• Title/Summary/Keyword: N-${\alpha}$ 곡선

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Adsorption and Biological Properties of Ni-treated PAN Based Activated Carbon Fiber (Ni가 처리된 PAN계 활성탄소섬유의 흡착특성과 생물학적 특성)

  • Oh, Won-Chun
    • Analytical Science and Technology
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    • v.13 no.2
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    • pp.194-199
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    • 2000
  • The study on the adsorption, the surface properties and the antibacterial effects of the Ni-treated PAN based activated carbon fibers was carried out. In the adsorption study on the Ni-treated PAN based ACFs, Type I isotherms for N1-N3 and Type II-Type III isotherms for N4-N6 were obtained, respectively. Futhermore, their adsorbed volumes slowly were decreased with the increase in the mole concentration of Ni on the treated PAN based ACFs. From the BET equation, the specific surface areas of the Ni-treated PAN based ACFs were in the range of $692.58-895.24m^2/g$. The micropore volumes obtained from ${\alpha}_s$-method using common-t value were $0.19-0.56cm^3/g$. The surfaces of PAN based ACFs partially blocked by metal after the treatment were observed from the SEM micrographs. Finally, from the antibacterial effects using Shake flask method against E. coli, the percentage of the effects was 92.5-100% and the antibacterial effect was increased with the increase in mole concentration of Ni treated.

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Oxidation of Polymers in Nonaqueous Solutions (비수용액 내에서 중합체의 산화)

  • Choi, Chil Nam;Yang, Hyo Kyung
    • Journal of the Korean Chemical Society
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    • v.45 no.2
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    • pp.138-160
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    • 2001
  • In this study we measured oxidation potentials and current densities for poly(vinylcholride) (PVC) and poly(carbonate)(PC) in nonaqueous solutions, in order to find out how corrosion (oxidation) potentials depend on temperature, pH, enzyme, or added salts. The Tafel's slopes were determined from the Tafel plots of polarization curves. The transfer coefficients (${\alpha}$) wre evaluated from the slope(1-${\alpha}$)nF/2.3 RT, and the electrode reactions appeared irreversible under all conditions.

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ESTIMATION OF THE SURVIVAL RATE IN FISH POPULATION FROM THE LENGTH COMPOSITION AND THE GROWTH EQUATION1 (체장조성과 성장곡선식에서 생잔율을 추정하는 방법)

  • SHIN Sang Taek
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.10 no.2
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    • pp.137-143
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    • 1977
  • A study has been made to find out a new method of calculating the survival rate of a fish population from length composition and growth equation. 1. In the steady state of the fish population, let the total mortality rate be z, the age of complete recruitment $\alpha$, and the number of $\chi$ year class $N_\chi$. Then ire obtain $$N\chi=N\alpha\;\exp\;{-z(\chi-\alpha)}$$ Let the oldest age in the catch be h, the average age between the age of complete recruitment and the oldest age in the catch $U\chi$. Then we have $$U\chi=\frac{a-b\;\exp\;(-z(b-a))}{1-\exp\;(-z(b-a))}+\frac{1}{z}....(1)$$ and then let be infinite. Then we obtain $$Z=\frac{1}{U\chi-\alpha....(2)$$ 2. Calculating numerical value of $U\chi$ from age composition table and growth equation and substitute in (1) or (2) for it, we may obtain the value of s and $\varrho^{-z}$. 3. This method is applied t a case of yellow croaker in the Yellow Sea and the East China Sea. The results are as follows: Total mortality rate 0.82595 Survival rate 0.43782 95 percent confidence interval 0.43767-0.43797.

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A Study on the Soil Water Characteristic Curve with Change of Coefficient of Uniform in Compacted Granitic Soils (다짐 화강풍화토의 균등계수 변화에 따른 함수특성곡선에 관한 연구)

  • Yoo, Kun-Sun;Kim, Doc-Kyoung;Yoo, Nam-Jae
    • Journal of Industrial Technology
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    • v.29 no.A
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    • pp.145-153
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    • 2009
  • In this study, to determine characteristics of compaction and the soil water characteristic curve(SWCC) in decomposed granitic soils, compaction tests and SWCC tests were carried out for samples having various contents of coefficient of uniform($c_u$), By compacting their samples with standard Proctor density test, the effects of binder contents on maximum dry density and optimum moisture content were investigated and compared. Samples compacted with the maximum dry density and the optimum moisture content were tested by means of the SWCC, to determine their SWCC parameters, such as Brooks & Corey(${\lambda}$, ${\Psi}_b$), Van Genuchten (${\alpha}$, n, m), Fredlund & Xing(a, n, m).

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A Study on the Stability of Langmuir-Blodgett(LB) Films of L-${\alpha}$-Phosphatidylethanolamine Monolayer (L-${\alpha}$-Phosphatidylethanolamine 단분자층 LB막의 안정성에 관한 연구)

  • Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.1
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    • pp.44-49
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    • 2014
  • We were investigated by cyclic voltammetry to the stability through the electrochemical characteristics of phospholipid(L-${\alpha}$-phosphatidylethanolamine, LAPE) monolayer LB films. LAPE monolayer LB films was deposited by the LB method on the indium tin oxide(ITO) glass. The electrochemical properties was measured by cyclic voltammetry with a three-electrode system in 0.5 N, 1.0 N, 1.5 N and 2.0 N $KClO_4$ solution. The measuring range is continuously oxidized to 1650 mV, with an initial potential of -1350 mV was reduced. Scanning rates of 50, 100, 150, 200, and 250 mV/s was set. As a result, LB monolayer films of LAPE was appeared on irreversible processes by the oxidation current from the cyclic voltammogram. Diffusion coefficient (D) of LAPE was calculated 195, 15.9, 5.75, 1.38 and $0.754cm^2s^{-1}{\times}10^{-9}$ at 0.01 N, 0.05 N, 0.10 N, 0.15 N and 0.20 N $KClO_4$ solutions, respectively.

Importance of Baseflow Separation and Nonpoint Source Pollutant Loadings through Baseflow for Efficient Watershed Managemen (효율적인 유역관리를 위한 기저유출 분리 및 기저비점의 중요성)

  • Han, Jeong Ho;Kum, Dong Hyuk;Kim, Jonggun;Lim, Kyoun Jae
    • Proceedings of the Korea Water Resources Association Conference
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    • 2017.05a
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    • pp.88-88
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    • 2017
  • 유역에서의 효율적인 수량 및 수질 관리를 위해서는 정확한 수문 구성요소에 대한 이해가 선행되어야 한다. 유출 수문곡선을 이용한 많은 연구가 수행되었음에도 불구하고 정확한 기저유출 산정에 관한 연구는 매우 제한적으로 수행되어 왔다. 수문학교과서에 수록된 다양한 기저유출 방법은 실제 장기 유출 수문곡선에 적용하는데 한계가 있으며, 유역의 다양한 유출특성을 반영할 수 없다. 따라서 본 연구에서는 USGS에서 개발한 기저유출 분리 모형와 SWAT BFlow, 그리고 WHAT 시스템에 특성에 대해서 분석하였으며, 이러한 모형을 이용한 기저유출 분석의 한계점을 제시하였다. 정확한 기저유출 분리를 위해서는 유역의 감수곡선 특성을 반영한 기저유출 분리가 이루어져야 하며, 주지하수 감수곡선처럼 유역 대표 감수 특성을 이용하기 보다는 유황이나 계절별 감수특성을 고려한 김수 특성 인자에 대한 연구가 필요하다. 이외에도 유역에서 기저유출로 인한 오염부하 특성을 NO3-N을 중심으로 분석하여 정확한 기저유출 산정의 중요성을 제시하였다. 이와 같이 기저유출과 같은 수문 구성 요소에 대한 정확한 이해 없이는 효율적인 수량 및 수질 관리가 어려울 것으로 판단된다.

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Experimental Study on the Hysteresis of Suction Stress in Unsaturated Sand (불포화 모래의 흡입응력 이력현상에 대한 실험적 연구)

  • Song, Young-Suk;Choi, Jin-Su;Kim, Gyo-Won
    • The Journal of Engineering Geology
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    • v.22 no.2
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    • pp.145-155
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    • 2012
  • The matric suction and volumetric water content of Jumunin standard sand with a relative density of 60% were measured using an Automated Soil-Water Characteristic Curve (SWCC) apparatus during both drying and wetting processes. The test time for the drying process was longer than that for the wetting process, because the flow of water is likely to be protected by air trapped in voids within the soils during the drying process. Based on the matric suction and volumetric water content, the SWCC was estimated using the model proposed by van Genuchten (1980). For the drying process, the unsaturated fitting parameters ${\alpha}$, n, and m were 0.399, 8.586, and 0.884, respectively; for the wetting process, the values were 0.548, 5.625, and 8.220, respectively. The hysteresis phenomenon occurred in the SWCCs, which means the SWCC of the drying process is not matched with the SWCC of the wetting process. Using these unsaturated parameters, we estimated the Suction Stress Characteristic Curve (SSCC), based on the relationship between suction stress and the effective degree of saturation. The suction stress showed a rapid decrease when the matric suction exceeds the Air Entry Value (AEV). Therefore, the effective stress of unsaturated soils is different from that of saturated soils when the matric suction exceeds the AEV. The suction stress of the drying process exceeds that of the wetting process for a given effective degree of saturation. The hysteresis phenomenon was also recognized in SSCCs. The hysteresis phenomenon of SSCCs arises from that of SWCCs, which is induced by the ink bottle effect and the contact angle effect. In the case of a sandy slope, the suction stress is positive and acts to enhance the slope stability as the water infiltrates the ground, but is negative when the suction stress exceeds the AEV. The results obtained for the wetting process should be applied in analyses of slope stability, because the process of water infiltration into ground is similar to the wetting process.

Estimation on Unsaturated Hydraulic Conductivity Function of Jumoonjin Sand for Various Relative Densities (주문진 표준사의 상대밀도에 따른 불포화 투수계수함수 산정)

  • Song, Young-Suk
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.33 no.6
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    • pp.2369-2379
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    • 2013
  • The Soil-Water Characteristics Curve (SWCC) is affected by the initial density of soil under unsaturated condition. Also, the characteristic of hydraulic conductivity is changed by the initial density of soil. To study the effect of initial density of unsaturated soil, SWCC and the Hydraulic Conductivity Function (HCF) of Jumoonjin sand with various relative densities, 40%, 60% and 75% were measured in both drying and wetting processes. As the results of SWCC estimated by van Genuchten (1980) model, the parameter related to Air Entry Value(AEV), ${\alpha}$ in the wetting process is larger than that in drying process, but the parameters related to the SWCC slope, n and the residual water content, m are larger than those in wetting process. The AEV is increased or Water Entry Value (WEV) is decreased with increasing the relative density of sand. The AEV is larger than the WEV at the same relative density of sand. As the results of HCF estimated by van Genuchten (1980) model which is one of the parameter estimation methods, the unsaturated hydraulic conductivity maintained at a saturated one in the low level of matric suctions and then suddenly decreased just before the AEV or the WEV. The saturated hydraulic conductivity in drying process is larger than that in wetting process. The saturated hydraulic conductivity is decreased with increasing the relative density of sand in both drying and wetting processes. Also, the hysteresis in unsaturated HCFs between drying and wetting process was occurred like the hysteresis in SWCCs. According to the test results, the AEV on SWCC is decreased and the saturated hydraulic conductivity is increased with increasing the initial density. It means that SWCC and HCF are affected by the initial density in the unsaturated soil.

A Kinetic Study of the Aluminum Electrode in Molten 60 Mole Percent $AlCl_3$-40 Mole Percent NaCl at 453${\circ}K$ (용융 (60 몰% $AlCl_3$-40 몰% NaCl) 염 속에서의 알루미늄전극의 반응속도론적 연구)

  • G. F. Uhlig;T. N. Andersen;S. Johns;H. Eyring
    • Journal of the Korean Chemical Society
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    • v.18 no.6
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    • pp.400-407
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    • 1974
  • Steady-state anodic and cathodic polarization curves were developed for the Al electrode in 60 mole %$AlCl_3$-40 mole % NaCl at $180^{\circ}C$$453^{\circ}K$). Ohmic resistance contributed substantially to the anodic polarization at current densities greater than 50 mA/$CM^2$ even with capillary tip placed close to the electrode. This could not be rationalized from the resistivity of the melt, which would lead to a much smaller polarization. It was therefore concluded that a layer of high resistance $AlCl_3$ (or $AlCl_3$-rich melt) formed close to the anode surface. From the IR-corrected anodic Tafel and Allen-Hickling plots an apparent anodic charge-transfer coefficient of ${\alpha}_a$ = (2.3 RT/F)(d log i/d${\eta}$) = $1.5{\pm}0.25$ was obtained. At cathodic current densities greater than approximately 30 mA/$cm^2$, slow ion diffusion and dendrite growth both interfered with the measurement of kinetic parameters.

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Analysis of Fatigue Crack Growth in a Viscoelastic Material using ${\Delta}J$-integral (${\Delta}J$-적분을 이용한 점탄성 재료의 피로균열 성장분석)

  • Yu, Seong-Mun;Zi, Goang-Seup;Thanh, Chau Dinh;Lee, Hyun-Jong;Mun, Sung-Ho
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.23 no.5
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    • pp.483-491
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    • 2010
  • In this paper, ${\Delta}J$-integral is used to analyze fatigue crack growth of viscoelastic material. Using analytical integral value, the J-integral is calculated. So, reduction of calculation time and increase of accuracy are made possible. The stress intensity factor is calculated using the finite element method code. In difference with existed fatigue crack analysis using ${\Delta}K$, we were successfully able to analyze various load amplitude and the fatigue crack of load cycle only with two fatigue crack growth parameters and creep compliance. The analysis gives N-${\alpha}$ curve for simulation of crack growth, and the curve almost corresponds with test results.