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The Study for Synthesis and Characteristic of ${\alpha},{\beta}$-tetra(phenoxy, 2-naphthoxy, 4-tritylphenoxy) Oxovanadium Phthalocyanine Derivatives  

Son, Dae-Hee (CFC Teramate Co. Ltd.)
Heo, Jin (CFC Teramate Co. Ltd.)
Kim, Song-Hyuk (Division of Applied Chemical Engineering, Pukyong National University)
Lee, Seung-Ho (Composite Materials Center, Korea Institute of Ceramic Eng. & Tech.)
Lee, Gun-Dae (Division of Applied Chemical Engineering, Pukyong National University)
Hong, Seong-Soo (Division of Applied Chemical Engineering, Pukyong National University)
Park, Seong-Soo (Division of Applied Chemical Engineering, Pukyong National University)
Publication Information
Applied Chemistry for Engineering / v.21, no.6, 2010 , pp. 638-642 More about this Journal
Abstract
After phthalonitrile derivatives were synthesized by the introduction of phenoxy, 2-naphthoxy or 4-trityl phenoxy group on ${\alpha}$- and ${\beta}$-position, oxovanadyl phthalocyanine (VOPc) derivatives containing electron-rich substituent group at different position were synthesized successfully in this investigation. The chemical structure of samples was determined by the means of $^1H$-NMR, MALDI-TOF mass spectroscopy, and FT-IR spectrometer. Also, optical and chemical properties were determined by the means of UV-Vis spectrometer, X-ray diffractometry, and thermo gravimetry. It was found that the maximum absorbing wavelength of VOPc derivatives ranged from 684 to 726 nm. Also, their solubility and Q-band were enhanced and shifted by the introduction of substitute group, respectively.
Keywords
oxovanadyl phthalocyanine; derivative; electrodonating substituent; red-shift;
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