• Bulletin of the Korean Chemical Society
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• v.30 no.4
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• pp.882-886
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• 2009

The electrode contact poling is one of the efficient tools to induce a stable polar order of nonlinear optical (NLO) chromophores in the solid film. Self-assembled NLO chromophores with high electro-optic (E-O) activities were utilized for quantitative determination of the chromophore order induced under contact poling by spectroscopic changes. We found that NLO chromophores rarely decompose under the high electric field during contact poling. The absorption spectra were de-convoluted into a sum of Gaussian components to separate energy transitions for a binary composite system which contains a secondary guest chromophore AJC146 in the self-assembled chromophore HDFD. Poling efficiency was significantly improved in the binary system compared to the individual components.

• Journal of Photoscience
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• v.11 no.3
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• pp.101-106
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• 2004

The photorefractive composites fabricated by blending NLO chromophores such as 3-(4-{bis-[4-(2-ethylhexyloxy)-phenyl]-amino}-phenyl)-2-isocyano-acrylonitrile (PAIA), bis-[4-(2-ethyl-hexyloxy)-phenyl]-{4-[2-(4-nitrophenyl)-vinyl]-phenyl}-amine (PNPA) with photoconducting crosslinkable matrix, bis-(4-ethynylphenyl)-(4-octyloxyphenyl)-amine (BEOPEA), showed photorefractive property due to the high composition of NLO chromophores caused by introducing alkoxy chain, and many problems faced in typical organic photorefractive systems such as timeconsuming chemical synthesis, difficulty in rational design, intrinsic instability and phase separation could be avoided.

• Proceedings of the Optical Society of Korea Conference
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• 1996.09a
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• pp.89-89
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• 1996

• The Journal of Korean Institute of Communications and Information Sciences
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• v.42 no.2
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• pp.444-452
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• 2017

Recently, a demand of Internet-of-things (IoT) rises dramatically and an interest in Low Power Wide Area (LPWA) grows larger accordingly. In this paper, performance in LoRa which is included in LPWA standard is analyzed. Particularly, after measuring Received Signal Strength Indication (RSSI) of received signal on Line-of-sight (LoS) and Non-line-of-sight (NLoS) environment and it is compared with RSSI which theoretical path loss model is applied to. Among many path loss models, the simulation for theoretical RSSI use Log-distance, Two-ray model and Okumura-Hata model that is based on the test database. Consequently, the result of Okumura-Hata model is the most similar with the measured RSSI. When a network based on LoRa is built, this result can used to decide optimal node arrangement.

• Korean Journal of Optics and Photonics
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• v.13 no.4
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• pp.356-362
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• 2002

The molecular orientational dynamics of the nonlinear optical(NLO) side-chain polymer N-(4-nitrophenyl)-(L)-prolinol-poly (pphenylene terephthalates) have been studied using nonlinear optical responses as measured by second harmonic generation (SHG). A new pulsed corona poling is used to orient the NLO chromophores and the polymer segments into the noncentrosymmetric structure required to obtain the SHG signal. By corona poling of negative high voltage pulses with variable repetition rates (between 0.5 and 10 ㎑) at temperature between 25$^{\circ}C$ and 80$^{\circ}C$, well below and about the glass transition temperature 70$^{\circ}C$, the side-chain chromophores and the polymer chain contour rearrange themselves and create the domain structure observed by atomic force microscopy(AFM). The pulsed corona voltage enhances the orientational ordering of the NLO chromophores and also significantly influences the growth of SHG signal and the improved relaxation behavior after the poling field is removed, reducing the visible damage to the polymer film dramatically. This new pulsed corona poling experiment gave direct in situ evidence that the NLO chromophore and the polymer backbone undergo anisotropic rearrangement during the poling process.

• Bulletin of the Korean Chemical Society
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• v.32 no.5
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• pp.1443-1454
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• 2011

Methods to prepare novel second-order nonlinear optical (2O-NLO) materials composed of all-silica zeolite (silicalite-1) and a series of 2O-NLO molecules having high second order hyperpolarizability constants (${\beta}$ values) are reviewed. These methods include the development of novel methods to incorporate a series of hemicyanine (HC) molecules into the channels of silicaite-1 films in uniform orientations. The first method is to incorporate HC molecules tethered with long alkyl chains (octadecyl or longer) into the silicalite-1 channels with the long alkyl chain side first through the hydrophobic-hydrophobic interaction between the long alky chains and the silicalite-1 channels. The second method is to incorporate the HC molecule tethered with a medium length alkyl chain (nonyl) into the silicalite-1 channels with the medium length alkyl chain side first through hydrophobic-hydrophobic interaction between the medium length alky chain in the photoexcited state and the silicalite-1 channels. The third method is to incorporate the HC molecule tethered with propionic acid into the silicalite-1 channels with the propionic acid side last mediated by a tetrabultylammonium cation ion-paired to the propionate unit. A method to prepare a novel third-order nonlinear optical (3O-NLO) material composed of zeolite-Y and PbS or PbSe quantum dots is also reviewed. This Account thus describes a promising new direction to which the search for highly sensitive 2O-NLO and 3O-NLO materials has to be conducted and a new direction to which zeolite research and applications have to be expanded.

• Journal of the Korean Chemical Society
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• v.57 no.4
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• pp.461-471
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• 2013

Optimized geometrical structure, atomic charges, molecular electrostatic potential, nonlinear optical (NLO) effects and thermodynamic properties of the title compound N-(2,5-methylphenyl)salicylaldimine (I) have been investigated by using ab initio quantum chemical computational studies. Calculated results showed that the enol form of (I) is more stable than keto form. The solvent effect was investigated for obtained molecular energies, hardneses and the atomic charge distributions of (I). Natural bond orbital and frontier molecular orbital analysis of the title compound were also performed. The total molecular dipole moment (${\mu}$), linear polarizability (${\alpha}$), and first-order hyperpolarizability (${\beta}$) were calculated by B3LYP method with 6-31G(d), 6-31+G(d,p), 6-31++G(d,p), 6-311+G(d) and 6-311++G(d,p) basis sets to investigate the NLO properties of the compound (I). The standard thermodynamic functions were obtained for the title compound with the temperature ranging from 200 to 450 K.

• Journal of Communications and Networks
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• v.18 no.3
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• pp.397-410
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• 2016

This paper proposes a novel cooperative localization method for distributed wireless networks in 3-dimensional (3D) global positioning system (GPS) denied environments. The proposed method, which is referred to as hybrid ellipsoidal variational algorithm (HEVA), combines the use of non-parametric belief propagation (NBP) and variational Bayes (VB) to benefit from both the use of the rich information in NBP and compact communication size of a parametric form. InHEVA, two novel filters are also employed. The first one mitigates non-line-of-sight (NLoS) time-of-arrival (ToA) messages, permitting it to work well in high noise environments with NLoS bias while the second one decreases the number of calculations. Simulation results illustrate that HEVA significantly outperforms traditional NBP methods in localization while requires only 50% of their complexity. The superiority of VB over other clustering techniques is also shown.

• Journal of the Korean Chemical Society
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• v.40 no.2
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• pp.32-152
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• 1996

• Proceedings of the Korean Information Science Society Conference
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• 2006.06d
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• pp.178-180
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• 2006

실내 위치 환경에서 많이 사용되고 있는 삼각 측량 기법은 TOA(Time of Arrival) 신호를 사용하기 때문에 건물의 외벽이나 창의 메탈 성분 같은 장애물로 인한 전파의 반사와 회절, 분산 등의 NLOS(Non-Line-Of-Sight) 환경으로 인하여 정확한 위치추적이 어렵다는 문제점이 있다. 따라서 본 논문은 이러한 문제점을 줄이기 위해서 Anchor로부터 수신되는 TOA의 range measurement의 표준 편차를 측정하여 LOS와 NLOS를 구분하고, 발견된 NLOS를 보정하는 방법에 대하여 연구한다. 또한 위치 정확도를 높이기 위하여 칼만 필터를 수행하여 이동객체의 위치를 생성하는 실내 환경에서의 위치 추적 시스템을 설계한다.