• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.28 no.2
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• pp.75-79
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• 2015

Ti was deposited on the Al substrate using DC magnetron sputtering with changing the $N_2$ gas for the possible application of a solar absorbing layer. $N_2$ gas ranged from 50 to 75 sccm was systematically applied in the 5 sccm interval and the variation of the absorption rate was investigated. Microstructural examination and elemental analysis indicate that Ti was reacted with $N_2$ gas and formed $TiNO_x$ compound. As compared with the film without any exposure of $N_2$ gas, absorption rate improved by more than 20%. Typically the average absorption of $TiNO_x$ fim with 65% of $N_2$ gas was about 99% in the visible range, and the average absorption was more than 90% in the infrared absorption region respectively.

• Journal of Advanced Marine Engineering and Technology
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• v.20 no.2
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• pp.1-6
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• 1996

As conservation of global environment has becoming a major outstanding issue of the world, the International Maritime Organization(IMO) has been legislation a convention for prevention of air pollution from ships. By the new convention, use of air pollutants such as SO/sub x/, NO/sub x/, Freon and Halon Gas shall be restricted. In this regards, analysing these requirements of the convention is required as the convention will also be applied on restriction of discharging exhaust gases from ships by establishing a requirement of SO/sub x/ and NO/sub x/ discharged. The purposed of this study is as follows ; 1) Introducing of the backgrounds of legislating the convention for prevention of air pollution from ships and major contents of the convention and a countermeasures on the convention by Korea. 2) Reviewing by analyzing the influence on domestic industies concerned by restriction of SO/sub x/, NO/sub x/ in exhaust gases and sulphur content of fuel oil. 3) Preparing a countermeasure on the convention properly.

• Journal of Environmental Science International
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• v.15 no.6
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• pp.533-538
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• 2006

Removal of $NO_x$ on $CaO/TiO_2$ photocatalyst manufactured by the addition of $Ca(OH)_2$ was measured in relation with the amount of $Ca(OH)_2$ and calcination temperature. In case of pure $TiO_2$, the $NO_x$ removal decreased greatly with the increase of calcination temperature from $500^{\circ}C\;to\;700^{\circ}C$, whereas in the photocatalyst added with $Ca(OH)_2$, the removed amount of $NO_x$ was high and constant regardless of calcination temperature. Considering $NO_x$ removal patterns depending on the amount of $Ca(OH)_2$ added(50, 30, 10wt%), high removal rate showed at the photocatalysts containing less than 30wt% of $Ca(OH)_2$, and it was about 30% higher than that of pure $TiO_2$. From the XRD patterns, it is seen that the addition of $Ca(OH)_2$ contributes to maintaining the anatase structure that is favourable to photocatalysis. It also indicates that the possibility of the formation of calcium titanate($CaTiO_3$) by reacting with $TiO_2$ above $700^{\circ}C$. Apart from the favourable crystalline structure, the addition of $Ca(OH)_2$ helped increase the alkalinity of photocatalyst surface, thus promoting the photooxidation reaction of $NO_x$.

• Journal of Industrial Technology
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• v.21 no.A
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• pp.279-284
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• 2001

In this study, we analyzed the $NO_X$ removal effiency by the low temperature plasma process and investigated the effect of several process variables. Most of NO is converted into $NO_2$ and, later, into $HNO_3$ which reacts with $NH_3$ to form $NH_4NO_3$ particles. As the frequency of appling voltage increases, as the applied voltage increases or as the residential time increases, removal efficiency of the NO supplied initially increase. The removal efficiency of $NO_X$ also increases with the increase of $NH_3$ supplied.

• Journal of Environmental Science International
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• v.15 no.4
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• pp.333-340
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• 2006

A (5 wt.%)Mn-(1 wt.%)$V_{2}O_{5}/TiO_{2}$ catalyst were prepared by co-precipitation method and used for low-temperature selective catalytic reduction (SCR) of $NO_x$ with ammonia in the presence of oxygen. The properties of the catalysts were studied by X-ray diffraction (XRD), temperature programmed reduction (TPR) and scanning electron microscope-energy dispersive X-ray spectroscopy (SEM-EDS). The experimental results showed that (5 wt.%)Mn-(1 wt.%)$V_{2}O_{5}/TiO_{2}$ catalyst yielded 81% NO conversion at temperature as low as $150^{\circ}C$ and a space velocity of $2,400\;h^{-1}$. Crystalline phase of $Mn_{2}O_3$ was present at ${\ge}\;15%$ Mn on $V_{2}O_{5}/TiO_{2}$. XRD confirmed the presence of manganese oxide ($Mn_{2}O_{3}$) at $2{\theta}=32.978^{\circ}(222)$. The XRD patterns presented of (5 wt.%)Mn-(1 wt.%)$V_{2}O_{5}/TiO_{2}$ did not show intense or sharp peaks for manganese oxides and vanadia oxides. The TPR profiles of (5 wt.%)Mn-(1 wt.%)$V_{2}O_{5}/TiO_{2}$ catalyst showed main reduction peat of a maximum at $595^{\circ}C$.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.42 no.2
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• pp.163-170
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• 2022

The present study investigates NO_x-removal and sound-absorption performances of photocatalytic porous concrete prepared by various TiO₂ application methods. Photocatalytic porous concrete samples were prepared by one of the following: 1) mechanically mixing TiO₂ during casting; 2) mixing bottom ash aggregate pretreated with TiO₂ during casting; and 3) spraying TiO₂ solution to the normally fabricated porous concrete. The test results indicated that the mechanical mixing of TiO₂ decreased the compressive strength as the added TiO₂ content increased. The use of pretreated bottom ash aggregate reduced the porosity, yet the compressive strength of the concrete was similar to that measured from the former method. Porous concrete samples sprayed with the TiO₂ solution exhibited enhanced compressive strength, while the porosity was analogous to those measured from other methods. The NO_x-removal performance was the highest in the samples sprayed with the TiO₂ solution, followed by the samples using pretreated bottom ash aggregate and mechanically mixed TiO₂. The samples with mechanically mixed TiO₂ identified a relationship between soundabsorption performance and porosity. However, no particular tendency was observable in the samples with other TiO₂ application methods.

• Bulletin of the Korean Mathematical Society
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• v.61 no.2
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• pp.401-419
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• 2024

Let K, H, K_II and H_II be the Gaussian curvature, the mean curvature, the second Gaussian curvature and the second mean curvature of a timelike tubular surface T_γ(α) with the radius γ along a timelike curve α(s) in Minkowski 3-space E³₁. We prove that T_γ(α) must be a (K, H)-Weingarten surface and a (K, H)-linear Weingarten surface. We also show that T_γ(α) is (X, Y)-Weingarten type if and only if its central curve is a circle or a helix, where (X, Y) ∈ {(K, K_II), (K, H_II), (H, K_II), (H, H_II), (K_II , H_II)}. Furthermore, we prove that there exist no timelike tubular surfaces of (X, Y)-linear Weingarten type, (X, Y, Z)-linear Weingarten type and (K, H, K_II, H_II)-linear Weingarten type along a timelike curve in E³₁, where (X, Y, Z) ∈ {(K, H, K_II), (K, H, H_II), (K, K_II, H_II), (H, K_II, H_II)}.

• Journal of Environmental Science International
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• v.32 no.5
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• pp.285-301
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• 2023

This study analyzed characteristics of ozone (O₃) formation regimes in Busan over a period of recent five years (2015~2019) and compared the findings with those obtained in Seoul. We employed four observed variations: early morning commuting-hour (i.e., 06:00-09:00 LST) nitrogen dioxide (NO₂), peak-hour (i.e., 12:00-16:00 LST) O₃, 8-hour average O₃ (MDA8 O₃), and △O₃ (=O_{3_max}- O_{3_min}) in Busan and Seoul. In addition, the NO₂-O₃ relation was assessed to interpret which of NOx-limited or volatile organic compound (VOC)-limited was dominant. In Busan, the annual mean O₃ concentration was relatively higher than in Seoul, whereas there were fewer high-concentration days. The Pearson correlation coefficients (R) between Early morning-hour NO₂ and the Peak-hour O₃ was positive (but close to zero) in Busan and negative in Seoul. Likewise, the R between the Early morning-hour NO₂ and the △O₃ showed a relatively considerable positive correlation (R=+0.4~0.5)(R=+0.4~0.5) in Busan, while a weak positive correlation (R=+0.1~0.2) in Seoul. From this result, it can be inferred that the O₃ formation regime in Busan was intrepreted to be nearly neutral or relatively closer to the NO_x-limited regime than Seoul, while Seoul to the VOC-limited regime. The study findings imply that O₃ control strategies should be applied differently in Busan and Seoul. The results here were inferred from surface NO₂ and O₃ observations, and the varification studies based on in-situ VOCs measurements would be needed.

• Journal of Industrial Technology
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• v.21 no.B
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• pp.155-161
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• 2001

In this study, we analyzed the $NO_X$ removal efficiency and particle size distribution by the pulsed corona discharge process and investigated the effect of several process variables. The NO removal efficiencies and the particle characteristics were measured and analyzed as the function of initial concentrations of NO, $H_2O$, and $NH_3$, applied voltage, pulse frequency and residence time. As the frequency of applied voltage increases, or as the applied voltage increases or as the residence time increases, the NO removal efficiency increases. The change of initial $NH_3$ and $H_2O$ concentrations do not affect the NO removal efficiency significantly. The particle concentration and size increases with the increases of initial NO concentration, residence time and applied voltage.

• Korean Journal of Metals and Materials
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• v.50 no.3
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• pp.201-205
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• 2012

The effects of various manganese precursors for the low-temperature selective catalytic reduction (SCR) of $NO_x$ were investigated in terms of structural, morphological, and physico-chemical analyses. $MnO_x/TiO_2$ catalysts were prepared from three different precursors, manganese nitrate, manganese acetate(II), and manganese acetate(III), by the sol-gel method. The manganese acetate(III)-$MnO_x/TiO_2$ catalyst tended to suppress the phase transition from the anatase structure to the rutile or the brookite after calcination at $500^{\circ}C$ for 2 h. It also had a high specific surface area, which was caused by a smaller particle size and more uniform distribution than the others. The change of catalytic acid sites was confirmed by Raman and FT-IR spectroscopy and the manganese acetate(III)-$MnO_x/TiO_2$ had the strongest Lewis acid sites among them. The highest de-NOx efficiency and structural stability were achieved by using the manganese cetate(III) as a precursor, because of its high specific surface area, a large amount of anatase $TiO_2$, and the strong catalytic acidity.