• Title/Summary/Keyword: ND4

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Nd1+XBa2-XCu3O7-δ Bulk Superconductor by Zone-melt Process

  • Soh, Dea-Wha;Guo, Fan-Zhan
    • Transactions on Electrical and Electronic Materials
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    • v.3 no.3
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    • pp.21-24
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    • 2002
  • Two kinds of $Nd_{1+X}Ba_{2-X}Cu_3O_{7-{\delta}}$, the sintering samples and zone melting samples, were heat-treated under pure Ar at 950$^{circ}C$. The substitution of Nd ion for Ba ion in the $Nd_{1+X}Ba_{2-X}Cu_3O_{7-{\delta}}$ before and after the heat treatment was investigated by XRD. In order to confirm the effects of the heat treatment, the Tc and Jc of samples with/without the heat treatment under Ar were comparatively studied. $Nd_{1+X}Ba_{2-X}Cu_3O_{7-{\delta}}$ samples were oxygenated under pure oxygen at $300^{circ}C$. From the XRD pattern it was found that the sample with x<0.4 was transferred from tetragonal phase to orthorhombic phase after the oxygenation, while the sample with x>0.4 did not show the phase transition even after a long time oxygenation. Therefore, the low oxygen partial pressure (Ar+1 % O$_2$) was used for the ambient atmosphere of the zone-melting samples, which could reduce the melting temperature and depress the substitution of Nd for Ba. After the improvement in the zone-melting process, the Jc value was increased to 2 x $10^4$A/$cm^2$ (0 T, 78 K). The particle orientation and the structure of zone-melted NdBaCuO were studied by the XRD and SEM analysis.

An Effect of the 2nd Land Length of a Piston on Thermal Stress (피스톤의 제2랜드 길이가 열응력에 미치는 영향)

  • Kwon, Y.W.;Park, S.C.
    • Journal of Power System Engineering
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    • v.12 no.2
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    • pp.5-11
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    • 2008
  • An analytical study was performed to have temperature and thermal stress distribution on a piston with the change of the 2nd land length of a piston and the existence of knocking in a cylinder. The result showed that the temperature on the skirt region was about $4\sim10^{\circ}C$ higher than that on the pin region. However the thermal stress on the skirt region was about 4MPa lower than on the pin region. It may be due to the higher heat release rate on the pin boss than on the skirt. The result regarding the variation of the 2nd land length of the piston showed that the temperature distribution on the piston was getting lower and the thermal stress distribution was getting higher as the 2nd land length of the piston was shorter.

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The Effects of Co-substitution on the Magnetic Properties of Nanocrystalline Nd-Fe-B based Alloy Containing α-Fe as Main Phase (Co 치환이 α-Fe기 초미세결정립 Nd-Fe-B계 합금의 자기특성에 미치는 영향)

  • Cho, D.H.;Cho, Y.S.
    • Journal of the Korean Magnetics Society
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    • v.12 no.1
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    • pp.30-33
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    • 2002
  • The Effects of Co-substitution in the nanocrystalline Nd-Fe-B-Mo-Cu alloys were investigated. $\alpha$-Fe based nanocrystalline Nd-Fe-B-Mo-Cu alloys were prepared by crystallization process of amorphous Nd-Fe-B-Mo-Cu alloy produced by rapid solidification process. The substitution of Co resulted in the decrease of grain size and improves the hard magnetic properties. The remanence, coercivity, and Curie temperature of nanocrystalline N $d_4$(F $e_{0.85}$ $Co_{0.15}$)$_{82}$ $B_{10}$M $o_3$Cu alloy showed more improved magnetic properties than those of Co-free alloy. The grain size was measured to be about 15 nm. The coercivity, remanence and maximum energy product were 239 kA/m, 1.41, and 103.5 kJ/ $m^3$, respectively, for the nanocrystalline N $d_4$(F $e_{0.85}$ $Co_{0.15}$)$_{82}$ $B_{10}$M $o_3$Cu alloy annealed for 0.6 ks at 640 $^{\circ}C$.

Synthesis, Structure and Characterization of Nd2XCd2-3XSiO4 (0.01≤X≤0.21) Solid-Solutions (Nd2XCd2-3XSiO4 (0.01≤X≤0.21) 고용체의 합성과 구조 규명)

  • Ramesh, S.;Das, B.B.
    • Journal of the Korean Chemical Society
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    • v.55 no.3
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    • pp.502-508
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    • 2011
  • Synthesis of $Nd_{2x}Cd_{2-3x}SiO_4$ ($0.01{\leq}x{\leq}0.21$) [S1-S3: x=0.01, 0.11 and 0.21] solid solutions were prepared by solgel method. Powder x-ray diffraction (XRD) results show monoclinic unit cell with space group P21/m. The average crystallite sizes are found to be 20 to 45 nm. The Scanning Electron Microcopy (SEM) images show morphology of the sample is in globular nature. The energy dispersive analysis of x-rays (EDX) and X-ray mapping results confirmed that all the constituent elements of the composites were present and that were distributed in uniformly. The optical absorption band at ~750 nm was due to $^4I_{9/2}{\rightarrow}^4F_{7/2}+^4S_{3/2}$ transition optically active $Nd^{3+}$ ions. Electron Paramagnetic Resonance (EPR) lineshapes of S1-S3 at 10, 40, 77 and 300 K show a broad unresolved isotropic lineshapes were observed due to rapid spin lattice relaxation of $Nd^{3+}$.

Oxidation Behavior and Magnetic Properties of Nd-Fe-B Based Melt-Spun Ribbons (Nd-Fe-B계 급냉리본의 산화거동과 자기적 특성)

  • Jo, Beom-Rae;Kim, Jin-Gu;Song, Jin-Tae;Gang, Gi-Won
    • Korean Journal of Materials Research
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    • v.5 no.4
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    • pp.483-489
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    • 1995
  • Nd-(Fe, Co)-B합금에 Ni, Al, Ti등을 복합치환하여 그에 따른 산화거동과 자기적 성질의 변화를 조사하였다. 이들 리본의 산호거동은 parabolic한 거동을 나타내고 있으며, Ni 첨가시 매우 낮은 산화량을 나타내었다. 또한 산화된 리본은 Nd-rich상의 우선적 산화에 의해 표면에 요철이 관찰되었으며 Ni 첨가시 그러한 요철은 많이 줄어들었다. 표면의 산화층은 Nd산화물이었고, 이는 입계에 있는 Nd-rich상이 산화되고 이것이 확산 통로로 작용하였다고 생각된다. 산화가 진행됨에 따라 입계상에 의한 domain wall pinning이 약해져 자기특성이 저하하였다. 그러나 Ni 첨가시 이러한 산화거동이 크게 억제되었으며 Ni의 첨가는 Nd-rich상의 산화저항성을 증가시킴으로써 리본의 산화를 억제해 자기특성의 저하를 억제하였다.

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CW Operation of LD-pumped Nd -YLF Laser- (레이저 다이오드로 펌핑되는 Nd:YLF 레이저의 발진 특성)

  • 강응철
    • Korean Journal of Optics and Photonics
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    • v.4 no.3
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    • pp.289-293
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    • 1993
  • A Nd:YLF laser pumped by a CW GaAlAs laser diode(LD) at 792 nm has been designed and fabricated. The output power was investigated as a function of LD spectrum and pump power. A folded laser resonator was desinged to compensate for the astigmatism produced at the Brewster surface of Nd:YLF rod. We obtained output power of CW 1.1 Watt when the pumping power was 2.8 Watt and the output wavelength of LD was temperature tuned to the peak absorption line of Nd:YLF. The overall efficiency was 39 % and slope efficiency was 41 %.

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Observations of Exchange Coupling in Nd2Fe14B/Fe/Nd2Fe14B Sandwich Structures and Their Magnetic Properties

  • Yang, Choong-Jin;Kim, Sang-Won
    • Journal of Magnetics
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    • v.4 no.2
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    • pp.39-45
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    • 1999
  • Sandwich structures of$ Nd_2Fe_{14}B/Fe/Nd_2Fe_{14}B $magnetic films have been grown by a KrF excimer laser (λ=248 nm) ablation technique. Magnetic properties were characterized by varying the thickness of hard ($Nd_2Fe_{14}B$) and soft (Fe) magnetic films and the volume fraction as well. In the (x)nm[NdFeB]/(y)nm[Fe]/(x)nm[NdFeB]/(100) Si structure the thickness (x) was varied from 3.6 to 54 nm, and (y) from 15 to 112 nm. At (y) = 15~20 nm where the volume fraction of Fe corresponded to 61~75%, the sandwich structure exhibited an enhanced Mr/Ms and iHc as well from the result of the exchange coupling between the magnetic layers. Experimentally calculated exchange constant$ (A_s) of A_s = 2.5{\times}10^{-10} J/m$ was estimated using the intrinsic coercivity (iHc) of 1.2 kOe at 5 K for the sandwich magnetic trilayers.

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Optical Properties of PbS Quantum Dots (QDs) Precipitated in Nd3+-Containing Glasses

  • Park, Won Ji;Heo, Jong
    • Journal of the Korean Ceramic Society
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    • v.52 no.2
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    • pp.146-149
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    • 2015
  • Silicate glasses with different $Nd_2O_3$ concentrations were prepared through conventional melt-quenching methods while PbS quantum dots (QDs) were precipitated through heat treatment. The peak wavelengths of absorption and the photoluminescence of PbS QDs shifted to the short-wavelength side as the concentration of $Nd_2O_3$ increased. The electron energy loss spectroscopy (EELS) indicated that $Nd^{3+}$ ions were preferentially distributed inside the PbS QDs instead of the glass matrix. In addition, there was no significant change in the lifetimes of the $Nd^{3+}:^4F_{3/2}$ fluorescence between the as-prepared glass ($607{\mu}s$) and the heat-treated glass($576{\mu}s$). $Nd^{3+}$ ions were surrounded by oxygen instead of sulfur and the Nd-O clusters probably acted as nucleating centers for the formation of PbS QDs inside the glasses.

EFFECT OF TEMPERATURE ON THE PLASTIC DEFORMABILITY OF GAS ATOMIZED NdFeB ANISOTROPIC MAGNETS

  • JU-YOUNG CHO;YONG-HO-CHOA;SUN-WOO-NAM;RASHEED MOHAMMAD ZARAR;TAEK-SOO KIM
    • Archives of Metallurgy and Materials
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    • v.65 no.4
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    • pp.1293-1296
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    • 2020
  • NdFeB anisotropic sintered permanent magnets are typically fabricated by strip casting or melt spinning. In this study, the plastic deformability of an NdFeB alloy was investigated to study the possibility of fabricating anisotropic sintered magnets using gas atomized powders. The results show that the stoichiometric composition Nd12Fe82B6 softens at high temperatures. The aspect ratio and orientation factor of Nd12Fe82B6 billets after plastic deformation were found to increase with increasing plastic deformation temperature, particularly above 800℃. This confirms that softening at high temperatures can lead to plastic deformation of Nd2Fe14B hard magnetic phases.