계 촉매필터의 $MnO_2$ 조촉매 효과)

  • Shin, Hae-Joong;Choi, Jae-Ho;Song, Young-Hwan;Lee, Ju-Young;Jang, Sung-Cheol;Choi, Joo-Hong
    • Proceedings of the SAREK Conference
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    • 2008.11a
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    • pp.363-368
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    • 2008
  • Nitrogen oxides (NO, $NO_2$ and $N_2O$) have been controlled effectively by the SCR catalysts coated on monolith or honeycomb in commercial sites with ammonia as reductant at high temperature range $300{\sim}400^{\circ}C$. However, the catalytic filter has much merit on the point of controlling the particles and nitrogen oxides simultaneously. It will be more advanced-system if the catalytic working temperature is reduced to the normal filtration temperature of under $200^{\circ}C$. This study has focus on the development of the catalytic filter working at the low temperature. So the additive effect of the components such as Pt and Mn (which are known the catalytic component of $V_2O_5/TiO_2$ was investigated. The $V_2O_5-WO_3$ catalytic filter exhibited high activity and selectivity at $250{\sim}320^{\circ}C$ showing more than 95% NO conversion for the treatment of 600 ppm NO at face velocity 2 cm/s. The Pt-$V_2O_5-WO_3$ catalytic filter shifted the optimum working temperature towards the lower temperature ($170{\sim}200^{\circ}C$). And NO conversion was 100% and higher than that of $V_2O_5-WO_3$ catalyst at $250{\sim}320^{\circ}C$. The $MnO_X-V_2O_5-WO_3$ catalytic filter showed the wide temperature range of $220{\sim}330^{\circ}C$ for more than 95% NO conversion. This is a remarkable advantage when considered the $MnO_X$ catalytic filter presents the maximum activity at $150{\sim}250^{\circ}C$ and $V_2O_5-WO_3$ catalytic filter shows the maximum activity at $250{\sim}320^{\circ}C$.

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Efficacy of Lactic Acid Bacteria Isolated from Kimchi for Swine Feed Additives (양돈사료 첨가용 김치 유산균의 효능)

  • Cho, Mee-Sun;Han, Sun-Kyung;Ryu, Ji-Sook;Choi, Ji-Hyun;Koo, Bon-Chul;Shin, Myeong-Su;Ahn, Jong-Seog;Lee, Wan-Kyu
    • Journal of Veterinary Clinics
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    • v.25 no.2
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    • pp.67-72
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    • 2008
  • The aim of this study was to investigate the efficacy of Lactobacillus spp. W44 and J124 strain isolated from Kimchi on the growth rate, average daily gain (ADG), feed conversion and change of intestine microflora in the weaning piglets. In the experiment 1, growth rate was significantly increased to $28.5\;{\pm}\;4.3\;kg$ and $27.6\;{\pm}\;3.3\;kg$ after oral administration of W44 and J124 strain as feed additives, respectively (p<0.05). ADG and feed conversion were also significantly improved after administration during 44 experiment days (p<0.05). In the analysis of intestinal microflora, the number of Lactobacillus spp. in the experiment groups was significantly increased 100 to 1,000 times compared to those of control group. In the experiment 2, the efficacy of W44 and J124 strains on the growth rate, ADG, feed conversion and change of intestine microflora were reconfirmed significantly (p<0.05). However, there were no significant differences on feed conversion in the W44 bead and J124 bead groups. In summary, our results suggest that W-44 and J-124 stains from Kimchi have a significant effect on the weight gain and feed conversion, and it may be useful probiotic strains for the weaning piglets as feed additives.

Reliability, Validity, and Conversion Index of the Workload Management System for Critical Care Nurses(WMSCN) (중환자 분류도구(WMSCN)의 신뢰도, 타당도 및 환산지수 검증)

  • Yoo, Cheong-Suk;Kwon, Eun-Ok;Kim, Soon-Hee;Cho, Yong-Ae
    • Journal of Korean Critical Care Nursing
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    • v.2 no.1
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    • pp.48-57
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    • 2009
  • Purpose: The purpose of this study is to establish reliability and validity and to identify the conversion index. Method: The WMSCN for ICU was revised from Workload Management System for Nurses(WMSN) of Walter Reed Army Hospital. Reliability of the WMSCN was evaluated interrater reliability between head nurses and staff nurses at 124 patients in April 2008. Validity through the correlation between direct nursing care hours and WMSCN score was conducted at 20 ICUs of 10 hospitals. Finally the conversion index was identified by total nursing hours and it divided by WMSCN score. Results: The scores by nurses were highly correlated with head nurses’(p=.967), and also scores of the WMSCN were highly correlated with the direct nursing care hours(p<.001). The distribution of patient classification ranks into class V(61.3%), class IV(24.2%) and class VI(11.3%). The scores of the WMSCN were no differences between MICU and SICU. Finally, the conversion index was 8.2 minutes. Conclusion: WMSCN is available to classify the nursing workload for critical care patients. The repeated evaluation of validity and reliability are requisite to use WMSCN effectively. And the conversion index should be adjusted to estimate the appropriate staffing in Korea.

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An Experimental Study on NOx Reduction in Exhaust Gas from Agricultural Diesel Engine with Plasma and Catalyst (플라즈마와 촉매를 이용한 농용 디젤기관 배기가스 중의 NOx 저감에 관한 실험적 연구)

  • 이승규;조기현;황의현
    • Journal of Biosystems Engineering
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    • v.24 no.6
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    • pp.465-472
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    • 1999
  • To remove nitrogen oxides(NOx) in exhaust gas of diesel engine, three-way catalytic process with plasma discharger has great possibilities. Characteristics of NOx removal depends on NO conversion to NO$_2$and/or HNO$_3$due to high activation energies for NO oxidation and reduction. NOx removal efficiency by using three-way catalytic with plasma discharger indicated about 50% at 40watt power consumption condition.

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Biological nitrogen removal of ammonium-rich industrial wastewater by suspended bacterial growth

  • Im, Jun-Taek;Seong, Se-Hyeon;Hwang, Seok-Hwan
    • 한국생물공학회:학술대회논문집
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    • 2002.04a
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    • pp.399-402
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    • 2002
  • Industrial wastewater with high ammonium concentration was treated in batch biological systems which was a modified Ludzack- Ettinger process. Up to 78% conversion of $NH_4\;^+-N$ to $NO_x\;^--N$ was achieved in batch culture condition. Under anoxic condition with methanol as the carbon source, the denitrifiers decreased $NO_x\;^--N$ concentration from 608 mg/L to 5.6 mg/L in 22 d. As well as anoxic denitrification of $NO_x\;^-$ to $N_2$, dissimilatory nitrate reduction to ammonium also occurred under the condition as respiratory denitrification.

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An Experimental Stduy on NOx Reduction in Exhaust Gas from Diesel Engine with Plasma (플라즈마를 이용한 디젤엔진 배기가스 중의 NOx 저감에 관한 실험적 연구)

  • 조기현;황의현
    • Transactions of the Korean Society of Automotive Engineers
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    • v.7 no.8
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    • pp.83-90
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    • 1999
  • To remove nitrogen oxides(NOx) in exhaust gas of diesel engine, three-way catalytic process with plasma discharger has great possbilities. Characteristics of NOx removal depends on NO conversion to $NO_2$ and/or $HNO_3$ due to high activation energies for NO oxidationand reduction. NOx removal efficiency by using three-way catalytic with plasma dischager indicated about 50% at 40 watt power consumption condition.

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A STUDY ON THE DEGREE OF CONVERSION OF LIGHT CURING COMPOSITE RESIN ACCORDING TO THE DEPTH OF CURE AND LIGHT CURING TIME (수종 광중합 복합 레진의 중합 깊이와 광조사 시간에 따른 중합률에 관한 연구)

  • Kim, Kyung-Hyun;Kwon, Oh-Sung;Kim, Hyun-Gee;Baek, Kyu-Chul;Um, Chung-Moon;Kwon, Hyuk-Choon
    • Restorative Dentistry and Endodontics
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    • v.22 no.1
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    • pp.35-60
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    • 1997
  • Physical properties of composite resins such as strength, resistance to wear, discoloration, etc, depend on the degree of conversion of the resin components. The clinical behavior of restorative resins varies brand to brand. Part of this variation is associated with the filler and differences in the polymer matrix. The polymer matrix of resins may differ because the involved monomers are dissimilar and because of variation in the catalyst system. The purpose of this study was to evaluate the degree of conversion of the composite resins according to the depth of cure and light curing time. 7mm diameter cylindrical aluminum molds were filled with each of five different hybrid light curing composite resins(Z-100, Charisma, Herculite XRV, Prisma TPH, Veridonfil) on the thin resin films. The molds were 1mm, 2mm, 3mm, 4mm, and 5mm in depth to produce resin films of various heights. Each sample was given 20sec, 40sec, and 60sec illumination with a light source. The degree of conversion of carbon double bonds to single bonds in the resin films was examined by means of Fourier Transform Infrared Spectrometer. The results were obtained as follows; 1. There was difference in the degree of conversion among five light curing composite resins according to the depth of cure for 20sec, 40sec, and 60sec illumination with light source with statistical significance(P<0.05). 2. Five light curing composite resins show lower degree of conversion at surface of the resin than depth of 1mm. 3. The degree of conversion of five light curing composite resins was siginificantly reduced from the maximum for the resin film when the light passed through as little as 1mm of each composite. 4. The degree of conversion of five light curing composite resins decrease significantly at the depth of 4mm, and polymerization was not occured at the depth of 5mm except for Prisma TPH. 5. The degree of conversion of five light curing composite resins was increased with increased light curing time, and there was no significant differences in the degree of conversion above 4mm in Z-100, 3mm in Charisma, and at depth of 5mm in Herculite XRV and Veridonfil(P>0.05).

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The Method of Evaluating The Potential for Conversion Legal Problems with Conversion And Basic Capacity of Vacant Onces in Tokyo

  • Sato, Kouichi;Matsumura, Shuichi;Namiki, Kenji
    • Proceeding of Spring/Autumn Annual Conference of KHA
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    • 2002.11a
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    • pp.301-306
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    • 2002
  • In Japan, the vacancy rates of office buildings have been at high in big cities since 1992. This problem is especially acute in Tokyo, where it is estimated that over 2.27 million square meters of office floor area will be oversupplied in 2003: big urban redevelopment projects will be completed in 2003. Under these circumstances, International Cooperative Research and Development on Sustainable Urban Management by Conversion of Buildings, called “SUMCOB”, has been carried out. This research aims to regenerate urban areas by converting redundant offices into flats, although instances of conversion are still very few in Japan. This paper introduces part of current results by SUMCOB, and discusses legal problems with conversion and basic capacity of vacant offices in Tokyo. It has been confirmed that there are no constraints concerned with Real Estate Registration Law (although it requires the change of the registration after conversion). and City Planning Law. However, some criteria are incompatible with Building Standard Law and Fire Service Law if the use of the building is changed from offices to flats. Typical incompatibility between offices and flats is lightening. If the buildings do not satisfy criteria for flats, the cost of renovation works for conversion will increase. To examine the basic capacity of vacant office buildings for conversion, field surveys in Tokyo have carried out at three areas: Kodenmacho (Chuo-ku), Toranomon (Minato-ku), and Iwamonocho (Chiyoda-ku). They are typical office areas that are included in center core of Tokyo. In Chuo-ku, the oldest commercial area in Tokyo, textile merchants have been located their headquarters. In Minato-ku, many rental office buildings have been located and several large scale redevelopments are advancing. Chiyoda-ku includes Marunouchi area, which is the prime office area in Japan. Thirty percent of the buildings in survey areas suffer from over twenty percent vacant floor rate, and fifty five percent were constructed before 1990. Especially most of buildings over forty percent vacant floor rate were constructed in 1980s. Vacant office problems haven't been seen in old buildings in Tokyo yet. The number of dwelling units made from office space will influence the conversion scheme. Seventy percent of the office buildings in survey areas have floor area of less than two hundred square meters. If they have been subdivided into two bedrooms type or three bedrooms type, the number of dwelling units in a floor would be less than three. The difficulty of conversion planning derives from frontage size, depth size, and their proportion. The five categories are proposed to grasp actual requirements for converting offices into flats.

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Preparation of Electroless Copper Plated Activated Carbon Fiber Catalyst and Reactive Evaluation of NO Removal (무전해 도금법으로 제조된 구리 함유 활성탄소섬유 촉매의 제조와 NO 제거 반응성 평가)

  • Yoon, Hee-Seung;Oh, Jong Hyun;Lee, Hyung Keun;Jeon, Jong-Ki;Ryu, Seung Kon
    • Korean Chemical Engineering Research
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    • v.46 no.5
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    • pp.863-867
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    • 2008
  • Pitch based activated carbon fiber(ACF) was prepared from reformed naphtha cracking bottom oil(NCB oil) by melt spinning. The fibers obtained were stabilized, carbonized, and then steam activated. The ACF was sensitized with Pd-Sn catalytic nuclei via a single-step activation approach. This sensitized ACF was used as precursors for obtaining copper plated ACFs via electroless plating. ACFs uniformly decorated with metal particles were obtained with reduced copper plating in the reaction solution. Effects of the amount of copper on characteristics of ACF/Cu catalysts were investigated through BET surface area, X-ray diffraction, scanning emission microscopy, and ICP. The amount of copper increased with plating time, but the surface area as well as the pore volume decreased. NO conversion increased with reaction temperature. NO conversion decreased with increasing the amount of copper, which is seemed to be due to the reduction of surface area as well as the dispersion of copper.