• Journal of The Korean Society of Grassland and Forage Science
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• v.40 no.4
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• pp.274-278
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• 2020

Pig slurry (PS) is the most applicable recycling option as an alternative organic fertilizer. The application of pig slurry has the risk of air pollution via atmospheric ammonia (NH3) and nitrous oxide (N2O) emission. The zeolite has a porous structure that can accommodate a wide variety of cations, thus utilizing for the potential additive of deodorization and gas adsorption. This study aimed to investigate the possible roles of zeolite in mitigating NH3 and N2O emission from the pig slurry applied to the maize cropping. The experiment was composed of three treatments: 1) non-N fertilized control, 2) pig slurry (PS) and 3) pig slurry mixed with natural zeolite (PZ). Both of NH3 and N2O emission from applied pig slurry highly increased by more than 3-fold compared to non-N fertilized control. The NH3 emission from the pig slurry was dominant during early 14 days after application and 20.1% of reduction by zeolite application was estimated in this period. Total NH3 emission through whole period of measurement was 0.31, 1.33, and 1.14 kg ha-1. Nitrous oxide emission in the plot applied with pig slurry was also reduced by zeolite treatment by 16.3%. Significant increases in forage and ear yield, as well as nutrient values were obtained by pig slurry application, while no significant effects of zeolite were observed. These results indicate that the application of zeolite and pig slurry efficiently reduces the emission of ammonia and nitrous oxide without negative effects on maize crop production.

• Journal of Environmental Impact Assessment
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• v.9 no.1
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• pp.39-46
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• 2000

Removal of ammonia using the porous ceramic biofilter inoculated with earthworm casts was characterized. By assuming a plug air flow in the biofilter and applying the Michaelis-Menten equation, the maximum removal rate of $NH_3$ was $280.7g-N{\cdot}m^{-3}{\cdot}h^{-1}$($18.0g-N{\cdot}kg^{-1}{\cdot}d^{-1}$) at $30^{\circ}C$. $NH_3$ removal rate was increased as temperature increases from $15^{\circ}C$ to $35^{\circ}C$. The maximum removal rate was $285.8g-N{\cdot}m^{-3}{\cdot}h^{-1}$($18.8g-N{\cdot}kg^{-1}{\cdot}d^{-1}$) at $35^{\circ}C$. At $15^{\circ}C$, the $NH_3$ removal rate was $122.8g-N{\cdot}m^{-3}{\cdot}h^{-1}$($8.1g-N{\cdot}kg^{-1}{\cdot}d^{-1}$). When 210 ppm $NH_3$ was supplied to the biofilter at space velocity of $220h^{-1}$, the removal efficiency of $NH_3$ at 15, 25, 30 and $35^{\circ}C$ was 80, 90, 95, and 96%, respectively. The removal rate of the ceramic biofilter was 3 to 15 times higher than other biofilters comparing the removal efficiency of $NH_3$ per unit volume of carrier. This result indicates that earthworm casts and porous ceramics are very good inoculum source and carrier, respectively, for the $NH_3$-degrading biofilter.

• Animal Bioscience
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• v.35 no.7
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• pp.1100-1108
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• 2022

Objective: The objective of this study was to evaluate the effect of waste cooking oil (WCO) addition on ammonia (NH₃) emissions during the composting of dairy cattle manure under two aeration conditions. Methods: The composting tests were conducted using the laboratory-scale composting apparatuses (14 L of inner volume). Three composting treatments (Control, WCO1.5, and WCO3, with WCO added at 0 wt%, 1.5 wt%, and 3 wt% of manure, respectively) were performed in two composting tests: aeration rate during composting was changed from 0.55 to 0.45 L/min in Test 1, and fixed at 0.3 L/min in Test 2, respectively. The NH₃ emitted and nitrogen losses during the composting were analyzed, and the effect of the addition of WCO on NH₃ emissions were evaluated. Results: Both tests indicated that the composting mixture temperature increased while the weight and water content decreased with increasing WCO content of the composting mixtures. On the other hand, the NH₃ emissions and nitrogen loss trends observed during composting in Tests 1 and 2 were different from each other. In Test 1, NH₃ emissions and nitrogen losses during composting increased with increasing WCO contents of the composting samples. Conversely, in Test 2, they decreased as the WCO contents of the samples increased. Conclusion: The WCO addition showed different effect on NH₃ emissions during composting under two aeration conditions: the increase in WCO addition ratio increased the emissions under the higher aeration rate in Test 1, and it decreased the emissions under the lower aeration rate in Test 2. To obtain reduction of NH₃ emissions by adding WCO with the addition ratio ≤3 wt% of the manure, aeration should be considered.

• Korean Journal of Environmental Agriculture
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• v.32 no.4
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• pp.366-368
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• 2013

BACKGROUND: Composting is the most frequently used waste management process for animal manure in Korea's livestock industry. In the composting process, a large amount of nitrogen (N) is volatilized to the atmosphere as amonia ($NH_3$). However, quantitative information of $NH_3$ emission from composting of liquid manure is required to obtain emission factors for management of livestock manure in Korea. METHODS AND RESULTS: To evaluate the $NH_3$ emission from composting of liquid manure affected by aeration, we conducted composting of liquid pig manure with three forced aeration systems. The aeration conditions were continuous (A60), cycle of 30 min aeration and 30 min pause (A30S30) and without aeration(A0). All treatments were aerated 12 hour per day with these aeration systems. The total ratio of $NH_3$ volatilization loss to total N content in liquid manure throughout composting period was estimated to 19.9% for A0 treatment, 25.9% for A30S30 treatment and 36.3% for A60 treatment. The A30S30 and A60 aeration systems increased $NH_3$ volatilization by 30.2 and 82.3% compared with systems without forced aeration. CONCLUSION(S): Ammonia emission during liquid pig manure composting was highly affected by forced aeration. The development of liquid pig manure composting systems with forced aeration would be considered both reducing ammonia emission and efficiency of composting.

• Journal of Microbiology and Biotechnology
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• v.10 no.3
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• pp.419-422
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• 2000

A three-phase fluidized-bed bioreactor including Thiobacillus sp. IW was tested to remove H_2S and $NH_3$ simultaneously. The inlet $H_2S$ was oxidized to $SO_4^{2-}$ by Thiobacillus sp. IW, and the $NH_3$ reacted with the $SO_4^{2-}$ to form $(NH_4)_2SO_4$. The removal efficiency of $H_2S$ was 98.4-99.9% for an inlet concentration of 36-730 ppm and that of $NH_3$ was 60.2-99.2% for an inlet concentration of 45-412 ppm. The removal efficiency of $NH_3$ was reduced when the inlet loading rate of $NH_3$ was increased above 10 mg/l/h. When the bioreactor was operated for 25 days with a lower inlet concentration of $NH_3$ compared with the of $H_2S$, the bioreactor exhibited an excellent performance with a stable pH, dissolved oxygen content, and cell concentration.

• Journal of The Korean Society of Grassland and Forage Science
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• v.42 no.1
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• pp.47-53
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• 2022

The objective of this study was to verify the effect of pig slurry application with acidification and biochar on feed value, nitrogen use efficiency (NUE) of maize forage, and ammonia (NH₃) emission. The four treatments were applied: 1) non-pig slurry (only water as a control, C), 2) only pig slurry application (P), 3) acidified pig slurry application (AP), 4) acidified pig slurry application with biochar (APB). The pig slurry and biochar were applied at a rate of 150 kg N ha^-1 and 300 kg ha^-1, respectively. The AP and APB treatments enhanced all feed values compared to C and P treatments. The NUE for plant N was significantly increased 92.1% by AP and APB treatment, respectively, compared to the P treatment. On the other hand, feed values were not significantly different between AP and APB treatments. The acidification treatment with/without biochar significantly mitigated NH₃ emission compared to the P treatment. The cumulative NH₃ emission throughout the period of measurement decreased by 71.4% and 74.8% in the AP and APB treatments. Also, APB treatment reduced ammonia emission by 11.9% compared to AP treatment. The present study clearly showed that acidification and biochar can reduce ammonia emission from pig slurry application, and pig slurry application with acidification and biochar exhibited potential effects in feed value, NUE, and reducing N losses from pig slurry application through reduction of NH₃ emission.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.13 no.5
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• pp.451-457
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• 2000

Experimental investigations on the effect of two kinds of additives ; aqueous NaOH solution and ammonia(NH$_3$) for removal of NOx and SO$_2$ simultaneously by corona discharge were carried out. The simulated combustion flue gas was[NO(0.02[%])-SO$_2$(0.08[%])-$CO_2$-Air-$N_2$] Volume percentage of aqueous NaOH solution used was 20[%] and $N_2$flow rate was 2.5[$\ell$/min] for bubbling aqueous NaOH solution Ammonia gas(14.81[%]) balanced by argon was diluted by air. NH$_3$ molecular ratios(MR) based on [NH$_3$] and [NO+SO$_2$] were 1, 1.5 and 2.5 The vapour of aqueous NaOH solution and NH$_3$was introduced to the main simulated combustion flue gas duct through injection systems which were located at downstream of corona discharge reactor. NOx(NO+NO$_2$) removal rate by injecting the vapour of aqueous NaOH solution was much better than that by injecting NH$_3$however SO$_2$removal rate by injecting NH$_3$was much better than that by injecting the vapour of aqueous NaOH SO$_2$removal rate slightly increased with increasing applied voltage. When the vapour of aqueous NaOH solution and NH$_3$were simultaneously injection NOx and SO$_2$ removal rate were significantly increased.

• Korean Journal of Environmental Agriculture
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• v.28 no.4
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• pp.392-396
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• 2009

For the reduction of ammonia ($NH_3$) volatilization from the cow manure composting process, a cow manure pile was covered with vinyl (white polyethylene) and the ammonia emissions were evaluated using the dynamic chamber system for 47 days. Nitrogen and phosphorus loss from cow manure pile by rainfall was also measured in this study. In the cow manure pile without covering, the amount of $NH_3$ emission was 0.78 N kg/Mg which accounted for 9.4% of total nitrogen contents in the cow manure. Eighty nine percent of the total $NH_3$ emission during experimental period from the cow manure pile without covering was emitted for the first 21 days. The vinyl covering of cow manure pile reduced 91% of $NH_3$ emission compared to the pile without covering. The amounts of nitrogen and phosphorus loss by rainfall from cow manure pile without covering were 1.27 N kg/Mg and 0.23 P kg/Mg for 47 days, respectively. Results from this study demonstrated that vinyl covering of cow manure pile could reduce $NH_3$ emission and loss of nitrogen and phosphorus by rainfall during composting.

• Journal of the Korean earth science society
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• v.28 no.5
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• pp.572-584
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• 2007

The quantification of ammonia concentrations has received a lot of scientific attention. Numerous devices for the quantification of $NH_3$ in the ambient air have been developed to provide more technical possibilities for research in abating $NH_3$ emission from various source processes. For the proper quantification of $NH_3$, a number of sampling methods have been discussed by grouping them into different categories based on the principle of functioning. In general, active samplers employ pumps to draw air in, while passive samplers are exposed to air over a certain period of time to obtain integrated signature of $NH_3$. In case of the former, impingers and absorption flasks can be employed simultaneously with suitable absorbents to capture $NH_3$ passing through them. The methods of analysis include both in-situ and laboratory determination. In the laboratory, colorimetric or ion chromatographic methods are generally used for its quantification. In the field, a number of real time analyzers have been proven to be useful. These real time analyzers can be grouped according to their principle of operation. These analyzers may use the principle of spectroscopy (e.g. DOAS), photoacousticics (e.g. photoacoustic monitor) or Chemiluminescence ($NO_x$ analyzer). The automated annular denuder sampling system with on-line analyzer is also suitable for continuous monitoring of ammonia in air.

• Applied Chemistry for Engineering
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• v.28 no.3
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• pp.355-359
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• 2017

Zeolite X with Si/Al molar ratio = 1.08~1.20 was produced using a hydrothermal synthesis method. Ion-exchanged zeolite X samples were then prepared by using metal nitrate solutions containing $Mg^{2+}$ or $Cu^{2+}$. For all zeolite X samples, X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy dispersive spectrometry (EDS) were used to identify the change in crystal structure. The analysis of ammonia adsorption capability of zeolite X samples was conducted through the ammonia temperature-programmed desorption ($NH_3$-TPD) method. From XRD results, the prepared zeolite X samples maintained the Faujasite (FAU) structure regardless of cation contents in zeolite X, but the crystallinity of zeolite X containing $Mg^{2+}$ and $Cu^{2+}$ cations decreased. The distribution of cation contents in zeolite X was identified via EDS analysis. $NH_3$-TPD analysis showed that the $NH_3$ adsorption capacity of $Mg^{2+}$- and $Cu^{2+}$-zeolite X were 1.76 mmol/g and 2.35 mmol/g, respectively while the $Na^+$-zeolite X was 3.52 mmol/g ($NH_3/catalyst$). $Na^+$-zeolite X can thus be utilized as an adsorbent for the removal of ammonia in future.