• Applied Chemistry for Engineering
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• v.33 no.3
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• pp.322-327
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• 2022

Fucoidans were degraded by hydrogen peroxide under the electron beam (2.5 MeV) with various radiation doses (5 kGy, 10 kGy, 15 kGy, and 20 kGy) at room temperature. The degradation property was analyzed with a gel permeation chromatography (GPC-MALLS) method. An average molecular weight of fucoidan decreased from 99,956 at the irradiation dose of 0 kGy to 6,725 at the irradiation dose of 20 kGy. The solution viscosity of fucoidans showed a similar pattern to the molecular weight change. The number of chain breaks per molecule (N) increased with increasing the irradiation dose and concentration of hydrogen peroxide. The radiation yield of scission value markedly increased with increasing the irradiation dose up to 15 kGy. Also a 10% hydrogen peroxide concentration was more efficient than that of 5%. The structures of degraded fucoidan samples were studied with Fourier transform infrared spectroscopy (FT-IR). The results showed that the degradation process did not significantly change the chemical structure or the content of sulfate group. The sulfur content of each sample was determined with an Elemental Analyzer. With increasing the concentration of hydrogen peroxide, the ratios of sulfur/carbon, hydrogen/carbon, and nitrogen/carbon slightly decreased. The antioxidant activities of fucoidans were investigated based on hydroxyl radical scavenging activities. The ability of fucoidan to inhibit the hydroxyl radical scavenging activity was depended on its molecular weight.

• Membrane and Water Treatment
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• v.13 no.5
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• pp.209-217
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• 2022

In the present research, Ficus religiosa Bark (FRB) is used as an adsorbent for the removal of heavy metal Cr (VI) ions. This Ficus religiosa Bark was characterized by Scanning Electron Microscope, Fourier transform infrared Spectroscopy, Thermo Gravimetric Analyzer and the results showed that activated adsorbent have high adsorption capacity and withstand even in high temperature. Batch and Continuous experiments were conducted to determine the effect of various parameters such as pH, contact time, adsorbent dose and initial metal concentration. The biosorption followed pseudo first order kinetic model. The adsorption isotherms of Cr (VI) on Ficus religiosa fitted well with the Temkin model. In Batch study, maximum biosorption capacity of Cr (VI) was found to be 37.97 mg g^-1 (at optimal pH of 2, adsorbent dosage of 0.3 grams and concentration of Cr (VI) is100 mg L^-1). The Continuous mode of study shows that 97% of Cr (VI) ion removal at a flow rate of 15 ml min^-1. From the results, selected Ficus religiosa Bark has the higher adsorption capacity for the removal of Cr (VI) ions from wastewater.

• ALGAE
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• v.37 no.3
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• pp.239-247
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• 2022

Enzyme-assisted hydrolysis is frequently used as a cost-effective and efficient method to obtain functional ingredients from bioresources. This study involved the enzyme-assisted hydrolyzation and purification of fucoidan from Ecklonia maxima stipe and the investigation of its anti-inflammatory activity in lipopolysaccharide (LPS)-induced RAW 264.7 cells. Fucoidans of Viscozyme-assisted hydrolysate from E. maxima (EMSFs) harvested in Jeju, Korea. Structural and chemical characterizations were performed using fourier transform infrared spectroscopy, scanning electron microscope, and monosaccharide analysis. Among fucoidans, EMSF6 was rich in fucose and sulfate and had a similar structural character to commercial fucoidan. EMSF6 showed a strong inhibitory effect on nitric oxide generation in LPS-induced RAW 264.7 cells and significantly decreased the production of LPS-induced pro-inflammatory cytokines, including interleukin-6, interleukin-1β, and tumor necrosis factor α. The anti-inflammatory potential of EMSF6 was mediated through the downregulation of inducible nitric oxide synthase and cyclooxygenase-2 expression. Thus, fucoidans from E. maxima stipe are promising candidates for functional food products.

• Coupled systems mechanics
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• v.12 no.2
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• pp.127-149
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• 2023

A theoretical method is developed to analyze the free vibration of an elastic annular plate in contact with an ideal liquid. The displacement potential functions of the contained liquid are expressed as a combination of the Bessel functions that satisfy the Laplace equation and the liquid boundary conditions. The compatibility condition along the interface between the annular plate and the contained liquid is taken into account to consider the fluid-structure coupling. The dynamic displacement of the wet annular plate is assumed to be a combination of dry eigenfunctions, allowing for prediction of the natural frequencies using the Rayleigh-Ritz method. The study investigates the effect of radial liquid boundary conditions on the natural frequencies of the wet annular plate, considering four types of liquid bounding: outer container bounded, outer and inner bounded, inner bounded, and radially unbounded. The proposed theoretical method is validated by comparing the predicted wet natural frequencies with those obtained from finite element analysis, showing excellent accuracy. The results indicate that the radial liquid bounding effect on the natural frequencies is negligible for the axisymmetric vibrational mode, but relatively significant for the mode with one nodal diameter (n =1) and no nodal circle (m' = 0). Furthermore, the study reveals that the wet natural frequencies are the largest for the plate with an inner bounded cylinder among the radial liquid boundary cases, regardless of the vibration mode.

• Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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• v.13 no.2
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• pp.177-185
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• 1995

Gravity anomalies were recovered on a $5'\times{5'}$grid using the sea surface height data obtained from the combination of Geosat, ERS-1, Topex/Poseidon altimeter data around Korean Peninsula bounded by latitude between $30^\circ{N}\;and\;50^\circ{N}$ and longitude $120^\circ{E}\;to\;140^\circ{E.}$ In order to recover the gravity anomalies from SSH(Sea Surface Height), inverse FFT technique was applied. The estimated gravity anomalies were compared with gravity anomalies measured by shipboard around Korean Peninsula. In comparison with the differences of gravity anomaly between measured data and altimeter data, the mean and the standard deviation were found to be -0.51 mGal and 13.48 mGal, respectively. In case of comparison between the measured data and the OSU91A geopotential model, the mean and the standard deviation were found to be 11.93 mGal and 19.19 mGal, respectively. The comparison of gravity anomalies obtained from the OSU91A geopotential model and the altimeter data was carried out. The results were mean of 5.30 meal and standard deviation of 19.62 mGal. From the results, we could be concluded that the gravity anomalies computed from the altimeter data is used to the geoid computation instead of the measured data.

• Korean Journal of Materials Research
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• v.11 no.2
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• pp.88-93
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• 2001

The thermal behavior and the crystallographic characteristics of an epitaxial $C49-TiSi_2$ island formed in a Si (001) substrate by $N_2$, treatment were investigated by X-ray diffraction (XRD) and high-resolution transmission electron microscopy (HRTEM). It was found from the analyzed results that the epitaxial $C49-TiSi_2$ was thermally stable even at high temperature of $1000^{\circ}C$ therefore did not transform into the C54-stable phase and did not deform morphologically. HRTEM results clearly showed that the epitaxial $TiSi_2$ phase and Si have the orientation relationship of (060)[001]$TiSi_2$//(002)[110]Si, and the lattice strain energy at the interface was mostly relaxed by the formation of misfit dislocations. Furthermore, the mechanism on the formation of the epitaxial $_C49-TiSi2$ in Si and stacking faults lying on the (020) plane of the C49 Phase were discussed through the analysis of the HRTEM image and the atomic modeling.

• Journal of KIISE:Databases
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• v.36 no.4
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• pp.263-279
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• 2009

Shape features in a content-based image retrieval (CBIR) system are divided into two classes: contour-based and region-based. Contour-based shape features are simple but they are not as efficient as region-based shape features. Most systems using the region-based shape feature have to extract the region firs t. The prior works on region-based systems still have shortcomings. They are complex to implement, particularly with respect to region extraction, and do not sufficiently use the spatial relationship between regions in the distance model In this paper, a region extraction method that is the combination of an edge-based method and a region growing method is proposed to accurately extract regions inside an object. Edges inside an object are accurately detected based on the Canny edge detector and the Hough transform. And the modified Integrated Region Matching (IRM) scheme which includes the adjacency relationship of regions is also proposed. It is used to compute the distance between images for the similarity search using shape features. The experimental results show the effectiveness of our region extraction method as well as the modified IRM. In comparison with other works, it is shown that the new region extraction method outperforms others.

• Journal of the Korean Society of Food Science and Nutrition
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• v.43 no.10
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• pp.1535-1542
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• 2014

This study was conducted to investigate the physicochemical properties and biological activities of collagens with different molecular weights from Alaska pollack (Theragra chalcogramma) skin as well as their efficacies as functional materials. The molecular weights of collagens were between 1~10 kDa (below 1 kDa (AP1), 1~3 kDa (AP2), 3~10 kDa (AP3), and above 10 kDa (AP4). The protein content of AP4 (40.19 g/100 g) was the highest. Collagen contents of AP1, AP2, AP3, and AP4 were 36.43, 32.23, 19.23, and 14.89%, respectively. The free amino acid and essential amino acid contents of AP1 were higher than those of AP2, AP3, and AP4. Fourier transform infrared spectroscopy spectra of collagens with different molecular weights showed wavenumbers representing the regions of amide I, amide II, amide III, and amide A, respectively. The electron-donating ability (29.51%) and SOD-like activity (38.45%) of AP1 were higher than those of AP2, AP3, and AP4. Tyrosinase inhibition activity of AP1 improved with higher treatment concentration. The rate of inhibition of MMP-1 production in HS68 cells exposed to UVB was suppressed by treatment with AP1 (29.78%) and AP2 (26.49%) at 1 mg/mL. Furthermore, there was a strong correlation between DPPH, superoxide dismutase, tyrosinase activity, and MMP-1 inhibition rate of collagens with different molecular weights.

• Applied Chemistry for Engineering
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• v.24 no.4
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• pp.363-369
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• 2013

In this work, the effects of ozone treatments on mechanical interfacial properties of carbon fibers-reinforced nylon-6 matrix composites were investigated. The surface properties of ozone treated carbon fibers were studied by Fourier transform infrared spectroscopy (FT-IR) and X-ray photoelectron spectroscopy (XPS). Mechanical interfacial properties of the composites were investigated using critical stress intensity factor ($K_{IC}$). The cross-section morphologies of ozone-treated carbon fiber/nylon-6 composites were observed by scanning electron microscope (SEM). As a result, $K_{IC}$ of the ozone-treated carbon fibers-reinforced composites showed higher values than those of as-received carbon fibers-reinforced composites due the enhanced $O_{1s}/C_{1s}$ ratio of the carbon fiber by the ozone treatments. This result concludes that the mechanical interfacial properties of nylon-6 matrix composites can be controlled by suitable ozone treatments on the carbon fibers.

• Journal of KIISE:Software and Applications
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• v.26 no.10
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• pp.1193-1203
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• 1999

본 논문에서는 한글과 영문 문서 영상들에 대한 기울어짐 추정(skew estimation) 알고리즘을 제안한다. 제안 방법은 전체 문서 영상에서 텍스트 요소들이 밀집되어 있는 영역을 선별하고, 선별된 영역에 대해 허프 변환을 적용하는 선택적 주의집중(selective attention) 방식을 채택한다. 제안 방법의 기울기 추정 과정은 2단계로 구성되는데, coarse 단계에서는 전체 영상을 몇 개의 영역으로 나누고 동일한 영역에 속하는 데이타들간의 연결 각도를 계산하여 각 영역별 accumulator에 저장한다. accumulator에 저장된 빈도치를 기준으로 $\pm$45$^{\circ}$범위 내에서 최대 $\pm$1$^{\circ}$의 오차를 가진 각 영역별 기울기를 계산한 후, 이들 중 최대 빈도값을 갖는 영역을 선정하고 그 영역의 기울기 각도를 문서 영상의 대략적인 기울기 각도로 결정한다. Refine 단계에서는 coarse 단계에서 선정된 영역에 허프 변환을 적용하여 정확한 기울기를 계산하는데, coarse 단계에서 추정한 기울기의 $\pm$1$^{\circ}$범위 내에서 0.1$^{\circ}$간격으로 측정한다. 이와 같은 선택적 주의집중 방식을 통해 기울기 추정에 소요되는 시간 비용은 최소화하고, 추정의 정확도는 최대화 할 수 있다.제안 방법의 성능 평가를 위한 실험은 다양한 형태의 영문과 한글 문서 영상 2,016개에 적용되었다. 제안 방법의 평균 수행 시간은 Pentium 200MHz PC에서 0.19초이고 평균 오차는 $\pm$0.08$^{\circ}$이다. 또한 기존의 기울기 추정 방법과 제안 방법의 성능을 비교하여 제안 방법의 우수성을 입증하였다.Abstract In this paper we propose a skew estimation algorithm for English and Korean document images. The proposed method adopts a selective attention strategy, in which we choose a region of interest which contains a cluster of text components and then apply a Hough transform to this region. The skew estimation process consists of two steps. In the coarse step, we divide the entire image into several regions, and compute the skew angle of each region by accumulating the slopes of lines connecting any two components in the region. The skew angle is estimated within the range of $\pm$45 degree with a maximum error of $\pm$1 degree. Next we select a region which has the most frequent slope in the accumulators and determine the skew angle of the image roughly as the angle corresponding to the most frequent slope. In the refine step, a Hough transform is applied for the selected region within the range of $\pm$1 degree along the angle computed from the coarse step, with an angular resolution of 0.1 degree. Based on this selective attention strategy, we can minimize the time cost and maximize the accuracy of the skew estimation.We have measured the performance of the proposed method by an experiment with 2,016 images of various English and Korean documents. The average run time is 0.19 second on a Pentium 200MHz PC, and the average error is $\pm$0.08 degree. We also have proven the superiority of our algorithm by comparing the performance with that of other well-known methods in the literature.