• Title/Summary/Keyword: N removal

Search Result 2,203, Processing Time 0.03 seconds

The Kinetic Analysis on Organic Substrate Removal and Nitrification in Anoxic-Anaerobic-Aerobic Process (무산소-혐기-호기법에서 유기기질제거와 질산화의 동역학적 해석)

  • Chae, Soo Kwon
    • Journal of Korean Society on Water Environment
    • /
    • v.23 no.5
    • /
    • pp.689-696
    • /
    • 2007
  • Kinetic analysis was important to develope the biological nutrient removal process effectively. In this research, anoxic-anaerobic-aerobic system was operated to investigate kinetic behavior on the nutrient removal reaction. Nitrification and denitrification were important microbiological reactions of nitrogen. The kinetics of organic removal and nitrification reaction have been investigated based on a Monod-type expression involving two growth limiting substrates : TKN for nitrification and COD for organic removal reaction. The kinetic constans and yield coefficients were evaluated for both these reactions. Experiments were conducted to determine the biological kinetic coefficients and the removal efficiencies of COD and TKN at five different MLSS concentrations of 5000, 4200, 3300, 2600, and 1900 mg/L for synthetic wastewater. Mathematical equations were presented to permit complete evaluation of the this system. Kinetic behaviors for the organic removal and nitrification reaction were examined by the determined kinetic coefficient and the assumed operation condition and the predicted model formulae using kinetic approach. The conclusions derived from this experimental research were as follows : 1. Biological kinetic coefficients were Y=0.563, $k_d=0.054(day^{-1})$, $K_S=49.16(mg/L)$, $k=2.045(day^{-1})$ for the removal of COD and $Y_N=0.024$, $k_{dN}=0.0063(day^{-1})$, $K_{SN}=3.21(mg/L)$, $k_N=31.4(day^{-1})$ for the removal of TKN respectively. 2. The predicted kinetic model formulae could determine the predicted concentration of the activated sludge and nitrifier, investigate the distribution rate of input carbon and nitrogen in relation to the solid retention time (SRT).

Removing High Concentration Nitrogen by Electrolysis (전기분해에 의한 고농도 질소 제거의 특성)

  • Gil, Dae-Soo;Lee, Byung-Hun;Choi, Hae-Kyoung;Kwon, Dong-Min
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.22 no.2
    • /
    • pp.265-277
    • /
    • 2000
  • Laboratory experiments were conducted to investigate characteristics for removing ammonia-nitrogens by electrolysis methods. A stainless steel plate is used as the cathode and either $IrO_2{\backslash}Ti$ plate serves as the anode. Experiments were conducted to examine the effects of the operating conditions, such as the current density, retention time, electrode gap, $Cl^-/NH_4{^+}-N$ on the $NH_4{^+}-N$ removal efficiency. Possible optimum range for these operating variables are experimentally determined. The $NH_4{^+}-N$ removal efficiencies between plate type anode and net type anode were about same effect, but electrolytic power using net type anode is low than plate type anode. The $Cl^-/NH_4{^+}-N$ ratio was about $20.0kgCl^-/kgNH_4{^+}-N$ when $NH_4{^+}-N$ removal obtained 73 %, $Cl^-/NH_4{^+}-N$ ratio needs $27.6kgCl^-/kgNH_4{^+}-N$ so as to $NH_4{^+}-N$ completely remove. The removal efficiency of $NH_4{^+}-N$ increase with current density, retention time and $Cl^-/NH_4{^+}-N$ ratio, but decreased with increasing electrode gap. The relationship of operating conditions and $NH_4{^+}-N$ removal efficiencies are $$NH_4{^+}-N_{re}(%)=14.5364(Current\;density)^{0.7093}{\times}(HRT)^{1.0060}{\times}(Gap)^{-0.9926}{\times}(Cl^-/NH_4{^+}-N)^{1.0024}$$ With adding COD or/and alkalinity, relationships are $$NH_4{^+}-N_{re}(%)=9.8408(Current\;density)^{0.6232}{\times}(HRT)^{1.0534}$$ There existed a competition between the removals for $NH_4{^+}-N$ and $COD_{Cr}$ during electrolysis, the removal of $NH_4{^+}-N$ was shown to be dominant. $NH_4{^+}-N$ removal was high as addition of glucose and alkalinity.

  • PDF

Municipal Wastewater Treatment by Submerged Membrane Process (침지형 membrane을 이용한 생활오수처리)

  • 김광남;정순형;정우영;윤용수
    • Journal of environmental and Sanitary engineering
    • /
    • v.14 no.2
    • /
    • pp.105-112
    • /
    • 1999
  • The removal characteristic of BOD, COD,T-N, and T-P was investigated in municipal wastewater treatment with anoxic and membrane submerged aerobic reactor. It was found that BOD and COD removal rate were obtained 90% and 92%, respectively, for 90 days operation. BOD and COD loading rate did not affect to the removal efficiency because MLSS concentration in aerobic tank was highly maintained.In the case of first reactor operated with anoxic and second reactor operated as aerobic, T-N, T-P removal rate were obtained 93% and 99% respectively.It was shown that removal efficiency could be maintained stable due to the complete removal of SS and sludge production decreased with increasing of sludge retention time.

  • PDF

Removal of N and P by Intermittented Aeration Activated Sludge Process (간헐폭기식 활성슬러지 공법에 의한 질소, 인 제거)

  • 김동밀;이영신
    • Journal of Environmental Health Sciences
    • /
    • v.18 no.2
    • /
    • pp.57-61
    • /
    • 1992
  • This study was made for enhanced removal of N and P by intermittented aeration Activated Sludge Process. Experiment were conducted to find the effects of aeration interval and nutrient removal efficiency. When applied aeration interval were 30~60 min, 2~4 h, 4~8 h, organic matter was not affected while phosphorous removal was aeration interval 30~60 min. Also, when applied mixing intensity were 15, 30, 45 and 60 rpm, organic matter was not affected while removal was maximum at 15 rpm. Total nitrogen and phosphorous removal were in the range of 76 and 85%. Density and MLSS of Sludge were in the range of 2.3~2.6 and 7198~7810 mg/l. Release of phosphorous from activated sludge under unaerobic condition was increased as pass time.

  • PDF

A comparative study on SBR and MLE Process for RO Retentate Treatment (RO 농축수 처리를 위한 SBR과 MLE 공정의 비교 평가)

  • Kim, Il-Whee;Lee, Sang-Il
    • Journal of Korean Society of Water and Wastewater
    • /
    • v.25 no.6
    • /
    • pp.907-915
    • /
    • 2011
  • In this study, the SBR and MLE process was performed for a removal of the RO retentate and the nitrogen removal efficiency was evaluated. The inflow-rate of two processes was set a 10 L/day. The SBR process was operated a two cycle as HRT per one cycle was 12hr and the HRT of the anoxic and aerobic tank was respectively 7.5 hr and 16.5 hr. The methanol was injected for an effective denitrificaion owing to a low C/N ratio of the RO retentate. The two processes were effectively performed for nitrogen removal, but the average removal efficiency of the SBR process was about 94.93% better performance than the MLE process. Therefore, the SBR process demonstrated a good performance more than the MLE process for nitrogen removal of the RO retentate. The kinetic of SNR and SDNR was observed respectively 0.051 kg $NH_{3}-N/kg\;MLVSS{\cdot}dayg$ and 0.287 kg ${NO_3}^--N/kg\;MLVSS{\cdot}day$, which will be useful to design for the wastewater treatment system with a RO retentate.

Mg/Al Impregnated Biochar for the Removal and Recovery of Phosphates and Nitrate

  • Kim, Dong-Jin
    • Proceedings of the Korean Environmental Sciences Society Conference
    • /
    • 2019.10a
    • /
    • pp.134-134
    • /
    • 2019
  • Utilization of organic waste as a renewable energy source is promising for sustainability and mitigation of climate change. Pyrolysis converts organic waste to gas, oil, and biochar by incomplete biomass combustion. Biochar is widely used as a soil conditioner and adsorbent. Biochar adsorbs/desorbs metals and ions depending on the soil environment and condition to act as a nutrient buffer in soils. Biochar is also regarded as a carbon storage by fixation of organic carbon. Phosphorus (P) and nitrogen (N) are strictly controlled in many wastewater treatment plants because it causes eutrophication in water bodies. P and N is removed by biological and chemical methods in wastewater treatment plants and transferred to sludge for disposal. On the other hand, P is an irreplaceable essential element for all living organisms and its resource (phosphate rock) is estimated about 100 years of economical mining. Therefore, P and N recovery from waste and wastewater is a critical issue for sustainable human society. For the purpose, intensive researches have been carried out to remove and recover P and N from waste and wastewater. Previous studies have shown that biochars can adsorb and desorbed phosphates implying that biochars could be a complementary fertilizer. However, most of the conventional biochar have limited capacity to adsorb phosphates and nitrate. Recent studies have focused on biochar impregnated with metal salts to improve phosphates and nitrate adsorption by synthesizing biochars with novel structures and surface properties. Metal salts and metal oxides have been used for the surface modification of biochars. If P removal is the only concern, P adsorption kinetics and capacity are the only important factors. If both of P and N removal and the application of recovery are concerned, however, P and N desorption characteristics and bioavailability are also critical factors to be considered. Most of the researches on impregnated biochars have focused on P removal efficiency and kinetics. In this study, coffee waste is thermally treated to produce biochar and it was impregnated with Mg/Al to enhance phosphates and nitrate adsorption/desorption and P bioavailability to increase its value as a fertilizer. Kinetics of phosphates and nitrate adsorption/desorption and bioavailability analysis were carried out to estimate its potential as a P and N removal adsorbent in wasewater and a fertilizer in soil.

  • PDF

Removal of Nitrogen and Phosphorus by Salix gracilistyla Miq. (갯버들(Salix gracilistyla Miq.)의 질소와 인 제거능)

  • 신정이;차영일
    • Korean Journal of Environmental Biology
    • /
    • v.17 no.4
    • /
    • pp.449-457
    • /
    • 1999
  • Removal efficiency and potential of N and P by Salix gracilistyla Miq. are determined in continuous flow tanks as a function of hydraulic retention time (HRT, days) and nutrient concentration (NC). Results show that the removal efficiency was longer HRT and lower nutrient solution. And also removal potential was higher at shorter HRT and higher nutrient concentration, and the regression equations were estimated. Mean above ground biomass of Salix gracilistyla Miq. in the middle reaches of Suip stream was 4880.81 g/$m^2$, and estimated removal by this vegetation from biomass and estimated equation above were 0.49~15.49 NH$_4$-N kg/day, 5.83~405.39 NO$_3$-N kg/day, 7.57~23.22 PO$_4$-P kg/day in Suip stream, respectively when HRT was 0.59~5.21, inflow concentration was 0.05~0.4, mg/L NH$_4$-N, 1.42~11.36 mg/L NO$_3$-N, 0.1~0.27 mg/L PO$_4$-P. According to this study, it is concluded that Salix gracilistyla Miq. are contribute by their high biomass and for water quality improvement of stream through nutrient removal potential.

  • PDF

Study of Supercritical Carbon Dioxide/n-Butyl Acetate Co-solvent System with High Selectivity in Photoresist Removal Process (포토레지스트 공정에서 높은 선택성을 가지는 초임계 이산화탄소/n-butyl acetate 공용매 시스템 연구)

  • Kim, Dong Woo;Heo, Hoon;Lim, Kwon Teak
    • Clean Technology
    • /
    • v.23 no.4
    • /
    • pp.357-363
    • /
    • 2017
  • In this study, the supercritical carbon dioxide ($scCO_2$)/ n-butyl acetate (n-BA) co-solvent system was employed to remove an unexposed negative photoresist (PR) from the surface of a silicon wafer. In addition, the selectivity of the $scCO_2$/n-BA co-solvent system was confirmed for the unexposed and exposed negative PR. Optimum conditions for removal of the unexposed PR were obtained from various conditions such as pressure, temperature and n-BA ratio. The n-BA was highly soluble in $scCO_2$ without cloud point and phase separation in mostly experimental conditions. However, the $scCO_2$/n-BA co-solvent was phase separated at 100 bar, above $80^{\circ}C$. The unexposed and exposed PR was swelled in $scCO_2$ solvent at all experimental conditions. The complete removal of unexposed PR was achieved from the reaction condition of 160 bar, 10 min, $40^{\circ}C$ and 75 wt% n-BA in $scCO_2$, as measured by ellipsometry. The exposed photoresist showed high stability in the $scCO_2$/n-BA co-solvent system, which indicated that the $scCO_2$/n-BA co-solvent system has high selectivity for the PR removal in photo lithograph process. The $scCO_2$/n-BA co-solvent system not only prevent swelling of exposed PR, but also provide efficient and powful performance to removal unexposed PR.

Inorganic Nutrient Removal Efficiency of Aquatic Plants from Recirculating Aquaculture System (수생식물을 이용한 담수 순환여과식 양식용수내의 무기영양염 처리 효율)

  • 마진석;오승용;조재윤
    • Journal of Aquaculture
    • /
    • v.16 no.3
    • /
    • pp.171-178
    • /
    • 2003
  • Inorganic nutrients such as nitrogen and phosphate compounds accumulate in recirculating aquaculture systems. These nutrients must be removed from the system before they affect pH and fish health. For this purpose, aquatic plants are a simple and inexpensive method of removal. There are four commonly used aquatic plants: Eichhornia crassipes (water hyacinth), Pistia stratiotes (water lettuce), Hygrophila angustifolia, and Hydrocotyle leucocephala in freshwater recirculating aquaculture systems in Korea, but their efficiencies are not known. Therefore, removal efficiencies of inorganic nutrients from a freshwater recirculating aquaculture water with four commonly used aquatic plants were tested. Removing efficiencies of TAN, N $O_2$$^{[-10]}$ -N, and N $O_3$$^{[-10]}$ -N of the plants in 210 L aquaria for 48-hour period were tested. The removing efficiencies of TAN, N $O_3$$^{[-10]}$ -N, and P $O_4$$^{3-}$-P of the two most effective plants, water hyacinth and water lettuce, were also tested in 690 L (surface area of 1.55 $m^2$) tanks under 2 different initial stocking densities, 4 kg and 6 kg, for 22 days. Proximate analysis major nutrients and N and P contents of the all plants were analyzed for calculating net removal weight of N and P by the plants. Water lettuce was the most effective for removing TAN, N $O_2$$^{[-10]}$ -N, and N $O_3$$^{[-10]}$ -N from the water for 48-hour period tested followed by water hyacinth and Hygrophila angustifolia. Water lettuce reduced TAN, N $O_2$$^{[-10]}$ -N, and N $O_3$$^{[-10]}$ -N concentration from 2.3 mg/L, 0.197 mg/L, and 21.4 mg/L to 0.4 mg/L, 0.024 mg/L and 17.4 mg/L, respectively while water hyacinth reduced them down to 0.6 mg/L, 0.029 mg/L and 17.9 mg/L, respectively. The concentrations of TAN, N $O_2$$^{[-10]}$ -N, and N $O_3$$^{[-10]}$ -N in Hydrocotyle leucocephala group were rather increased up to 3.7 mg/L, 5.7 mg/L and 48.2 mg/L, respectively. This is because the creeping stem of Hydrocotyle leucocephala had to be cut to meet stocking weight resulting in decaying of the stem in the aquaria during experiment. The net growth in weight of water hycinth and water lettuce of 4 kg each in the 1.55 $m^2$ tanks for 22 days were 9.768 kg and 10.803 kg respectively, and those at initial weight of 6 kg each were 8.393 kg and 9.433 kg, respectively. The reason of lower net growth in the later group was restricted growth space. Nitrogen and phosphorus contents in water hyacinth were 2.89% and 0.27%, and those in water lettuce were 3.87% and 0.36%, respectively. Average quantities of removed N and P from 1.55 $m^2$ tanks by water hyacinth for 22 days were 18.9 g and 1.75 g, while those by water lettuce were 36.8 g and 3.5 g, respectively. Therefore water lettuce showed much higher efficiencies for removing both N and P from recirculating aquaculture water than water hyacinth.

Advanced Sewage Treatment by the Modified SBR(Sequencing Batch Reactor) Process (변형 연속회분식 반응기를 이용한 오수의 고도처리)

  • 김병군;서인석;홍성택;정위득
    • Journal of environmental and Sanitary engineering
    • /
    • v.17 no.3
    • /
    • pp.46-51
    • /
    • 2002
  • This study was performed to treat a sewage at the upper stream of dam using modified sequencing batch reactor, During the operating period, average $COD_{cr}$, removal efficiency was about 85% but average T-N and ${PO_4}^{3-}-P$ removal efficiencies were 43% and 30% respectively. Because the organic matter was very low compared with nitrogen and phosphorous in influent($BOD_{5}/{NH_4}^{+}-N{\;}={\;}2,{\;}BOD_{5}/{PO_4}^{3-}-P{\;}={\;}15.6$), nitrogen and phosphorus removal efficiency was relatively low. Average nitrogen removal efficiency was 50 % at $10^{\circ}C$ or above and it was 36 % at $10^{\circ}C$ or below. As reactor was located in outdoor without any thermostat, temperature decreased at least $2.4^{\circ}C$ in the winter season. Therefore, if we would apply this modified sequencing batch reactor to sewage which concentration of organic matter was very low compared with nitrogen and phosphorous, we have to addition of external carbon and installation of any thermostat.