• 한국윤활학회:학술대회논문집
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• 한국윤활학회 1999년도 제29회 춘계학술대회
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• pp.119-126
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• 1999

The rolling fatigue lives (RFL) of five kinds of silicon nitride balls were investigated. Four kinds of Si$_3$N$_4$ balls were fabricated using different raw materials, sintering aids and sintering conditions, Commercially available Si3N4 ball was also studied for comparison. All the balls were finished up to the dimensional accuracy of Grade 10 defined in KS B 2001 (Steel Balls for Ball Bearings) with a size of 9.525mm. RFL tests were then conducted under the initial theoretical maximum contact stress 6.38 GPa and the spindle speed 10,000 rpm. Gear oil was provided by oiled race as lubricant. The results of RFL test indicated the prerequisitic conditions for the long rolling life of Si$_3$N$_4$ball : (1) the high density, (2) mjcrostructures consisted of small uniformly distributed grains, (3) little glassy phase in grainboundary, and (4) little crystalline phase and secondary phase that induces residual thermal stress due to the differences of thermal expansion coefficient with Si$_3$N$_4$Phase.

• Tribology and Lubricants
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• 제15권2호
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• pp.150-155
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• 1999

The rolling fatigue lives (RFL) of five kinds of silicon nitride balls were investigated. Four kinds of Si$_3$N$_4$balls were fabricated using different raw materials, sintering aids and sintering conditions. Commercially available Si$_3$N$_4$ball was also studied for comparison. All the balls were finished up to the dimensional accuracy of Grade 10 defined in KS B 2001 (Steel Balls fer Ball Bearings) with a size of 9.525 mm. RFL tests were then conducted under the initial theoretical maximum contact stress 6.38 GPa and the spindle speed 10,000 rpm. Gear oil was provided by oiled race as lubricant. The results of RFL test indicated the prerequisitic conditions for the long rolling life of Si$_3$N$_4$ball : (1) the high density, (2) microstructures consisted of small uniformly distributed grains, (3) little glassy phase in grainboundary, and (4) little crystalline phase and secondary phase that induces residual thermal stress due to the differences of thermal expansion coefficient with Si$_3$N$_4$phase.

• KEPCO Journal on Electric Power and Energy
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• 제3권1호
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• pp.29-34
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• 2017

Leaching kinetics for extracting yttrium from the coal fly ash was investigated in the presence of sulfuric acid during extraction. The leaching kinetics of yttrium were conducted at reactant densities of 5~1,000 g coal fly ash per L of $1.0{\sim}10.0N\;H_2SO_4$, agitation speed of 250 rpm and temperature ranging from 30 to $90^{\circ}C$. As a result, the leaching kinetic model was determined in a two-step model based on the shrinking core model with spherical particles. The first step was proceeded by chemical reaction at ash surface, and the second step was proceeded by ash layer diffusion because the leaching conversion of yttrium by the first chemical reaction increases with increased the time irrelevant to the temperature whereas it increases with increased the leaching temperature. The activation energy of the first chemical leaching step was determined to be $1.163kJmol^{-1}$. After the first chemical reaction, the activation energy of ash layer diffusion leaching was derived to be $41.540kJmol^{-1}$. The optimum conditions for leaching the yttrium metal of 60 % were found to be the slurry density of 250 g fly ash per L of $H_2SO_4$, solvent concentration of $2.0N\;H_2SO_4$, second step leaching of temperatures of $30^{\circ}C$ for 3 hours and then $90^{\circ}C$ for 3 hours at agitation rate of 250 rpm.

• 한국식품영양학회지
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• 제26권3호
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• pp.547-552
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• 2013

황백 껍질은 황벽나무(Phellodendron amurense)의 건조된 수피로부터 얻어진다. 이 수피는 한국의 전통 한약제로서, 설사, 황달, 무릎과 발의 통증, 요도관 및 피부 감염증에 폭넓게 사용되어 왔다. 본 연구는 황벽나무의 메탄올 추출액으로부터 항균성 화합물 분리를 위해 CPC 방법으로 효과적으로 수행하였다. 두 용매의 CPC 최적조성은 n-butanol:acetic acid:water(4:1:5 v/v/v)이었다. 이동상의 유속은 1,000 rpm 회전력에서 상승법으로 분당 3 $m{\ell}$ 속도로 전개시켰다. CPC에서 분리된 분획분은 prep-HPLC로 정제하였다. 분리된 palmatine은 $^1H$, $^{13}C$-NMR, ESI-MS 데이터 분석으로 확인하였다.

• 센서학회지
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• 제2권1호
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• pp.35-40
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• 1993

$Si_{3}N_{4}$ 박막의 코팅된 pH-ISFET의 게이트 부위 위에 lipase 효소를 고정화하여 FET(field effect transistor) 형지질(lipid) 센서를 제조하였다. 효소 고정화막 형성 물질로는 수용성 고분자인 polyvinyl alcohol(PVA)에 감광성기인 1-methyl-4-(formylstyryl) pyridinium methosulfate(SbQ)를 결합시킨 PVA-SbQ를 사용하였다. PVA-SbQ 수용액 (SbQ 1mole %, 10 wt%) $200{\mu}L$, bovine serum albumin (BSA) 7.5 mg, lipase 10 mg으로 구성 된 현탁액을 사용한 사진식각(photolithographic) 공정의 최적 조건은 피막의 상온 진공 건조 시간 45분, spin coater의 회전수 $5,000{\sim}6,000$ rpm, UV 노광시간 $20{\sim}30$초, 증류수 현상 시간 $30{\sim}40$초로 나타났다. 이렇게 구성된 지질 센서는 triacetin을 지질 시료로 하였을 때 $10{\sim}100$ mM의 농도 범위에서 직선성의 검정선을 나타내었다.

• International Journal of Advanced Culture Technology
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• 제3권1호
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• pp.145-152
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• 2015

The article aims to apply a friction stir spot welding for producing the lap joint between AA5052 aluminum alloy and C11000 copper alloy. The dimension of the materials was 100 mm in length, 30 mm in width and 1.0 mm in thickness. The copper plate was set overlap the aluminum plate by 30 mm. The welding parameter was the rotating speed of 2500-4000 rpm, the pin inserting rate of 2-8 mm/min and the holding time of 6 sec. The mechanical properties test and the microstructure investigation were performed to evaluate the lap joint quality. The summarized results are as follows. The friction stir spot welding could produce effectively the lap joint between AA5052 and C11000 copper. Increase of the rotating speed and holding time directly affected to decrease the tensile shear strength of the lap joint. The optimized welding parameters in this study that indicated the tensile shear strength of 864 N was the rotating speed of 3500 rpm, the pin inserting rate of 6 mm/min and the holding time of 4sec. The experimental results also showed that the hardness of the weld metal was lower than that of the base materials.

• 한국공작기계학회논문집
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• 제17권5호
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• pp.36-43
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• 2008

This research is tendencious to manufacture solid piston-rod of shock absorber as hollow piston-rod using friction welding. The SM45C has been welded to the SM45C-pipe in order to investigate the effect of upset pressure on friction weldability. The friction time and upset pressure was variable conditions under the conditions of spindle revolution of 2,000rpm, friction pressure of 55MPa, and upset time of 2.0seconds. Under these conditions, the microstructure of weld interface, tensile fracture surface and mechanical tests were studied of friction weld, and so the results were as follows. When the upset pressure is sufficient, gets the high tensile strength. The optimal welding conditions were n=2,000rpm, $P_1$=55MPa, $P_2$=95MPa, $t_1$=1.5sec, $t_2$=2.0sec when the total upset length is 4.5mm.

• 한국환경보건학회지
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• 제26권3호
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• pp.38-42
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• 2000

This study was performed to define the effects of the cattle feces on aerobic composting of food wastes in vessel system. Weights of cattle feces added to food wastes of 3kg were 0.25, 0.50, 1.00 and 1.50kg, respectively. Reactors were operated with stirring for 1 hour per day by 1rpm and aeration for 2 hours per day. When the weight of cattle feces was increased, the highest temperature of sample was increased, the duration period of higher temperature was elongated, and the fluctuatio of pH was severs. When the weight of cattle feces was decreased, the final density was increased. The more cattle feces were added, the more porosity was increased, C/N ratio, salinity and conductivity were decreased. There facts denotes that the addition of cattle feces increases the efficiency of composting process and the final product of composting, namely compost.

• 수산해양기술연구
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• 제12권1호
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• pp.1-6
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• 1976

To investigate the relation of $NO_x$ emission and consumption rate in a direct injection diesel engine with a multihole nozzle under same fuel consumption and rpm, a naphthyl ethylenediaming method on NO, emission and Tektronix oscilloscop on the indicator diagrams have been used. Comparisons of the $NO_x$ emission and fuel consumption rate made on various conditions have led to the fllowing results. 1. The higher the injection pressure in the later injection time the lower $NO_x$ emission and the fuel consumption rate have been attained. 2. By the change of nozzle hole diameter under the same injection pressure, the $NO_x$ emission was much more lowered in the small diameter than large one, but fuel consumption rate was in inverse proption to the $NO_x$ emission. 3. The effect of injection spray angle, $\frac{1_n}{d_n}$ on $NO_x$ emission, fuel consumption rate under same injection time and injection pressure was neglectable.

• Journal of Industrial and Engineering Chemistry
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• 제67권
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• pp.109-122
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• 2018

This work highlights extraction and removal of Lignosulfonate using sunflower oil-Tri-n-octylamine (TOA) system in bulk liquid membrane transport. Maximum extraction and recovery percentages of 92.4% and 75.2% were achieved. Optimum manifold operating conditions were: 4 vol.% TOA, $2{\pm}0.1$ feed phase pH, 300 rpm stirring speed, at $40^{\circ}C$ with 0.2 (M) $Na_2SO_4$ solution. 1:2 (organic/aqueous) and 1:1 (aqueous/aqueous) phase ratios produced best results. Extraction (36.85 kJ/mol) was found to be intermediate controlled and stripping (54.79 kJ/mol) was chemical reaction controlled. Kinetic estimation of data with higher rate constants for stripping vis-${\grave{a}}$-vis extraction showed latter to be rate determining.