• Title/Summary/Keyword: NH gas

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산란계의 Ceramics 급여 효과

  • 손장호
    • Proceedings of the Korea Society of Poultry Science Conference
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    • 2004.11a
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    • pp.103-104
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    • 2004
  • This study was evaluated the dietary affect of ceramics on laying performance, intestinal microflora population, NH$_3$ and VFA gas emission from excreta and fatty acids composition of egg yolk in laying hens. A total of 180 layer at 34 weeks of age were fed the experimental diets containing 0.0 % (Control), 0.4 % and 0.8 % of ceramics powder for 6 weeks. It is concluded that 0.4 % ceramics powder supplementation in the 34 to 40 weeks laying hens diet, improves the laying performance and ratio of egg yolk n-6/n-3 fatty acids contents and decreasing emission of NH$_3$ and VFA gas from excreta.

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Effect of Air Additions on the Growth Characteristics of the Compound Layer during Oxynitriding in50%NH3+Air+N2 Atmosphere (50% NH3-Air-N2가스분위기에서 Oxynitriding시 Compound Layer의 성장 특성에 미치는 공기첨가효과)

  • Kim, Y.H.;Lee, Y.S.
    • Journal of the Korean Society for Heat Treatment
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    • v.7 no.3
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    • pp.206-218
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    • 1994
  • In 50%$NH_3+Air+N_2$ atmospheres, the effect of air additions on the growth characteristics of the compound layer during oxynitriding at $570^{\circ}C$ for 2hr in carbon and alloy steels has been investigated. The ammount of apparent residual ammonia during oxynitriding has shown to be increased with air additions(9~36 Vol. %) and X-ray diffraction analysis of case oxynitreded has shown that the compound layer consist of ${\varepsilon}-Fe_{2-3}$(N, C) phase and ${\gamma}^{\prime}-Fe_4$(N,C) phase. In the case of carbon steels, the thickness of oxide layer, compound layer and porous layer and the amount of ${\varepsilon}-Fe_{2-3}$(N,C) phase in the compound layer were increased with additions of air in 50%$NH_3+N_2$ atmospheres. At the same gas composition, the thickenss of oxide layer, compound layer and porous layer in alloy steels showed slightly thin layer thickness compared to those of carbon steels and the ${\gamma}^{\prime}-Fe_4$(N,C) phase in the compound layer of alloy steels was found barely. Therefore, the most obvious effect of air addition in the gas nitriding atmosphere has been found to in crease further kinetics of nitriding reaction.

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Production of Single-Cell Protein on Petroleum Hydrocarbon -II. On the Growth of Candida tropicalis KIST 359- (석유탄화수소를 이용한 단세포단백질의 생산에 관한연구 -II. Candida tropialis KIST 359 에 대하여-)

  • Park, Yoong;Mheen, Tae-Ick;Pyun, Yoo-Ryang;Kwon, Tai-Wan
    • Korean Journal of Food Science and Technology
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    • v.2 no.2
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    • pp.61-67
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    • 1970
  • The growth characteristics of Candida tropicalis KIST 359, isolated from soil samples collected at an oil depot in Korea, have been studied by cultivating batches under varying conditions. The conclusions of the study were: 1. The yeast easily assimilates hydrocarbons in a range of $C_{14}-C_{17}$, and the optimum cultivation temperature and pH are $30^{\circ}C$ and 5.5, respectively. 2. Using this strain of micro-organism, gas oil gives a higher cell yield than kerosine and with gas oil except urea all other nitrogen sources $(NH_4NO_3,\;NH_4Cl,\;(NH_4)_2SO_4\;and\;(NH_4)_2HPO_4)$ similarly support a satisfactory growth of the yeast. 3. The highest yield is obtained with a gas oil level of 10%(v/v), and concentrations of nitrogen source and $MgSO_4{\cdot}7H_2O$ of 0.5 and 0.05%(w/v), respectively. 4. The protein content of dried yeast cells is 59.8%. Its amino acid composition can be compared well with that of FAO provisional patterns, but with a low methionine and a high lysine content.

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A Study on the Uniform Mixing of Ammonia-Air with the Change of Ammonia Supply Device Shape in a De-NOx System (탈질설비에서 암모니아 혼합기의 형상에 따른 암모니아-공기 균일 혼합에 관한 연구)

  • Ha, Ji Soo
    • Journal of the Korean Institute of Gas
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    • v.23 no.3
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    • pp.20-26
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    • 2019
  • Selective catalytic reduction(SCR) method is widely used among various methods for reducing nitrogen oxides in combustion devices of coal power plant. In the present study, the computational fluid dynamic analysis was accomplished to derive the optimal shape of ammonia-dilution air mixing device in a ammonia injection grid. The distribution characteristics of flow and $NH_3$ concentration had been elucidated for the reference shape of ammonia mixing device(Case 1). In the mixing device of Case 1, it could be seen that $NH_3$ distribution was shifted to the wall opposite to the inlet of the ammonia injection pipe. For the improvement of $NH_3$ distribution, the case(Case 2) with closing one upper injection hole and 4 side injection holes, the case(Case 3) with installing horizontal plate at the upper of ammonia injection pipe, the case(Case 4) with installing horizontal plate and horizontal arc plate at he upper of ammonia injection pipe were investigated by analyzing flow and $NH_3$ concentration distributions. From the present study, it was found that the % RMS of $NH_3$ for Case 4 was 4.92%, which was the smallest value among four cases, and the range of $R_{NH3}$ also has the optimally uniform distribution, -10.82~8.34%.

Alkylation of Isobutane with 1-Butene over Heteropoly Acid Catalysts (헤테로폴리산 촉매상에서 1-부텐에 의한 i-부탄의 알킬화반응)

  • Hong, Sung Hee;Lee, Wha Young;Song, In Kyu
    • Applied Chemistry for Engineering
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    • v.8 no.2
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    • pp.211-219
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    • 1997
  • Liquid or gas phase alkylation of isobutane with 1-butene for i-octane production was carried out over Cs- or $NH_4$-exchanged $H_3PW_{12}O_{40}$. Pretreatment temperature of the catalyst played an important role on the catalytic activity of heteropoly acids in the liquid phase alkylation. Cation-exchanged $H_3PW_{12}O_{40}$ showed a better total yield and i-octane selectivity than the mother acid in the liquid phase alkylation, and $(NH_4)_{2.5}H_{0.5}PW_{12}O_{40}$ was more efficient than $Cs_{2.5}H_{0.5}PW_{12}O_{40}$ in terms of i-octane selectivity. It was found that the acidic property (deactivation of acid sites) of the catalyst was closely related to the catalytic activity of Cs- or $NH_4$-exchanged $H_3PW_{12}O_{40}$ in the gas phase alkylation. $C_5-C_7$ were mainly formed in the early stage of gas phase alkylation due to the strong acidic property of the catalyst, whereas $C_8$ and $+C_9$ were mainly produced as the reaction proceeded due to the deactivation of acid sites. $Cs_{2.5}H_{0.5}PW_{12}O_{40}$ showed the highest total yield in the gas phase alkylation among the catalysts examined.

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A Study on the Atomic-Layer Deposition Mechanism and Characteristics of TiN Films Deposited by Cycle-CVD (Cycle-CVD법으로 증착된 TiN 박막의 ALD 증착기구와 특성에 관한 연구)

  • Min, Jae-Sik;Son, Young-Woong;Kang, Won-Gu;Kang, Sang-Won
    • Korean Journal of Materials Research
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    • v.8 no.5
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    • pp.377-382
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    • 1998
  • Atomic layer deposition(ALD) of amorphous TiN films on $SiO_2$ between 17$0^{\circ}C$ and 21O$^{\circ}C$ has been investigated by alternate supply of reactant sources, Ti[N($C_2,H_5,CH_3)_2]_4$ [tetrakis(ethylmethylamminoltitanium: TEMAT] and $NH_3$. Reactant sources were injected into the reactor in the order of TEMAT vapor pulse, Ar gas pulse, $NH_3$. gas pulse and Ar gas pulse. Film thickness per cycle was saturated at around 1.6 monolayer(MU per cycle with sufficient pulse times of reactant sources at 20$0^{\circ}C$. The results suggest that film thickness per cycle could be beyond 1 MLicycie in ALD, which were explained by rechemisorption mechanisms of reactant sources. The ideal linear relationship be¬tween number of cycles and film thickness is confirmed. As a results of surface limited reactions of ALD, step cover¬age was excellent. Particles caused by the gas phase reactions between TEMAT and NH3 were almost free because TEMAT was seperated from $NH_3$ by the Ar pulse. In spite of relatively low substrate temperature, carbon impurity was incorporated below 4 at%.

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Gas sensor based on hydrogenated multilayer graphene

  • Park, Seong-Jin;Park, Min-Ji;Yu, Gyeong-Hwa
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.273.1-273.1
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    • 2016
  • Graphene exhibits a number of unique properties that make it an intriguing candidate for use in sensor. Here, we report graphene-based gas sensor. Graphene was grown using CVD. Then, the sensor was made using standard lithography techniques. The sensor conductance increased upon exposure to NH3, whereas it decreased upon NO2, suggesting that NH3 and NO2 might be discriminated using the graphene-based sensor. To improve the sensitivity, graphene was treated with hydrogen plasma. After hydrogen treatment, the electrical properties of graphene changed from ambipolar to p-type semiconductors. In addition, the sensor performance was improved probably due to an opening of bandgap.

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A Study on Hydraulic Behavior and Mass Transfer by Absorption in Packing Tower (충전탑에서 흡수에 따른 물질전달과 수력학적 거동에 관한 연구)

  • 김석택
    • Journal of Environmental Science International
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    • v.9 no.5
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    • pp.393-396
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    • 2000
  • Packing tower has been used in the chemical industry and the protection of environment for a long time. In the view of environmental protection purification of exhaust gas can be performance effective by gas absorption in counter-current packing tower. In this study characteristics of hydraulic and mass transfer were investigated in D. $0.3m {\times} H. 1.4m$ packing tower with 50mn plastic Hiflow-ring. This study was carried out "Test systems were experimented in conditions of Air, $Air/H_2O. NH_3-Air/H_2O, NH_3-Air/H_2O-H_2SO_4$ and $SO_2-Air/H_2O-NaOH$ under steady state" The extent of test included dry and wetting pressure drop physical law separation efficiency and hold-up as function of gas and liquid load.quid load.

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A Study of NOx Removal in Flue Gas by Selective Catalytic Reduction (선택적 촉매환원법에 의한 배기가스중 NOx 저감에 관한 연구)

  • 박해경;김경림;최병선;이인철;최익수
    • Journal of Korean Society for Atmospheric Environment
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    • v.4 no.2
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    • pp.38-46
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    • 1988
  • NOx is an important air pollution material which is generated when fossil fuels are burning, NOx removal in flue gas by selective catalytic reduction was studied over various catalysts in a fixed bed continuous flow reactor. The ranges of experimental conditions were at the temperatures between $200^\circ$C and $350^\circ$C, the $NH_3/NOx$ mole ratios between 0.8 and 1.4, oxygen concentrations between 1.5% and 3% and the space velocities between 5, 000 $hr^-1$ and 12, 500 $hr^-1$. The efficiency of NOx removal in the ranges of experimental conditions was highest at the temp. of 300$^\circ$C, oxygen concentration of 2.5-2.6% and $NH_3/NOx$ mole ratios of 1.0-1.2. The catalyst with high activity for NOx removal in flue gas was found to be $MoO_3-V_2O_5/TiO_2$.

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Study of Methane Storage through Structure Transition of Gas Hydrate (가스하이드레이트 구조 변형을 통한 메탄 저장에 관한 연구)

  • Lee, Ju-Dong;Lee, Man-Sig;Kim, Young-Seok
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.54-57
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    • 2006
  • Structure H formation experiments were conducted in a semi-batch stirred vessel using methane as the small guest substance and neohexane(NH), tert-butylmethylether(TBME) and methylcyclohexane(MCH) as the large molecule guest substance (LMGS). The results indicate that the rates of gas uptake and induction times are generally dependent on the magnitude of the driving force. When tert-butyl methyl ether is used as the LMGS rapid hydrate formation, much smaller induct ion time and rapid decomposition can be achieved. Liquid-liquid equilibrium (LLE) data for the above LMGS with water have been measured under atmospheric pressure at 275.5, 283.15K, and 298.15K. It was found that TBME is the most water soluble followed by NM and MCH. The solubility of water in the non-aqueous liquid was found to increase in the following order: MCH

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