• Journal of the Korean Applied Science and Technology
• /
• v.13 no.1
• /
• pp.31-39
• /
• 1996

In this study, sensitizing dye was prepared by the reaction of 2-methyl-3-sulfopropyl-4, 5-naphthothiazolium(inner salt) with triethyl orthoformate in the presence of triethylamine. The product was identified by using various analytical tools such as Elemental analyzer, IR spectrophotometer, UV-Vis spectrophotometer, $^1H-NMR$ spectrometer, TGA and DSC. Therefore, it was concluded that naphthothiazolo carbocyanine dye can be used as red-sensitizing dye for the spectral sensitization of photographic emulsion.

• Journal of the Korean Magnetic Resonance Society
• /
• v.20 no.1
• /
• pp.13-16
• /
• 2016

Various experiments using zebrafish have been highlighted recently in the scientific community. Because it is possible to conduct practical experiment from various neurological research to area of genetic study or toxicity experiment. However, gender difference effects are nearly not considered. If the gender differences of zebrafish are considered it is possible to obtain more accurate data. In this study, zebrafish which have different genders were compared each other with NMR-based metabolomics. The extracts of male and female zebrafish were measured by 600 MHz NMR spectrometer. Statistical analysis and target profiling were conducted. As a result, muscle related metabolites were observed in male zebrafish and nerve related metabolites were observed in female zebrafish.

• Journal of the Korean Magnetics Society
• /
• v.4 no.2
• /
• pp.184-187
• /
• 1994

Nuclear magnetic resonance of $^{133}Cs$ in a $CsMnCl_{3}$ single crystal grown by the Czochralski method has been investigated by employing a Bruker FT NMR spectrometer. The $^{133}Cs$ resonance of two different groups were recorded. Various transitions belonging to two cesium spectra of a different intensity ratio are analyzed. The quadrupole coupling constant of Cs(I) is $0.15{\pm}0.01$ MHz, and that of Cs(II) is $0.21{\pm}0.01$ MHz. The anisotropy parameter is zero for both. The principal axes of the EFG tensors for these two sites are found to be the same. The Z axis, conventionally the largest component of the EFG tensor, is parallel to the crystallographic c-axis.

• Journal of the Korean Magnetics Society
• /
• v.5 no.3
• /
• pp.175-178
• /
• 1995

The temperature dependence of $^{23}Na$ nuclear magnetic resonance in a $NaMnCl_{3}$ single crystal grown by the Czochralski method has been investigated by employing a Bruker FT NMR spectrometer operating at 4.7 T. The quadrupole coupling constant of $^{23}Na$ in $NaMnCl_{3}$ increases as the temperature increases. The temperature dependence of $e^{2}qQ/h$ may be fitted with a linear equation of the form $e^{2}qQ/h=155+0.117(T-T_{r})\;kHz$ for the temperature range of 140-380 K.

• Progress in Superconductivity and Cryogenics
• /
• v.24 no.3
• /
• pp.24-29
• /
• 2022

One of the recent proposals with nuclear magnetic resonance (NMR) is a multi-bore NMR which consists of array of magnets which could present possibilities to quickly cope with pandemic virus by multiple inspection of virus samples. Low temperature superconductor (LTS) can be a candidate for mass production of the magnet due to its low price in fabrication as well as operation by applying the helium zero boil-off technology. However, training feature of LTS magnet still hinders the low cost operation due to multiple boil-offs during premature quenches. Thus in this paper, LTS magnet with low mechanical stress is designed targeting the "training-free" LTS magnet for mass production of magnet array for multi-bore NMR. A thorough process of an LTS magnet design is conducted, including the analyses as the followings: electromagnetics, mechanical stress, cryogenics, stability, and protection. The magnet specification was set to 4.7 T in a winding bore of 85 mm, corresponding to the MR frequency of 200 MHz. The stress level is tolerable with respect to the wire yield strength and epoxy crack where mechanical disturbance is less than the minimum quench energy.

• Microbiology and Biotechnology Letters
• /
• v.26 no.5
• /
• pp.442-449
• /
• 1998

Several transglucosylated xylitols were synthesized using intermolecular transglucosylation reaction of cyclodextrin glucanotransferase (CGTase) and their bifidogenic effects were investigated. The CGTase from Thermoanaerobacter sp. showed the highest transglycosylation activity on xylitol compared to those obtained from other strains. Extruded starch was identified to be the most suitable glucosyl donor for transglucosylation reaction on xylitol molecule by CGTase. The optimum reaction conditions for transglucosylation were also studied using extruded starch as a glucosyl donor. The transglucosylated xylitols were purified by activated carbon column chromatography with ethanol gradient elution from 0 to 18%, and their chemical structures were analyzed by fast atom bombardment mass spectrometer, $\^$13/C-nuclear magnetic resonance spectrometer, and enzyme digestion method. Two transglucosylated xylitol, F-I and F-II, which had one or two glucose molecules attached to maternal xylitol by ${\alpha}$-1,4-linkage, were mainly obtained. F-II showed increased stimulation effect on the growth of Bifidobacterium breve compared to xylitol, indicating the possibility utilized as a new functional alternative sweetners having bifidogenic effects.

• Polymer(Korea)
• /
• v.38 no.4
• /
• pp.550-556
• /
• 2014

Recently, the peptide(or protein)-polymer hybrid materials (PPs) were sought in many research areas as potential building blocks for assembling nanostructures in selective solvents. In PPs, the facile routes of preparing well-defined peptide-polymer bio-conjugates and their specific activities in various applications are important issues. Our strategy to prepare the peptide-polymer hybrid materials was to combine atom transfer radical polymerization (ATRP) method with solid phase peptide synthesis. The standard solid phase peptide synthesis method was employed to prepare the PYGK (proline-tyrosine-glycine-lysine) peptide. PYGK is an analogue peptide, PFGK (proline-phenylalanine-glycine-lysine), which interacted with plasminogen in fibrinolysis. The peptide and the peptide-initiator were characterized with MALDI-TOF mass spectrometry and $^1H$ NMR spectrometer. The peptide-polymer, pSt-PYGK was characterized by GPC, IR, $^1H$ NMR spectrometer and TLC. Spherical micellar aggregates were determined by TEM and SEM. Current synthesis methodology suggested opportunities to create the well-defined peptide-polymer hybrid materials with specific binding activity.

• Applied Chemistry for Engineering
• /
• v.21 no.6
• /
• pp.638-642
• /
• 2010

After phthalonitrile derivatives were synthesized by the introduction of phenoxy, 2-naphthoxy or 4-trityl phenoxy group on ${\alpha}$- and ${\beta}$-position, oxovanadyl phthalocyanine (VOPc) derivatives containing electron-rich substituent group at different position were synthesized successfully in this investigation. The chemical structure of samples was determined by the means of $^1H$-NMR, MALDI-TOF mass spectroscopy, and FT-IR spectrometer. Also, optical and chemical properties were determined by the means of UV-Vis spectrometer, X-ray diffractometry, and thermo gravimetry. It was found that the maximum absorbing wavelength of VOPc derivatives ranged from 684 to 726 nm. Also, their solubility and Q-band were enhanced and shifted by the introduction of substitute group, respectively.

• Journal of the Korean Chemical Society
• /
• v.36 no.2
• /
• pp.305-310
• /
• 1992

(${\eta}^5$-Cyclopentadienyl)bis(ethylene)cobalt (Jonas reagent), (${\eta}^5$-cyclopentadienyl)di(carbonyl)cobalt, and bis(${\eta}^5$-cyclopentadienyl)cobalt (cobaltocene) were reacted with oximes, respectively, under various conditions for synthesizing cobalt oxime sandwich complex. Jonas reagent and a dienemonooxime, 2,4-hexadienealdoxime underwent the reaction. This produced unexpected compound, (${\eta}^5$-cyclopentadienyl)(2,4-hexadienenitrile)cobalt [VII]. The compound [VII] was identified by NMR, mass spectrometer, IR and elemental analyzer etc.

• Elastomers and Composites
• /
• v.47 no.3
• /
• pp.216-222
• /
• 2012

In this study, p-acryloyloxybenzoic acid(ABA) was synthesized with p-hydroxybenzoic acid(HBA) and acryloyl chloride(AC). The synthesized ABA monomer was grafted onto ethylene-propylene-diene rubber(EPDM) in toluene using benzoyl peroxide(BPO) as an initiator. The structures of ABA and EPDM-g-ABA were characterized by FT-IR, $^1H$-NMR, and $^{13}C$-NMR spectrometer. The graft ratio of EPDM-g-ABA increased with increasing the concentration of the initiator and the monomer. Mechanical properties such as tensile strength and compression set of the EPDM-g-ABA were improved with increasing the graft ratio. The $T_g$ and initial decomposition temperature were also increased with increasing the graft ratio.