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A Distinctive Chemical Composition of the Tektites from Thailand and Vietnam, and Its Geochemical Significance (타이와 베트남에서 수집된 텍타이트의 화학조성과 지구화학적 의의)

  • Lee, Seung-Gu;Tanaka, Tsuyoshi;Asahara, Yoshihiro;Minami, Masayo
    • The Journal of the Petrological Society of Korea
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    • v.26 no.3
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    • pp.281-295
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    • 2017
  • We determined chemical compositions like abundance of major and trace elements, Sr and Nd isotope compositions for two tektites from the Thailand and Vietnam. Their chemical compositions are similar to each other, and seem to be similar to those of PAAS (Post Archean Australian Shale) rather than upper continental crust. In particular, primitive mantle-normalized spider diagrams and chondrite-normalized REE patterns for two tektites are the same, suggesting that they might be derived from the same source material. The $^{87}Sr/^{86}Sr$ and $^{143}Nd/^{144}Nd$ ratios from Thailand tektite are $0.718870{\pm}0.000008(2{\sigma}_m)$ and $0.512024{\pm}0.000012(2{\sigma}_m)$, respectively, and those from Vietnam are $0.717022{\pm}0.000008(2{\sigma}_m)$ and $0.511986{\pm}0.000013(2{\sigma}_m)$, respectively. The $^{87}Sr/^{86}Sr$ and $^{143}Nd/^{144}Nd$ ratios from Thailand tektite are slightly enriched than those of Vietnam tektite. $^{87}Sr/^{86}Sr$ ratios from the Vietnam and Thai tektites were plotted on the range of Australasian tektites reported previously. $^{143}Nd/^{144}Nd$ ratio of Vietnam tektite from this study was lower than the range of $^{143}Nd/^{144}Nd$ ratio from the Australasian tektite reported previously whereas that of Thai tektite was included in the range of $^{143}Nd/^{144}Nd$ ratio from the Australasian tektite. The geochemical characteristics from two tektites in this study indicate that they may be derived from the very similar source materials.

Microstructure and Electrical Properties of $Pr_6$$O_{11}$-Based ZnO Varistors Doped with $Nd_24$O_3$ ($Nd_24$O_3$가 첨가된 $Pr_6$$O_{11}$계 ZnO 바리스터의 미세구조 및 전기적 성질)

  • 남춘우;박춘현;윤한수
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.3
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    • pp.206-213
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    • 2000
  • The microstructure and electrical properties of Pr$_{6}$/O sub 11/-Based ZnO varistors with Nd$_2$O$_3$ was doped in the range of 0.0 to 2.0 mol% were investigated. Most of the added Nd$_2$O$_3$were segregated at the nodal points and grain boundaries and were found to form the Nd-rich phase. In addition the bulk intergranular layer at the grain boundaries and nodal points was consisted of Nd-rich phase and Pr-rich phase. the average grain size was decreased in the range of 7.8 to 5.6${\mu}{\textrm}{m}$ with increasing Nd$_{2}$/O sub 3/ additive content. The nonlinearity of ZnO varistors sintered at 130$0^{\circ}C$ was much more excellent than that at 135$0^{\circ}C$ ZnO varistors doped with 1.0mol% Nd$_{2}$/O sub 3/ exhibited the best nonlinearity. which is 65.2 in the nonlinear exponent and 4.5$\mu$A in the leakage current. Consequently. it is estimated that Pr$_{6}$/O sub 11/ -based ZnO varistors doped with 1.0 mol% Nd$_{2}$/O sub 3/ are to be sufficiently used as basic composition to fabricate good varistors in the future.ure.

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Influence on Dielectric Properties and Evaporation of PbO According to Substituting $Nd^{3+}$ for $Pb^{2+}$ in $Pb(Mg_{1/3}Nb_{2/3})O_3$ System ($Pb(Mg_{1/3}Nb_{2/3})O_3$계 세라믹스의 $Pb^{2+}$$Nd^{3+}$로 치환함에 따른 유전특성 및 PbO 휘발에 관한 연구)

  • 김성열;이응상
    • Journal of the Korean Ceramic Society
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    • v.30 no.3
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    • pp.175-180
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    • 1993
  • Influence of Nd3+ substitution for Pb2+ on the dielectric properties and the PbO evaporation according to substituting Nd3+ for Pb2+ in Pb(Mg1/3Nb2/3)O3 system ceramics have been investigated. The dielectric constant at the curie temperature and evaporation of PbO were decreased with increase of Nd3+ amounts. The percentage of PbO evaporation was 2.5wt% in the PMN system substituted Nd3+ for Pb2+, while it was 3.7wt% in the PMN system.

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Microwave Dielectric Properties of $CaTiO_3-(Li_{1/2}Nd_{1/2})TiO_3$ ceramics ($CaTiO_3-(Li_{1/2}Nd_{1/2})TiO_3$계 세라믹스의 마이크로파 유전특성)

  • Yoon, Jung-Rag;Heo, Young-Kyu;Lee, Heon-Yong
    • Proceedings of the KIEE Conference
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    • 1997.07d
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    • pp.1459-1461
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    • 1997
  • The microwave dielectric ceramic properties of $CaTiO_3-(Li_{1/2}Nd_{1/2})TiO_3$ were investigated. The solid solution of $CaTiO_3-(Li_{1/2}Nd_{1/2})TiO_3$ had the perovskite structure in the range of all composition. The dielectric constant and temperature coefficient of resonant frequency of solid solution were decreased with the contend of $(Li_{1/2}Nd_{1/2})TiO_3$, whereas, the $Q{\times}f$ value was increased. In the $(1-X)CaTiO_3-X(Li_{1/2}Nd_{1/2})TiO_3$ system, the microwave properties could be controlled by the variation of X, X is weight fraction. Typical value of K=119, $Q{\times}f=2970$ and $TCF=14ppm/^{\circ}C$ were obtained for $0.2CaTiO_3-0.8(Li_{1/2}Nd_{1/2})TiO_3$.

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Magnetic Properties of ${\alpha}-Fe$ Based Nd-Fe-B Melt-Spun Alloys (${\alpha}-Fe$ 기 Nd-Fe-B 급속응고합금의 자기특성)

  • 조용수;김윤배;박우식;김희태;김창석;김택기
    • Journal of the Korean Magnetics Society
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    • v.4 no.2
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    • pp.122-125
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    • 1994
  • The magnetic properties of Nd-Fe-B alloys of containing 4 at.% Nd have been studied for the development of new type rare-earth magnets. The amorphous phase of a melt-spun $Nd_{4}Fe_{85.5}B_{10.5}$ alloy is transformed into the phases which have a small amount of $Nd_{2}Fe_{14}B_{1}$ in ${\alpha}-Fe$ matrix by annealing above their crystallization temperature. The addition of Mo, Nb, V or Cu to $Nd_{4}Fe_{85.5}B_{10.5}$ alloy results in the reduction of grain size and the sub¬sequent improvement of the coercivity. The coercivity of $Nd_{4}Fe_{82}B_{10}M_{3}Cu_{1}$(M = Mo, Nb, V) alloys increases in the order of M = V < Nb < Mo and shows the highest value of 2.7 kOe when M = Mo. On the other hand, the rem¬anence of these alloys shows the opposite trend and the rn>st improved value of 1.35 T is observed when M = V.

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Properties of Glass-Ceramic in ${Nd_2}{O_3}-{Al_2}{O_3}-{SiO_2}$System (${Nd_2}{O_3}-{Al_2}{O_3}-{SiO_2}$ 계의 결정화유리의 물성)

  • Choi, Woo-Hyeong;Kim, Hyeong-Sun
    • Korean Journal of Materials Research
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    • v.11 no.7
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    • pp.545-549
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    • 2001
  • Glass-ceramics were prepared and evaluated for the properties to expand the scope of application of the rare earth aluminosilicate glasses, A glass-ceramic added with $TiO_2$as a nucleating agent, which was crystallized internally and it was characterized for physical, thermal and mechanical properties of crystal and residual glass in the glass-ceramic, X-ray diffractometer reveals an unknown crystal as $Nd_{4.6}Si_{7.6}Al_{4.0}Ti_{2.4}O_{32}$ which was found in surface and internal crystals dependent on composition and heat treatments. The thermal expansion coefficients of glass-ceramics were $5.4~6.2{\times}10^{-6}/^{\circ}C$, which increased with increasing crystal growth. Considering that the hardness and the elastic constant of crystal in glass-ceramics are 12GPa and 220GPa, respectively, the application of the glass-ceramics would be applicable for structural materials at elevated temperature.

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Magnetic Propertes of $Nd_{x}{(Fe_{0.9}Co_{0.1})}_{90-x}B_{6}Nb_{3}Cu_{1}(x=\;3,\;4,\;5)$ Nanocrystalline Alloys ($Nd_{x}{(Fe_{0.9}Co_{0.1})}_{90-x}B_{6}Nb_{3}Cu_{1}(x=\;3,\;4,\;5)$ 초미세결정립합금의 자기특성)

  • 조용수;김만중;천정남;김택기;박우식;김윤배
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.880-894
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    • 1995
  • Magnetic properties of $Nd_{x}{(Fe_{0.9}Co_{0.1})}_{90-x}B_{6}Nb_{3}Cu_{1}(x=\;3,\;4,\;5)$ rrelt-spun alloys with 6 at% B content were studied aiming for finding out a new $\alpha$-Fe based Nd-Fe-B nanocrystalline alloy with good hard magnetic properties. $Nd_{x}{(Fe_{0.9}Co_{0.1})}_{90-x}B_{6}Nb_{3}Cu_{1}$ melt-spun alloys prepared by RSP crystallized to nanocrystalline phase. An optimally annealed $Nd_{3}{(Fe_{0.9}Co_{0.1})}_{87}B_{6}Nb_{3}Cu_{1}$ melt-spun alloys had larger volume ratio of $\alpha$-Fe(Co) than that of higher Nd content alloy and showed high remanence of about 1.6 T. On the contrary, the increase of Nd content in $Nd_{x}{(Fe_{0.9}Co_{0.1})}_{90-x}B_{6}Nb_{3}Cu_{1}$ alloys gave rise to gradual increase of an amount of $Nd_{2}{(Fe,\;Co)}_{14}B$ phase and improved coercivity. An optimally annealed $Nd_{5}{(Fe_{0.9}Co_{0.1})}_{85}B_{6}Nb_{3}Cu_{1}$ alloy showed the most improved hard mag¬netic properties. The remanence, coercivityand energy product of the alloy were 1.35 T, 219 kA/m (2.75 kOe), and $129\;kJ/m^{3}$ (16.2 MGOe), respectively.

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A New Method to Determine the Spin Rorientation Angle of Cone Anisotropy from Polcrystalline Magnetization Curves: Anisotropy from Polycrystalline Magnetization Curves Application to $Nd_2Fe_{14}B$ (다결정 자화곡선을 이용한 콘이방성물질의 스핀재배열각 결정법 : $Nd_2Fe_{14}B$에의 적용)

  • ;Jin Han-min
    • Journal of the Korean Magnetics Society
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    • v.8 no.3
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    • pp.144-149
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    • 1998
  • A new method to calculate the spin reorientation angle of cone anisotropy from magnetization curves of magnetically aligned powder is suggested. The spin reorientation angle of polycrystalline $Nd_2Fe_{14}B$ determined by this method coincided with the results obtained from torque magnetometry or magnetization measurements on single crystal. The underestimation of about 9% is expected if the basal plane anisotropy is neglected in determination of the spin reorientation angle of $Nd_2Fe_{14}B$ at 4.2 K.

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Occurrence of UV Filters in Nakdong River Basin : Mainstreams, Tributaries and STP Effluents (낙동강 수계에서의 자외선 차단제류 검출 특성 : 본류, 지류 및 하수처리장 방류수)

  • Seo, Chang-Dong;Son, Hee-Jong;Choi, Jin-Taek;Yoo, Pyung-Jong;Jang, Seong-Ho
    • Journal of Korean Society of Environmental Engineers
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    • v.37 no.8
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    • pp.472-479
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    • 2015
  • This study was investigated occurrence and distribution patterns of UV filters in Nakdong River basin (mainstream, tributaries and sewage treatment plant (STP) effluents). 5 (EHS, BP-3, 4-MBC, BZC and EHMC) out of 7 UV filters were detected in 5 out of 20 sampling sites (mainstream and tributaries), 7 UV filters were not detected in mainstream samples, and the EHS, BP-3, 4-MBC, BZC and EHMC concentration levels in tributary samples were ND~60.8 ng/L, ND~72.1 ng/L, ND~57.2 ng/L, ND~60.1 ng/L and ND~85.2 ng/L, respectively. 5 (EHS, BP-3, 4-MBC, BZC and EHMC) out of 7 UV filters were detected in effluents of 11 STPs around the Nakdong River basin. The EHS, BP-3, 4-MBC, BZC and EHMC concentration levels in 11 STP effluents were ND~89.3 ng/L, ND~90.8 ng/L, ND~88.1 ng/L, ND~118.5 ng/L and ND~104.4 ng/L, respectively. According to the sampling season, distribution patterns and detected concentrations of 5 UV filters were similar in June and September 2014, but change ranges of distribution patterns and detected concentrations of 5 UV filters were highly variable in April and November 2014.