• Bulletin of the Korean Chemical Society
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• 제18권8호
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• pp.850-856
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• 1997

A series of tetradentate Schiff-base ligands; 1,3-bis(salicylideneimino) propane, 1,4-bis(salicylideneimino)butane, and 1,5-bis(salicylideneimino)pentane, and their Cu(Ⅱ) and Ni(Ⅱ) complexes have been synthesized. The properties of ligands and complexes have been characterized by elemental analysis, IR, NMR, UV-Vis spectra, molar conductance, and thermogravimetric anaylsis. The mole ratio of Schiff base to metal at complexes was found to be 1 : 1. All complexes were four-coordinated configuration and non-ionic compound. The electrochemical redox processes of the ligands and their complexes in DMF solution containing 0.1 M TEAP as supporting electrolyte have been investigated by cyclic voltammetry, chronoamperometry, differential pulse voltammetry at glassy carbon electrode, and by controlled potential coulometry at platinum gauze electrode. The redox process of the ligands was highly irreversible, whereas redox process of Cu(Ⅱ) and Ni(Ⅱ) complexes was observed as one electron transfer process of quasi-reversible and diffusion-controlled reaction. Also the electrochemical redox potentials of complexes were affected by chelate ring size of ligands. The diffusion coefficients of Cu(Ⅱ) and Ni(Ⅱ) complexes in DMF solution were determined to be 4.2-6.6×10-6 cm2/sec. Also the exchange rate constants were determined to be 3.6-9.7×10-2 cm/sec.

• Bulletin of the Korean Chemical Society
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• 제29권10호
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• pp.1905-1910
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• 2008

The reaction of 3,14-dimethyl-2,6,13,17-tetraazatetracyclo[16.4.0$0^{1.18}.0^{7.12}$]docosane ($L^1$) with formaldehyde in warm methanol yielded 3,14-dimethyl-2,6,13,17-tetraazatetracyclo[16.4.$1^{2.6}.0^{1.18}.0^{7.12}$]tricosane ($L^7$) containing one 1,3-diazacyclohexane subunit. In methanol, $L^7$ readily reacts with $Cu^{2+}$ ion to form [$CuL^7(H_2O)$]$^{2+}$ which is extremely inert against methanolysis. In the solution containing $Ni^{2+}$ ion, however, $L^7$ reacts with methanol to yield [$NiL^3$]$^{2+}$ ($L^3$ = 2-(methoxymethyl)-5,16-dimethyl-2,6,13,17-tetraazatricyclo[16.4.$0^{1.18}.0^{7.12}$]- docosane), in which one N-$CH_2OCH_3$ pendant arm is appended. The copper(II) complex [$CuL^7(H_2O)$]- $(ClO_4)_2{\cdot}3H_2O\;(I{\cdot}3H_2O)$ has a severely distorted trigonal bipyramidal coordination geometry with a 4-5- 6-5 chelate ring sequence. The crystal structure of [$NiL^3$]$(PF_6)_2{\cdot}2H_2O$ (IIb) shows that the N-$CH_2OCH_3$ pendant arm is not coordinated to the metal ion in the solid state. In various solvents (S), however, the nickel(II) complex exists as a mixture of [$NiL^3$(S)]$^{2+}$, in which the N-$CH_2OCH_3$ group as well as S is coordinated to the metal ion, and [$NiL^3$]^{2+}.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2000년도 하계학술대회 논문집
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• pp.423-426
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• 2000

The 3-D $31.5$\times$31.5$\times$2.5mm$^3$model of contour vibration mode piezoelectric transformer with Pb($Ni_{1/2}$$W_{1/2}$)$O_3$-Pb(Zr,Ti)$O_3$ ceramics was simulated by ANSYS according to the dot size 17, 18, 19, 20, 21 $mm\phi$ and analyzed the results. The mechanical quality factor of the 3-D model was decreased with the dot size and increased as 2605 at 20 $mm\phi$ and after then decreased again. The output voltage of that sample was 74123 [V] and the maximum stress of the dot electrode at that sample was 288[$10^7$N/$m^2$] and the maximum displacement of the ring electrode at that sample was 128 [$\mu\textrm{m}$].

• 대한공업교육학회지
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• 제31권1호
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• pp.200-210
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• 2006

초기 응력부식균열에 대한 감수성 평가 시험법인 C링 시험법(C-ring Test)은 용접부의 후열처리 균열감수성을 평가하는 시험법으로 적합하다고 알려져 있다. C링 시험법은 실제 용접부 열영향부에 노치를 제작하여 잔류응력이 열영향부에 미치는 영향을 평가할 수 있다는 장점을 가지고 있다. 따라서 본 연구에는 C링 시험법을 이용하여 원자력 발전소 압력용기에 사용되는 Co-Mo강의 용접부 결함 발생 현상을 검토 하고자 Co-Mo강에 대하여 후열처리를 실시하였으며, C링 시험법을 통하여 용접 열영향부의 후열처리 균열을 평가하고자한다. 결론은 다음과 같다. 바나듐 모디파이 합금(AMAX 3Cr-1Mo­-0.1V, JSW 3Cr-­1Mo-­V-­Ti-­B 및 JSW $2\frac{1}{4}Cr$-1Mo-­V-­Ti-­B강)은 Berkeley $3Cr-1\frac{1}{2}Mo-\frac{1}{2}Ti$ 및 $2\frac{1}{4}Cr$-­1Mo합금강보다 후열처리 균열에 대한 감수성 보다 높게 나타났다. C-ring 시험에 있어서 바나듐 모디파이 합금은 2종의 후열처리조건과 3종의 응력조건에서 모두 균열을 나타냈으나 Berkeley $3Cr-1\frac{1}{2}Mo-\frac{1}{2}Ni$강과 Luken $2\frac{1}{4}Cr-1Mo0.1C$재료는 690MPa와 더 이상의 응력조건에서 2종의 후열처리를 실시하는 조건에서도 균열이 발생하지 않았다. C-ring 시험결과, 균열깊이는 바나듐 모디파이 재료인 경우, 낮은 후열처리온도와 비교해서 높은 후열처리온도인 경우가 감소하고 있다. C-ring 시험에 대한 SEM분석결과 균열은 오스테나이트 결정 입계를 따라 파괴되는 파괴양상을 나타내고 있으며 연성파면은 나타나지 않았다.

• 한국원자력학회:학술대회논문집
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• 한국원자력학회 1998년도 춘계학술발표회논문집(2)
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• pp.84-89
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• 1998

Alloy 600 및 alloy 690과 Ni-8Cr-lOFe 합금 등의 응력부식(stress corrosion cracking, SCC) 거동을 고온의 염기성 분위기에서 C-ring 시편을 사용하여 연구하였다. Alloy 600과 alloy 690을 여러 조건에서 열처리하여 etching한 후 탄화물의 분포와 입계 주변의 Cr고갈 정도 등의 미세조직을 광학현미경과 주사 전자현미경(SEM)으로 관찰하였다. 이들 재료에 대한 SCC 시험을 315$^{\circ}C$의 40% NaOH 수용액에서 일정한 부하전위(부식전위 + 200㎷)를 가하면서 수행하였으며, 동일 조건에서의 분극거동도 측정하였다. Alloy 600 MA(mill anneal) 및 TT(thermal treatment)의 SCC 저항성은 alloy 690 TT와 Ni-8Cr-10Fe SA(solution anneal)보다 낮았다. Alloy 600 TT 재료는 alloy 600 MA 및 SA 재료에 비해 SCC 저항성이 더 컸다. 고용 탄소농도는 alloy 600의 SCC 저항성에 큰 영향을 주지 못했다. 대부분의 Alloy 600은 균열전파 입계균열을 보였으나, 일부에서는 입계 및 입내 혼합양상(mixed mode cracking)을 보였다. 염기성 분위기에서 Ni기 합금의 SCC 거동을 미세조직, 분극거동의 관점에서 고찰하였다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1999년도 춘계학술대회 논문집
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• pp.247-250
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• 1999

In this study, three kinds of Mn-Zn ferrite/Ni-Zn ferrite/$Ni_2Y$ ferroxplana prepared by the coprecipitation method was compounded with silicon rubber, and thereafter made ring-type specimens with various compositional ratio. The material constant of ferrite/rubber composite absorbers was obtaibed by the 2-port method. The material constants of the ferrite/rubber composite absorber with various compositional ratio of three kinds of ferrite were used to design the matching frequency and thickness with the impedance matching map. We were able to predict the matching condition from the design method.

• Bulletin of the Korean Chemical Society
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• 제26권6호
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• pp.925-929
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• 2005

Some new metal(II) complexes, $M^{II}L_2$ [M = Mn (1), Co (2), Ni (3), Cu (4), and Zn (5)] of 2-acetylpyridine benzoylhydrazone ligand (HL) containing trifunctional NNO-donor system have been synthesized and crystallographically characterized for the complex 1 and 5. The complexes consist of two ligands to give sixcoordinate, which are bonded to the metal atom on a meridional plane through acetylpyridine ring nitrogen, azomethine nitrogen, and benzoyl oxygen atoms, respectively. The coordination geometry for other complexes was identified on the basis of the physicochemical data by elemental analyses, FAB -MS, IR, $^1H$ NMR, and electronic spectral measurements. The resulting data indicated that the complexes are accordance with the above formulation.

• 한국자기학회:학술대회 개요집
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• 한국자기학회 2007년도 The 1st International Symposium on Advanced Magnetic Materials
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• pp.203.1-203.1
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• 2007

• Bulletin of the Korean Chemical Society
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• 제32권6호
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• pp.1884-1890
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• 2011

A series of Ni(II) and Pd(II) complexes bearing N4-type tetradentate ligands, [Ni($X^1X^2$-6-$Me_2bpb$) 1] and [Pd($X^1X^2$-6-$Me_2bpb$) 2]; 6-$Me_2bpb$ = N,N'-(o-phenylene)bis(6-methylpyridine-2-carboxamidate), $X^1$ = Cl, H, or $CH_3$, $X^2$ = $NO_2$, Cl, F, H, $CH_3$, or $OCH_3$) were designed, synthesized, and characterized to investigate electronic and steric effects of ligand on the norbornene polymerization catalysts. Using modified methylaluminoxanes as an activator, the complexes exhibited high catalytic activities for the polymerization of norbornene and the nickel complexes exhibited better catalytic activity the palladium complexes. Ni complex 1a with $NO_2$ group on the benzene ring showed the highest catalytic activity of $4.9{\times}10^6$ g of PNBEs/$mol_{Ni}{\cdot}h$ and molecular weight of $15.28{\times}10^5$ g/mol with PDI < 2.30. Complexes with electron-withdrawing groups are more thermally stable (> 100 $^{\circ}C$), and tend to afford higher polymerization productivities than the ones having electron-donating groups. Amorphous polynorbornenes were obtained with good solubility in halogenated aromatic solvents. A vinyl addition mechanism has been proposed for the catalytic polymerization.

• 한국정보통신학회논문지
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• 제10권7호
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• pp.1281-1286
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• 2006

초고내압용 (1,200 V급) 의 플래너 접합 장벽 쇼트키 정류기 개발을 위해서 기존의 실리콘 재질 대신에 탄화규소 (4H-SiC) 제질을 사용하였다 . 기판의 크기는 2 인치 웨이퍼이며, 농도는 $3*10^{18}/cm^{3}$의 $n^{+}-$형이며, 에피층은 두께 $12{\mu}m$, 농도는 $5*10^{15}/cm^{-3}\:n-$형이다. 제작 소자는 접합 장벽 쇼트키 다이오드이며, 항복전압을 개선시키기 위해 고농도 의 보론 보호테의 불순물 분포를 사각모양 설계하였으며, 보호태의 폭과 간격을 변화하였다 . 정류성 접촉 금속은 $Ni(3,000\:{\AA})/Au(2,000\:{\AA})$ 사용하였다 . 결과로써, 소자의 특성은 온-상태 전압이 1.26 V, 온-상태 저항은 m$45m{\Omega}/cm^{3}$으로 낮은 특성과역방향 항복전압은 1,180 V의 최대값이며, 이 항복전압의 역방향 누설전류밀도는 $2.26*10^{-5}A/CM^{3}$의 값이며, 전기적 파라미터의 특성 결과가 개선되었다.